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2011 Fiscal Year Final Research Report

Development of Metal-Encapsulating Silicone Gel Catalysts

Research Project

  • PDF
Project/Area Number 21605009
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Element strategy
Research InstitutionKyushu University

Principal Investigator

MOTOYAMA Yukihiro  九州大学, 先導物質化学研究所, 准教授 (20283492)

Project Period (FY) 2009 – 2011
Keywords合成化学 / 触媒 / 化学プロセス / 固定化触媒 / 環境対応 / 希少元素
Research Abstract

In this work, we succeeded in immobilizing bipyridine and chiral bis(oxazoline) ligands bearing alkenyl moieties into the polysiloxane gels by hidrosilylation using polymethylhydrosiloxane and 1, 5-hexadiene. These ligand-encapsulating gels capture the Cu salts effectively to generate the catalytically active species in the gel. These metal-encapsulating silicone gels act as efficient recyclable catalysts for atom-transfer radical cyclization of alfa-halogenated acetoamides and asymmetric cyclopropanation of alkenes and diazoacetates without leaching of the metallic species.

  • Research Products

    (7 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results)

  • [Journal Article] A Chiral Bis(oxazoline) Ligand Embedded into Polysiloxane Gel : Application to a Reusable Copper Catalyst for Asymmetric Cyclopropanation2011

    • Author(s)
      Motoyama, Y.; Nishikata, K.; Nagashima, H.
    • Journal Title

      Chem. Asian J.

      Volume: 6 Pages: 78-82

    • Peer Reviewed
  • [Journal Article] Catalytic Atom-Transfer Radical Cyclization by Copper/Bipyridine Species Encapsulated in Polysiloxane Gel2010

    • Author(s)
      Motoyama, Y.; Kamo, K.; Yuasa, A.; Nagashima, H.
    • Journal Title

      Chem. Commun.

      Volume: 46 Pages: 2256-2258

    • Peer Reviewed
  • [Presentation] A Chiral Bis(oxazoline) Ligand Embedded into Polysiloxane Gel : Application to a Reusable Copper Catalyst for Asymmetric Cyclopropanation2011

    • Author(s)
      Motoyama, Y.; Nishika ta, T.; Nagashima, H.
    • Organizer
      The Second International Symposium on Process Chemistry
    • Place of Presentation
      Kyoto
    • Year and Date
      20110000
  • [Presentation] ポリシロキサンゲル内包塩基複合型ロジウム触媒を用いたシリルカルボニル化反応2011

    • Author(s)
      鈴川喬之、本山幸弘、永島英夫
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      20110000
  • [Presentation] Catalytic Reactions in Metal-Encapsulated Polysiloxane Gels2009

    • Author(s)
      Motoyama, Y.; Yuasa, A.; Kamo, K.; Abe, M.; Kosako, Y.; Nagashima, H.
    • Organizer
      GelSympo
    • Place of Presentation
      Osaka
    • Year and Date
      20090000
  • [Presentation] Encapsulated MolecularCatalysts in Polysiloxane Gels : Copper/Bipyridine-Catalyzed Atom-Transfer Radical Cyclization2009

    • Author(s)
      Yuasa, A.; Kamo, K.; Motoyama, Y.; Nagashima, H.
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      Kyoto
    • Year and Date
      20090000
  • [Presentation] Catalysis in Polysiloxane Gel : Cu-Catalyzed Atom-Transfer Radical Cyclization ofα-Halogenated Acetamide Derivatives2009

    • Author(s)
      Yuasa, A.; Kamo, K.; Motoyama, Y.; Nagashima, H.
    • Organizer
      近畿化学会第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      20090000

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Published: 2013-07-31  

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