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2011 Fiscal Year Final Research Report

Functionalization of Pd and Ni catalysts with nanoporous structure

Research Project

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Project/Area Number 21605013
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Element strategy
Research InstitutionKyoto University (2010-2011)
National Institute of Advanced Industrial Science and Technology (2009)

Principal Investigator

HAKAMADA Masataka  京都大学, 大学院・エネルギー科学研究科, 助教 (30462849)

Co-Investigator(Kenkyū-buntansha) TAI Yutaka  産業技術総合研究所, サステナブルマテリアル研究部門, 研究グループ長 (20357338)
Project Period (FY) 2009 – 2011
Keywordsナノ材料 / 触媒・化学プロセス・希少資源
Research Abstract

Nanoporous Pd and Ni were successfully fabricated by dealloying(selective dissolution from binary alloys). The diffusion of nobler metals at alloy/electrolyte interface plays an important role in the formation of nanoporous structure ; the difference in the standard electrode potential does not always allow the dissolution of less noble element(and subsequent nanoporosity evolution). Also, catalytic properties of synthesized nanoporous Pd and Ni were evaluated.

  • Research Products

    (9 results)

All 2012 2011 2010 2009 Other

All Journal Article (3 results) (of which Peer Reviewed: 2 results) Presentation (5 results) Book (1 results)

  • [Journal Article] Solid/electrolyte interface phenomena during anodic polarization of Pd0. 2M0. 8(M=Fe, Co, Ni) alloys in H2SO42010

    • Author(s)
      M. Hakamada, K. Tajima, K. Yoshimura, Y. Chino, M. Mabuchi
    • Journal Title

      J. Alloy. Compd.

      Volume: 494 Pages: 309-314

    • DOI

      DOI:10.1016/j.jallcom.2010.01.019

  • [Journal Article] Catalytic decoloration of methyl orange solution by nanoporous metals

    • Author(s)
      M. Hakamada, F. Hirashima and M. Mabuchi
    • Journal Title

      Catal. Sci. Tech.

      Volume: (掲載可)

    • Peer Reviewed
  • [Journal Article] Fabrication microstructure and properties of nanoporous Pd

    • Author(s)
      M. Hakamada and M. Mabuchi
    • Journal Title

      Crit. Rev. Solid State Mater. Sci.

      Volume: (掲載可)

    • DOI

      DOI:10.1080/10408436.2012.674985

    • Peer Reviewed
  • [Presentation] ナノポーラス金属によるメチルオレンジ水溶液の脱色2012

    • Author(s)
      袴田昌高、平嶋芙美、馬渕守
    • Organizer
      日本金属学会2012年春期(第150回)大会
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-29
  • [Presentation] 矩形高周波電解によるパラジウム表面へのナノポーラス構造形成2011

    • Author(s)
      袴田昌高、馬渕守
    • Organizer
      日本金属学会2011年秋期(第149回)大会
    • Place of Presentation
      宜野湾
    • Year and Date
      2011-11-07
  • [Presentation] Less noble nanoporous metals fabricated by dealloying2011

    • Author(s)
      M. Hakamada, M. Takahashi, T. Yamamoto, J. Motomura and M. Mabuchi
    • Organizer
      7th International Conference on Porous Metals and Metallic Foams
    • Place of Presentation
      釜山(韓国)
    • Year and Date
      2011-09-20
  • [Presentation] ナノポーラスPdのCO酸化特性2010

    • Author(s)
      袴田昌高、山本太応、古川敏之、高橋真生、平嶋芙美、多井豊、千野靖正、馬渕守
    • Organizer
      日本金属学会2010年秋期(第147回)大会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-25
  • [Presentation] ポーラス構造体の機能性開拓2009

    • Author(s)
      袴田昌高、中野裕美、馬渕守、金属ナノ
    • Organizer
      日本金属学会・第4回機能性ポーラス材料研究会
    • Place of Presentation
      京都京都
    • Year and Date
      2009-09-16
  • [Book] マクロおよびナノポーラス金属の開発最前線(第4章2節脱合金化によるナノポーラス金属の創製)2011

    • Author(s)
      袴田昌高、馬渕守
    • Total Pages
      255-232

URL: 

Published: 2013-07-31  

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