2011 Fiscal Year Final Research Report
Molecular approach to comprehend the tacticity effects on the interaction between polymer chain and water for acrylamide polymers
| Project/Area Number |
21750126
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Keywords | 高分子構造 |
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| Research Abstract |
Effects of stereoregularity on the interaction between acrylamide polymers and water have been investigated by infrared(IR) spectroscopy, quartz crystal microbalance(QCM), and molecular mechanics(MM) calculations. The IR spectroscopy and QCM method have revealed that the interaction between the polymer side chain and water is modified by the change of stereoregularity of polymer, which is caused by the balance between the intramolecular interaction of polymers and solvation as revealed by MM calculations
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