2010 Fiscal Year Final Research Report
Reaction of Guanidinodiazonium Salt
| Project/Area Number |
21750105
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyushu Institute of Technology |
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Principal Investigator |
KITAMURA Mitsuru Kyushu Institute of Technology, 大学院・工学研究院, 准教授 (10313199)
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| Project Period (FY) |
2009 – 2010
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| Keywords | ジアゾ / アジド / ジアゾニウム塩 / アミノ化 / ジアゾナフトキノン / ジアゾ移動 / アジド移動 |
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| Research Abstract |
Guanidino diazonium salt having Cl^- as a counter anion was prepared by the reaction of 2-chloro-1,3-dimethylimidazolinium chloride (DMC) and sodium azide. The corresponding phosphate, was isolated as a crystal, and was found to be stable and safe reagent. Guanidino diazonium salts were found to have the abilities of diazo and azide transfer to various nucleophilic reagent.
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