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2011 Fiscal Year Final Research Report

Chemical synthesis of graphene model molecules with atomic defects

Research Project

  • PDF
Project/Area Number 21685005
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionTohoku University

Principal Investigator

ISOBE Hiroyuki  東北大学, 大学院・理学研究科, 教授 (30302805)

Project Period (FY) 2009 – 2011
Keywordsπスタック / クリセン / 多環式芳香族化合物 / 有機エレクトロニクス
Research Abstract

Recently, the studies for bottom-up production of discrete large π-conjugated molecules are focused much attention. In this research, we designed and synthesized new π-conjugated molecules inspired by new π-conjugated molecular species, "graphene with atomic defects", which had been found by electronic microscope analysis.

  • Research Products

    (33 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (15 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] 2,11-Dibromo-5,8-dibutyl[4]helicene2012

    • Author(s)
      Isobe, H.; Matsuno, T.; Hitosugi, S.; Nakanishi, W. Acta Crystallogr.
    • Journal Title

      Sect. E: Struct. Rep. Online

      Volume: E68 (4) Pages: o1239

    • DOI

      doi:10.1107/S1600536812013141

    • Peer Reviewed
  • [Journal Article] Atropisomerism in a belt-persistent nanohoop molecule: Rotational restriction forced by macrocyclic ring strain2012

    • Author(s)
      Hitosugi, S.; Nakanishi, W.; Isobe, H
    • Journal Title

      Chem. Asian J

      Volume: 7 (7) Pages: 1550-1552

    • DOI

      doi:10.1002/asia.201200187

    • Peer Reviewed
  • [Journal Article] Synthesis of disilanyl double-pillared bisdibenzofuran with a high triplet energy2012

    • Author(s)
      Nakanishi, W.; Shimada, Y.; Taka, H.; Kita, H.; Isobe, H
    • Journal Title

      Org. Lett

      Volume: 14 (6) Pages: 1636-1639

    • DOI

      doi:10.1021/ol3003964

    • Peer Reviewed
  • [Journal Article] Iridium-catalyzed direct borylation of phenacenes2012

    • Author(s)
      Hitosugi, S.; Nakamura, Y.; Matsuno, T.; Nakanishi, W
    • Journal Title

      Isobe, H. Tetrahedron Lett

      Volume: 53 (9) Pages: 1180-1182

    • DOI

      doi:10.1016/j.tetlet.2011.12.106

    • Peer Reviewed
  • [Journal Article] Bottom-up synthesis of finite models of helical (n,m)-single-wall carbon nanotubes2011

    • Author(s)
      Hitosugi, S.; Nakanishi, W.; Yamasaki, T.; Isobe, H
    • Journal Title

      Nat. Commun

      Volume: 2 (10) Pages: (5)

    • DOI

      doi:10.1038/ncomms1505

    • Peer Reviewed
  • [Journal Article] [6]Cyclo-2,7-naphthylene: A redetermination2011

    • Author(s)
      Nakanishi, W.; Xue, J. Y.; Yoshioka, T.; Isobe, H
    • Journal Title

      Acta Crystallogr., Sect. E: Struct. Rep. Online

      Volume: E67 (7) Pages: o1762-o1763

    • DOI

      doi:10.1107/S1600536811023427

    • Peer Reviewed
  • [Journal Article] Illusory molecular expression of "Penrose stairs" by an aromatic hydrocarbon2011

    • Author(s)
      Nakanishi, W.; Matsuno, T.; Ichikawa, J
    • Journal Title

      Isobe, H. Angew. Chem. Int. Ed

      Volume: 50 (27) Pages: 6048-6051

    • DOI

      doi:10.1002/anie.201102210

    • Peer Reviewed
  • [Journal Article] [n]Cyclo-2,7-naphthylenes: Synthesis and isolation of macrocyclic aromatic hydrocarbons having bipolar carrier transport ability2011

    • Author(s)
      Nakanishi, W.; Yoshioka, T.; Taka, H.; Xue, J. Y.; Kita, H.; Isobe, H
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 50 (23) Pages: 5323-5326

    • DOI

      doi:10.1002/anie.201101314

    • Peer Reviewed
  • [Journal Article] Electron mobility in a mercury-mediated duplex of triazole-linked DNA (TLDNA)2011

    • Author(s)
      Isobe, H.; Yamazaki, N.; Asano, A.; Fujino, T.; Nakanishi, W.; Seki, S
    • Journal Title

