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2010 Fiscal Year Final Research Report

Development of Synthetic Method of Rotaxane Incorporated with SPM toward Constructing Functional Molecules

Research Project

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Project/Area Number 21750050
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionTokyo University of Science

Principal Investigator

YAMASAKI Ryu  Tokyo University of Science, 理学部, 助教 (90453844)

Project Period (FY) 2009 – 2010
Keywords超分子化学 / ナノ材料 / 分子機械 / 有機金属化学
Research Abstract

Rotaxane is one of the interlocked compound which composed with macrocycle and axis which is inseparable without breaking bonds. To functionalize these interlocked molecules, I envisioned to use a stiff macrocycle, SPM, as the macrocycle. As a result, I succeeded to synthesize the unsymmetrical SPM molecule and attempted to prepare rotaxane via reaction mediated by this macrocycle.

  • Research Products

    (34 results)

All 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 10 results) Presentation (21 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Synthesis and Structure of Dinuclear Silver (I) and Palladium (II) Complexe of 2,7-Bis(methylene) naphthalene-Bridged Bis-N-Heterocyclic Carbene Ligands2011

    • Author(s)
      Shinichi Saito, Mitsuya Saika, Ryu Yamasaki, Isao Azumava, Hvuma Masu.
    • Journal Title

      Organometallics 30巻

      Pages: 1366-1373

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Silver and Palladium Complexes with Xanthene Based N-Heterocyclic Carbene-Oxazoline Ligands2010

    • Author(s)
      Takeshi Makino, Ryu Yamasaki, Isao Azumaya, Hyuma Masu, Shinichi Saito
    • Journal Title

      Organometallics 29巻

      Pages: 6291-6297

    • Peer Reviewed
  • [Journal Article] 環をつかった化学のマジック2010

    • Author(s)
      山崎龍、斎藤慎一
    • Journal Title

      化学 65巻

      Pages: 72-73

  • [Journal Article] Ring expansion reactions of ethyl cyclopropylideneacetate and benzosila- cyclobutenes: formal σ bond cross metathesis2010

    • Author(s)
      Shinichi Saito, Takahiro Yoshizawa, Shinya Ishigami, Rvu Yamasaki
    • Journal Title

      Tetrahedron Letters 51巻

      Pages: 6028-6030

    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed [3+2+2] Cycloaddition of Ethyl Cyclopropylidene- acetate and Heteroatom-Substituted Alkynes : Application to Selective Three-Component Reaction with 1,3- Diynes2010

    • Author(s)
      Ryu Yamasaki, Natsuki Terashima, Ikuo Sotome, Shunsuke Komagawa, Shinchi Saito
    • Journal Title

      Journal of Organic Chemistry 75巻

      Pages: 480-483

    • Peer Reviewed
  • [Journal Article] Selective Synthesis of Eight-membered Cyclic Ureas by the [6+2] Cycloaddition Reaction of 2-Vinyl- azetidines and Electron-Deficient Isocyanates2010

    • Author(s)
      Shunsuke Koya, Kenichi Yamanoi, Ryu Yamasaki, Isao Azumaya, Hyuma Masu, Shinichi Saito
    • Journal Title

      Organic Letters 11巻

      Pages: 5438-5441

    • Peer Reviewed
  • [Journal Article] Thermal and catalytic isomerization of exomethylenecycloheptadienes. Experimental and theoretical studies.2010

    • Author(s)
      Yukiko Fukusaki, Jun Miyazaki, Isao Azumaya, Kosuke Katagiri, Shunsuke, Komagawa, Ryu Yamasaki, Shinichi Saito.
    • Journal Title

      Tetrahedron 65巻

      Pages: 10631-10636

    • Peer Reviewed
  • [Journal Article] Synthesis of Nine-membered Carbocycles by the [4 + 3 + 2] Cycloaddition Reactn of Ethyl Cyclopropylideneacetate and Dienynes2009

    • Author(s)
      Shinichi Saito, Kyotaro Maeda, Ryu Yamasaki, Takuya Kitamura, Minami Nakagawa, Korehito Kato, Isao Azumaya, Hyuma Masu
    • Journal Title

      Angewandte Chemie-International Edition. 49巻

      Pages: 1830-1833

    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Intermolecular [3 + 2 + 2] Cocyclization of Ethyl Cyclopropylidene- acetate and Alkynes.2009

