2010 Fiscal Year Final Research Report
Excited Charge Transfer Complex : Effect of Irradiation Wavelength on Asymmetric Photochemistry
| Project/Area Number |
21750044
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
MORI Tadashi Osaka University, 工学研究科, 准教授 (70311769)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 励起波長効果 / エキシプレックス / 温度効果 / 不斉光反応 / 励起CT錯体 / Paterno-Buchi反応 / 温度効果 / エントロピー・エンタルピー |
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| Research Abstract |
Effect of excitation wavelength on the asymmetric photoreaction of some donor-acceptor complexes has been studied. The diastereoselectivitives observed upon selective excitation at the charge transfer (CT) band are different from those obtained with direct excitation of donor or acceptor molecule. It turned out that both the ground and excited states' interactions are crucial for controlling stereochemical outcomes
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[Journal Article] Diastereodifferentiating the [2+2] Photocycloaddition of Ethylene to Aryl- menthyl Cyclohexenonecarboxylates : Stacking-Driven Enhancement of the Product Diastereoselectivity That Is Correlated with the Reactant Ellipticity.2010
Author(s)
Tsutsumi, K., Yanagisawa, Y., Furutani, A., Morimoto, T., Kakiuchi, K., Wada, T., Mori, T., Inoue, Y.
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Journal Title
Chem.Eur.J. 16(25)
Pages: 7448-7455
Peer Reviewed
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[Journal Article] Critical stereocontrol by inter-amino distance of supramolecular photocyclodimerization of 2-anthracenecarboxylate mediated by 6-(ω-aminoalkylamino)-γ-cyclodextrins.2010
Author(s)
Ke, C., Yang, C., Liang, W., Mori, T., Liu, Y., Inoue, Y.
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Journal Title
New J.Chem. 234(7)
Pages: 1323-1329
Peer Reviewed
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[Journal Article] Dual Chiral, Dual Supramolecular Diastereodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate Tethered to Amylose Scaffold.2010
Author(s)
Fukuhara, G., Nakamura, T., Yang, C., Mori, T., Inoue, Y.
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Journal Title
Org.Lett. 12(15)
Pages: 3510-3513
Peer Reviewed
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[Journal Article] Bio-supramolecular photochirogenesis with molecular chaperone : enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin.2010
Author(s)
Bando, K., Zako, T., Sakono, M., Maeda, M., Wada, T., Nishijima, M., Fukuhara, G., Yang, C., Mori, T., Pace, T.C.S., Bohne, C., Inoue, Y.
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Journal Title
Photochem. Photobiol. Sci. 9(5)
Pages: 655-660
Peer Reviewed
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[Journal Article] Supramolecular complexation of N-alkyland N, N'-dialkylpiperazines with cucurbit [6] uril in aqueous solution and in the solid state.2009
Author(s)
Rekharsky, M.V., Yamamura, H., Mori, T., Sato, A., Shiro, M., Lindeman, S.V., Rathore, R., Shiba, K., Ko, Y.H., Selvapalam, N., Kim, K., Inoue, Y.
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Journal Title
Chem.Eur.J. 15(8)
Pages: 1957-1965
Peer Reviewed
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[Journal Article] Catalytic Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylic Acid Mediated by a Non-Sensitizing Chiral Metallosupramolecular Host.2009
Author(s)
Ke, C., Yang, C., Mori, T., Wada, T., Liu, Y., Inoue, Y.
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Journal Title
Angew.Chem., Int.Ed. 48(36)
Pages: 6675-6677
Peer Reviewed
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[Journal Article] Supramolecular complexation and enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid with 4-aminoprolinol derivatives as chiral hydrogen-bonding templates.2009
Author(s)
Kawanami, Y., Pace, T. C. S., Mizoguchi, J.-i., Yanagi, T., Nishijima, M., Mori, T., Wada, T., Bohne, C., Inoue, Y.
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Journal Title
J.Org.Chem. 74(20)
Pages: 7908-7921
Peer Reviewed
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[Presentation] Effect of Wavelength and Confinement on the Diastereoselective Photoreaction of 1, 1-Dicyano-2-methyl-4-phenyl-1-pentene2010
Author(s)
Mori, T., Nishiuchi, E., Matsumura, K., Saito, H., Inoue, Y.
Organizer
第5回分子情報ダイナミクス研究会
Place of Presentation
大阪大学銀杏会館
Year and Date
20100329-20100330
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