      Chem. Lett

      Volume: 40 (3) Pages: 318-319

    • DOI

      doi:10.1246/cl.2011.318

    • Peer Reviewed
  • [Journal Article] Double-pillaring strategy forsilacyclophanes: Synthesis and structures of disilanyl double-pillared bisanthracenes2011

    • Author(s)
      Nakanishi,W.; Hitosugi, S.; Shimada, Y.; Isobe, H
    • Journal Title

      Chem. Asian J

      Volume: 6 (2) Pages: 554-559

    • DOI

      doi:10.1002/asia.201000543

    • Peer Reviewed
  • [Journal Article] 1,8-Diiodoanthrancene2010

    • Author(s)
      Nakanishi, W.; Hitosugi, S.; Piskareva, A.; Isobe, H
    • Journal Title

      Acta Crystallogr., Sect. E: Struct. Rep. Online

      Volume: E66 (10) Pages: o2515

    • DOI

      doi:10.1107/S1600536810035191

    • Peer Reviewed
  • [Journal Article] Disilanyl double-pillared bisanthracene: A bipolar carrier transport material for organic light emitting diode devices2010

    • Author(s)
      Nakanishi, W.; Hitosugi, S.; Piskareva, A.; Shimada, Y.; Taka, H.; Kita, H.; Isobe, H
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 49 (40) Pages: 7239-7242

    • DOI

      doi:10.1002/anie.201002432

    • Peer Reviewed
  • [Journal Article] Nanometer-size fluorous fullerene vesicles in water and on solid surfaces2010

    • Author(s)
      Homma, T.; Harano, K.; Isobe, H.; Nakamura, E
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 49 (9) Pages: 1665-1668

    • DOI

      doi:10.1002/anie.200904659

    • Peer Reviewed
  • [Journal Article] In vivo gene delivery by cationic tetraamino fullerene2010

    • Author(s)
      Maeda-Mamiya, R.; Noiri, E.; Isobe, H.; Nakanishi, W.; Okamoto, K.; Doi, K.; Sugaya, T.; Izumi, T.; Homma, T.; Nakamura, E
    • Journal Title

      Proc. Natl. Acad. Sci., U.S.A.

      Volume: 107 (12) Pages: 5339-5344

    • DOI

      doi:10.1073/pnas.0909223107

    • Peer Reviewed
  • [Journal Article] Concise synthesis of halogenated chrysenes ([4]phenacenes) that favor π-stack packing in single crystals2009

    • Author(s)
      Isobe, H.; Hitosugi, S.; Matsuno, T.; Iwamoto, T.; Ichikawa, J
    • Journal Title

      Org. Lett

      Volume: 11 (17) Pages: 4026-4028

    • DOI

      doi:10.1021/ol901693y

    • Peer Reviewed
  • [Presentation] ジシラン二重架橋によるカルバゾール二量体の合成2013

    • Author(s)
      鎌田翔,中西和嘉,磯部寛之
    • Organizer
      日本化学会第93回春季年会3A3-50
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-24
  • [Presentation] ジシラン二重架橋によるカルバゾール二量体の合成2012

    • Author(s)
      鎌田翔,中西和嘉,磯部寛之
    • Organizer
      第23回基礎有機化学討論会1P086
    • Place of Presentation
      京都
    • Year and Date
      2012-09-19
  • [Presentation] らせん型最短カーボンナノチューブのボトムアップ化学合成2012

    • Author(s)
      一杉俊平,中西和嘉,山崎孝史,磯部寛之
    • Organizer
      第23回基礎有機化学討論会A07
    • Place of Presentation
      京都
    • Year and Date
      2012-09-19
  • [Presentation] らせん型最短ナノチューブのボトムアップ化学合成2012

    • Author(s)
      一杉俊平,中西和嘉,山崎孝史,磯部寛之
    • Organizer
      第43回フラーレン・ナノチューブ・グラフェン総合シンポジウム1P-31
    • Place of Presentation
      仙台
    • Year and Date
      2012-09-05
  • [Presentation] "Illusory molecular expression of"Penrose stairs" by an aromatic hydrocarbon and dynamic behaviors in solution"2012

    • Author(s)
      Matsuno, T.; Nakanishi, W.; Ichikawa, J.; Isobe, H
    • Organizer
      The Campus Asia Summer School 2012 (O-18)
    • Place of Presentation
      仙台
    • Year and Date
      2012-08-22
  • [Presentation] らせん型最短ナノチューブのボトムアップ化学合成2012

