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2011 Fiscal Year Final Research Report

Molecular characterization of non-equilibrium polymer solutions studied under a temperature gradient as an external field

Research Project

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Project/Area Number 21685026
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionTokai University

Principal Investigator

KITA Rio  東海大学, 理学部, 准教授 (90322700)

Project Period (FY) 2009 – 2011
Keywords高分子溶液 / 非平衡熱力学 / 輸送係数 / 温度勾配 / ルードヴィッヒ・ソレー効果
Research Abstract

We have studied the Ludwig-Soret effect, which means the development of the concentration gradient due to the applied stable temperature gradient, for polymer solutions in order to obtain deeper understandings for the molecular mechanisms of the Ludwig-Soret effect. This research project aims to contribute to develop non-equilibrium thermodynamics and polymer physics. We have selected several water-soluble polymers systematically to reveal the effects of molecular interactions through hydrogen bonds. The experimental studies has been carried out by means of thermal diffusion forced Rayleigh scattering. Additionally, the project has revealed a new insight about the research field of life science due to systematic studies on biological macromolecules under the non-equilibrium conditions.

  • Research Products

    (17 results)

All 2012 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 7 results) Presentation (4 results) Remarks (2 results)

  • [Journal Article] Molecular Dynamics of Poly(N-isopropylacrylamide) in Protic and Aprotic Solvents Studied by Dielectric Relaxation Spectroscopy2012

    • Author(s)
      S. Nakano, Y. Sato, R. Kita, N. Shinyashiki, S. Yagihara, S. Sudo and M. Yoneyama
    • Journal Title

      Journal of Physical Chemistry

      Volume: B 116 Pages: 775-781

    • Peer Reviewed
  • [Journal Article] 水分子をプローブとする物質・生体の評価手法2012

    • Author(s)
      八木原晋, 新屋敷直木, 喜多理王
    • Journal Title

      ケミカルエンジニアリング

      Volume: 57 Pages: 17-23

  • [Journal Article] Segmental Relaxation of Hydrophilic Poly(vinylpyrrolidone) in Chloroform Studied by Broadband Dielectric Spectroscopy2011

    • Author(s)
      N. Shinyashiki, A. Spanoudaki, W. Yamamoto, E. Nambu, K. Yoneda, A. Kyritsis, P. Pissis, R. Kita and S. Yagihara
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 2140-2148

    • Peer Reviewed
  • [Journal Article] Thermoreversible gelation of isotactic-rich poly(N-isopropylacrylamide) in water2011

    • Author(s)
      S. Nakano, T. Ogiso, R. Kita, N. Shinyashiki, S. Yagihara, M. Yoneyama and Y. Katsumoto
    • Journal Title

      Journal of Chemical Physics

      Volume: 135(11) Pages: 114903

    • Peer Reviewed
  • [Journal Article] 物質中のダイナミックな水構造の直接観測(広帯域誘電分光からわかってきたこと)2011

    • Author(s)
      八木原晋, 新屋敷直木, 喜多理王
    • Journal Title

      日本バイオレオロジー学会誌電子版

      Volume: 25 Pages: 2-11

  • [Journal Article] Dynamics of Polymer and Glass Transition in Partially Crystallized Polymer Solution Studied by Dielectric Spectroscopy2010

    • Author(s)
      N. Shinyashiki, M. Asano, M. Shimomura, S. Sudo, R. Kita and S. Yagihara
    • Journal Title

      Journal of Biomaterials Science-Polymer Edition

      Volume: 21(14) Pages: 1937-1946

    • Peer Reviewed
  • [Journal Article] Temperature Dependence of Soret Coefficient in Aqueous and Nonaqueous Solutions of Pullulan2010

    • Author(s)
      Y. Kishikawa, S. Wiegand and R. Kita
    • Journal Title

      Biomacromolecules

      Volume: 11(3) Pages: 740-747

    • Peer Reviewed
  • [Journal Article] Dielectric study of liposome dispersion using statistical analysis of jitter2010

    • Author(s)
      Y. Hosoi, R. Kita, N. Shinyashiki, and S. Yagihara
    • Journal Title

      Trans. Materials Research Society of Japan

      Volume: 35(4) Pages: 861-864

    • Peer Reviewed
  • [Journal Article] ソフトマテリアルの熱誘起分子拡散のレーザー計測2010

    • Author(s)
      岸川友貴, 喜多理王
    • Journal Title

      レーザー研究

      Volume: 38 Pages: 106-112

  • [Journal Article] Glass Transitions in Aqueous Solutions of Protein(Bovine Serum Albumin)2009

    • Author(s)
      N. Shinyashiki, W. Yamamoto, A. Yokoyama, T. Yoshinari, S. Yagihara, R. Kita, K. L. Ngai and S. Capaccioli
    • Journal Title

      Journal of Physical Chemistry

      Volume: B 113(43) Pages: 14448-14456

    • Peer Reviewed
  • [Journal Article] 高分子中で水はどのように振る舞うか2009

    • Author(s)
      八木原晋, 新屋敷直木, 喜多理王
    • Journal Title

      高分子学会誌

      Volume: 58 Pages: 65-69

  • [Presentation] レーザー散乱による高分子鎖と溶媒分子の熱拡散計測2012

    • Author(s)
      喜多理王
    • Organizer
      第12回レーザー学会東京支部研究会電気学会光・量子デバイス技術研究会
    • Place of Presentation
      東海大学高輪校舎(品川区)
    • Year and Date
      2012-03-06
  • [Presentation] 高分子水溶液の温度勾配下の輸送現象(ルードヴィッヒ・ソレー効果)と相互作用の解析2011

    • Author(s)
      喜多理王
    • Organizer
      高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-30
  • [Presentation] 温度勾配下での分子の不可逆的輸送現象の解析-生体高分子の異常拡散について-2011

    • Author(s)
      喜多理王
    • Organizer
      東海大学医学部特別セミナー
    • Place of Presentation
      東海大学伊勢原校舎(神奈川県伊勢原市)
    • Year and Date
      2011-06-28
  • [Presentation] 光散乱法による高分子とゲルの分子ダイナミクス2010

    • Author(s)
      喜多理王
    • Organizer
      日本バイオレオロジー学会,バイオレオロジーリサーチフォーラム
    • Place of Presentation
      慶応大学(横浜市)
    • Year and Date
      2010-03-13
  • [Remarks]

    • URL

      http://www.sp.u-tokai.ac.jp/kita_lab/index.html

  • [Remarks]

    • URL

      http://www.sp.u-tokai.ac.jp/~rgms/

URL: 

Published: 2013-07-31  

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