2010 Fiscal Year Final Research Report
Multiple control of stereoregularity of acrylic block copolymers through stereospecificity transformation
| Project/Area Number |
21750125
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
KITAURA Takehiro Osaka University, 大学院・基礎工学研究科, 助教 (80452407)
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| Project Period (FY) |
2009 – 2010
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| Keywords | 立体特異性重合 / リビング重合 / アニオン重合 / ブロックポリマー / ステレオコンプレックス |
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| Research Abstract |
Synthetic methodology of structurally defined stereoblock (co)polymethacrylates was established. The stereoblock copolymer of butyl acrylate block, isotactic and syndiotactic methyl methacrylate blocks showed property of thermoplastic elastmer. Investigation of stereocomplexation of stereoblock copolymers in solution revealed that linear like supramolecular association was formed.
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