    • Author(s)
      Shinsuke Komagawa, Kouhei Takeuchi, Ikuo Sotome, Isao Azumaya, Hyuma Masu, Ryu Yamasaki, Shinichi Saito.
    • Journal Title

      Synthesis of Seven-Membered Carbocycles、Journal of Organic Chemistry. 74巻

      Pages: 3323-3329

    • Peer Reviewed
  • [Journal Article] Synthesis, Structure and Catalytic Activity of Macrocyclic NHC Pd Pincer Complexes2009

    • Author(s)
      Noriaki Watarai, Hiroyasu Kawasaki, Isao Azumaya, Ryu Yamasaki, Shinichi Saito
    • Journal Title

      HETEROCYCLES 79巻

      Pages: 531-548

    • Peer Reviewed
  • [Journal Article] Ni-catalyzed [3+2+2] cycloaddition of ethyl cyclopropylidene- acetate and 1,3-diynes. Application to the three-component cycloaddition.2009

    • Author(s)
      Ryu Yamasaki, Ikuo Sotome, Shunsuke Komagawa, Isao Azumaya, Hyuma Masu, Shinichi Saito
    • Journal Title

      Tetrahedron Letters. 50巻

      Pages: 1143-1145

    • Peer Reviewed
  • [Presentation] [4+3+2]型環化付加反応におけるアミド結合を有するジエンインの配座と収率の関係2011

    • Author(s)
      藤田哲嗣・中川みなみ・山崎龍・斉藤慎一
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      20110300
  • [Presentation] 効率的な金属配位可能なSPM合成法開発と触媒反応への応用2011

    • Author(s)
      山崎龍・重藤敦嗣・斎藤慎一
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      20110300
  • [Presentation] 芳香族ビニログ性アミドの合成と物性2011

    • Author(s)
      池田宏和・山崎龍・桝飛雄真・東屋功・斎藤慎一
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      20110300
  • [Presentation] フェナントロリン-銅錯体を反応活性体として利用したインターロック化合物の合成研究2011

    • Author(s)
      山崎龍、佐藤雄太、高橋英子、中薗和子、斎藤慎一
    • Organizer
      第11回リング・チューブ超分子研究会シンポジウム
    • Place of Presentation
      東京工業大学
    • Year and Date
      20110300
  • [Presentation] Synthesis of medium-sized rings by the Ni-catalyzed cycloaddition reactions2010

    • Author(s)
      Ryu Yamasaki, Shinichi Saito
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイ
    • Year and Date
      20101200
  • [Presentation] Synthesis of monocyclic compounds by the nickel-catalyzed [4+3+2] cycloaddition2010

    • Author(s)
      Korehito Kato, Ryu Yamasaki, Shinichi Saito
    • Organizer
      2010 International Chemal Congress of Pacifc Basin Societies
    • Place of Presentation
      ハワイ
    • Year and Date
      20101200
  • [Presentation] Synthesis and catalytic activit of pyridine-incorporated SPM-metal complex2010

    • Author(s)
      Atsushi Shigeto, Shinchi Saito, Ryu Yamasaki
    • Organizer
      2010 International Chemical Congss of Pacific Basin Soeties
    • Place of Presentation
      ハワイ
    • Year and Date
      20101200
  • [Presentation] Synthesis of seven-menbered cyclic ureas by the [5+2] cycloaddition reaction of 2-vinylaziridines and electron-deficient isocyanates2010

    • Author(s)
      Eri Kanno, Shunsuke Koya, Kenichi Yamanoi, Ryu Yamasaki, Shinichi Saito
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイ
    • Year and Date
      20101200
  • [Presentation] Synthesis of interlocked compounds by the reaction of macrocycle-metal complexes2010

    • Author(s)
      Ryu Yamasaki, Shinichi Saito.
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイ
    • Year and Date
      20101200
  • [Presentation] [5+2] Cycloaddition Reaction of 2-Vinylaziridines and Electron-deficient Isocyanes : the Efct of the Stereochemistry on the Reaction2010

    • Author(s)
      Eri Kanno, Shunsuke Koya, Kenichi Yamanoi, Ryu Yamasaki, Shinichi Saito
    • Organizer
      8th Symposium on Chemial Apprchesto Chirality
    • Place of Presentation
      東京理科大学
    • Year and Date
      20101200
  • [Presentation] ビニルアジリジンと電子欠乏性イソシアネートとの[5+2]環化付加反応2010

