2010 Fiscal Year Final Research Report
Development of electron-accepting conjugated molecules densely-substituted with boron atoms
| Project/Area Number |
21750037
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
AGOU Tomohiro Kyoto University, 次世代開拓研究ユニット, 助教 (90466798)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 有機ホウ素化合物 / ボラアセン / 電子受容体 / アニオンセンシング |
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| Research Abstract |
Synthesis of functional hetero-π-conjugated molecules by taking advantage of electron-withdrawing property and Lewis acidity of boron was investigated for the development of electron-transporting material and anion sensors. Fluorescence molecular sensors for biologically active anions, such as fluoride and cyanide ions, were developed using a dibenzoazaborine framework. The synthesis of electron-accepting conjugated molecules based on oligoacene-like frameworks substituted with boron atoms was investigated. The electron-accepting and anion-complexation abilities of a 9,10-dihydro-9,10-diboraanthracene were elucidated.
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[Journal Article] Assembling N,P,N Pincers for Coordination-Driven Synthesis of Supramolecular [2,2]Paracyclophane2011
Author(s)
Ana Isabel Aranda Perez, Thomas Biet, Sebastien Graule, Tomohiro Agou, Christophe Lescop, Neil R. Branda, Jeanne Crassous, Regis Reau
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Journal Title
Chemistry A European Journal 17
Pages: 1337-1351
Peer Reviewed
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