2010 Fiscal Year Final Research Report
Development of Catalyst Immobilized Micro Reactor for Combinatorial Multi Step Reactions
| Project/Area Number |
21750091
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
UENO Masaharu The University of Tokyo, 大学院・理学系研究科, 助教 (80361509)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 合成化学 / 触媒・化学プロセス / マイクロ・ナノデバイス / 酸化反応 |
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| Research Abstract |
We have developed a gold-immobilized micro capillary column reactor for the oxidation of alcohols with molecular oxygen. The oxidation of various alcohols proceeded easily to give the corresponding aldehydes and ketones in good to excellent yields. We also developed polymer immobilized chiral sulfoxide for allylation. Moreover, we have developed diastereoselective allylation of aldehydes and allenylation or propargylation of hydrazonoester in aqueous condition which applicable to microsystem.
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