    • Author(s)
      一杉俊平,中西和嘉,山崎孝史,磯部寛之
    • Organizer
      日本化学会第92春期年会4E1-25
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-28
  • [Presentation] 錯視的構造を有する環状多環式芳香族化合物の合成と溶液中での動的挙動2012

    • Author(s)
      松野太輔,中西和嘉,市川淳士,磯部寛之
    • Organizer
      日本化学会第92回春季年会3K2-03
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-27
  • [Presentation] シクロ-2,7-ナフチレン:合成と有機ELキャリア輸送層への応用2011

    • Author(s)
      Xue Jing,中西和嘉,吉岡知昭,高秀雄,北弘志,磯部寛之
    • Organizer
      第22回基礎有機化学討論会1P124
    • Place of Presentation
      筑波
    • Year and Date
      2011-09-21
  • [Presentation] シクロ-2,7-ナフチレン:合成と有機ELキャリア輸送層への応用2011

    • Author(s)
      Xue Jing,中西和嘉,吉岡知昭,高秀雄,北弘志,磯部寛之
    • Organizer
      平成23年度化学系学協会東北大会1P087
    • Place of Presentation
      仙台
    • Year and Date
      2011-09-18
  • [Presentation] ジシラニル二重架橋ビスアントラセン:OLEDにおける両極性キャリア輸送材料2011

    • Author(s)
      一杉俊平,中西和嘉,アンナピスカリョーバ,嶋田裕亮,高秀雄,北弘志,磯部寛之
    • Organizer
      日本化学会第91春期年会1E5-28
    • Place of Presentation
      日本化学会第91春期年会(2011)講演予稿集
    • Year and Date
      2011-03-11
  • [Presentation] [4]ヘリセン環状二量体の合成と構造2010

    • Author(s)
      松野太輔,中西和嘉,磯部寛之
    • Organizer
      平成22年度化学系学協会東北大会1P057
    • Place of Presentation
      盛岡
    • Year and Date
      2010-09-26
  • [Presentation] ジシラニル二重架橋ビスアントラセン:OLEDにおける両極性キャリア輸送材料2010

    • Author(s)
      一杉俊平,中西和嘉,アンナピスカリョーバ,嶋田裕亮,高秀雄,北弘志,磯部寛之
    • Organizer
      第21回基礎有機化学討論会A31
    • Place of Presentation
      名古屋
    • Year and Date
      2010-09-11
  • [Presentation] [4]ヘリセン環状二量体の合成と構造2010

    • Author(s)
      松野太輔,中西和嘉,磯部寛之
    • Organizer
      高次π空間の創発と機能開発第2回若手研究会
    • Place of Presentation
      筑波
    • Year and Date
      2010-07-15
  • [Presentation] πスタック型結晶構造をもつクリセン誘導体の合成法の開発2010

    • Author(s)
      一杉俊平,松野太輔,岩本武明,市川淳士,磯部寛之
    • Organizer
      日本化学会第90春期年会4G1-05
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-29
  • [Presentation] πスタック型結晶構造をもつクリセン誘導体の合成法の開発2009

    • Author(s)
      一杉俊平,松野太輔,岩本武明,市川淳士,磯部寛之
    • Organizer
      平成21年度化学系学協会東北大会3P044
    • Place of Presentation
      福島
    • Year and Date
      2009-09-21
  • [Remarks]

    • URL

      http://www.orgchem2.chem.tohoku.ac.jp/

  • [Patent(Industrial Property Rights)] 有機エレクトロニクス素子用材料,有機エレクトロニクス素子,照明装置,表示装置及び有機薄膜太陽電池素子2011

    • Inventor(s)
      高秀雄,北弘志,磯部寛之,一杉俊平,中西和嘉
    • Industrial Property Rights Holder
      コニカミノルタホールディングス株式会社
    • Industrial Property Number
      特許国際公開 WO 2011/132493 A1
    • Filing Date
      2011-03-24
    • Overseas
  • [Patent(Industrial Property Rights)] 縮退系大環状化合物、並びに、その結晶及び製造方法2010

    • Inventor(s)
      磯部寛之 ・中西和嘉・吉岡知昭
    • Industrial Property Rights Holder
      国立大学法人東北大学
    • Industrial Property Number
      特許公開 2012-121861
    • Filing Date
      2010-12-10

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Published: 2014-08-29  

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