2010 Fiscal Year Final Research Report
Synthesis of the Multinuclear Transition Metal Complexes with Mechanically Interlocked Flexible Structures and Its Application
| Project/Area Number |
21750058
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
SUZAKI Yuji Tokyo Institute of Technology, 資源化学研究所, 助教 (70436707)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 超分子化学 / ロタキサン / クラウンエーテル / パラジウム / 触媒 |
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| Research Abstract |
The facile macrocyclic compounds bearing palladium(II) were synthesized. The framework of macrocyclic compounds contain 18 carbon atoms and 6 oxygen atoms. The interlocked molecules composed of two macrocyclic molecules threaded by a liner molecule were employed as the bimetallic catalyst for the 1:1 cyclization reaction of difunctionalized substrates.
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