    • Author(s)
      管野恵理、山野井健一、小矢俊亮、山崎龍、斎藤慎一
    • Organizer
      第36回反応と合成の進歩シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      20101100
  • [Presentation] Diastereoselective Ni-Catalyzed [4+3+2] Cocyclization Reaction between Dienyne and Methylenecyclopropane2010

    • Author(s)
      Ryu Yamasaki, Takuya Kitamura, Kyotaro Maeda, Minami Nakagawa, Korehito Kato, Masu Hyuma, Isao Azumaya, Shinichi Saito
    • Organizer
      7th Symposium on Chemical Approaches to Chirality
    • Place of Presentation
      東京理科大学
    • Year and Date
      20100900
  • [Presentation] ニッケル触媒存在下におけるエチルシクリプロピリデンアセテートとベンゾシラシクロブテンの環拡大反応2010

    • Author(s)
      斎藤慎一、山崎龍、石神慎也、吉澤孝弘
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学
    • Year and Date
      20100900
  • [Presentation] Preparation of Interlocked Compounds by Macrocyclic Phenantroline-Cu Complees as the Platform of Coupling Reaction2010

    • Author(s)
      Ryu Yamasaki, Yuta Sato, Eiko Takahashi, Kazuko Nakazono, Shinichi Saito
    • Organizer
      Post 5th International Symposium on Macrocyclic and Supramolecular Chemistry & 第ホストゲスト化シンポジウム
    • Place of Presentation
      大阪
    • Year and Date
      20100600
  • [Presentation] Preparation of Interlocked Compounds by Macrocyclic Phenantroline-Cu Complees as the Platform of Coupling Reaction2010

    • Author(s)
      Ryu Yamasaki, Yuta Sato, Eiko Takahashi, Kazuko Nakazono, Shinichi Saito
    • Organizer
      5th International Symposium on Macrocyclic & Supramolecular Chemistry
    • Place of Presentation
      奈良
    • Year and Date
      20100600
  • [Presentation] Ni触媒によるジエンインとメチレンシクロプロパンとの[4+3+2]型環化付加反応:ジエンインの構造の重要性2010

    • Author(s)
      山崎龍、前田京太郎、北村卓也、中川みなみ、加藤惟人、桝飛雄真、東屋功、斉藤慎一
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      20100300
  • [Presentation] Ni触媒存在下における[4+3+2]型環化付加反応を利用した単環性9員環化合物の合成2010

    • Author(s)
      加藤惟人、山崎龍、斎藤慎一
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      20100300
  • [Presentation] Synthesis and Catalytic Activity of Macrocyclic BINOL Derivatives2009

    • Author(s)
      Natsuko Ichihara, Eiko Takahashi, Nobutaka Ueda, Ryu Yamasaki, Shinichi Saito
    • Organizer
      6th Symposium on Chemical Approaches to Chirality
    • Place of Presentation
      東京理大学
    • Year and Date
      20091100
  • [Presentation] ジエンインを用いた[4+3+2]型環化付加反応におけるジエン部位の置換基効果2009

    • Author(s)
      北村卓也, 前田京太郎, 山崎龍, 斎藤慎一, 桝飛雄真、東屋功
    • Organizer
      第35回反応と合成の進歩シンポジウム
    • Place of Presentation
      金沢
    • Year and Date
      20091100
  • [Presentation] Ni 触媒によるジエンインと電子欠乏性メチレンシクロプロパンとの間の[4+3+2]型環化付加反応2009

    • Author(s)
      山崎龍、前田京太郎、中川みなみ、北村卓也、加藤惟人、東屋功、桝飛雄真、斎藤慎一
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学
    • Year and Date
      20090900
  • [Presentation] Nickel-Catayzed [4+2] Cocyclization of Ethyl Cloprolideneacete Dienynes2009

    • Author(s)
      Shinichi Saito, Kyotaro Maeda, Ryu Yamasaki, Minami Nakagawa, Takuya Kitamura, Korehito Kato
    • Organizer
      15th IUPAC Symposium on Organomallic Chemistry directed trds Organic Sesis
    • Place of Presentation
      Glasow
    • Year and Date
      20090700
  • [Book] 化学事典(共著、共同編集)2010

    • Author(s)
      斎藤慎一, 山崎龍, 他
  • [Remarks]

    • URL

      http://www.sut.ac.jp/ridai/doc/ji/RIJIA01Detail.php?act=nam&kin=ken&diu=A21073

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Published: 2012-02-13   Modified: 2016-04-21  

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