2010 Fiscal Year Final Research Report
Synthesis, structure and aromatic properties of σ-bonded gallatabenzene complexes
| Project/Area Number |
21750056
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
MURAOKA Takako Gunma University, 大学院・工学研究科, 助教 (40400775)
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| Project Period (FY) |
2009 – 2010
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| Keywords | ガラタベンゼン錯体 / シグマ結合型 / ガラシクロペンタジエニル錯体 |
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| Research Abstract |
Attempts to the synthesis of σ-bonded gallacyclohexadienyliron and -tungsten complexes by the reactions of dichlorogallyliron or -tungsten complexes with dilithiodialkenyl derivatives or cyclic tin compounds were not successful. On the other hand, gallacyclopentadienyliron complexes were obtained by the transmetallation between dichlorogallyliron complex and cyclopentadienylzirconium compound.
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