2010 Fiscal Year Final Research Report
Organic and catalysis chemistry based on low-valent boron compounds
| Project/Area Number |
21685006
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Chuo University (2010)
The University of Tokyo (2009) |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2010
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| Keywords | 有機元素化学 / ラジカル / 触媒 |
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| Research Abstract |
This research project has achieved the followings. (1) Exploration of chemistry of boryl anion, especially for the formation of boron-containing chemical bond with second-row p-block elements, and application of the resulting products for organic syntheses. (2) Attempt to synthesize boron-centered radical and low-oxidation state boron compound, borylene, and confirmation of photo-activated boryl radical species. (3) Syntheses and properties of transition-metal complexes bearing a boron-containing multidentate ligand and their application to catalysis.
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[Journal Article] Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions2010
Author(s)
Nozaki, K.; Aramaki, Y.; Yamashita, M.; Ueng, S.-H.; Malacria, M.; Lacote, E.; Curran, D. P.
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Journal Title
J. Am. Chem. Soc.
Volume: 132
Pages: 11449-11451
Peer Reviewed
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