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2010 Fiscal Year Final Research Report

Fabrication of novel nanotube-based hybrid materials and development of characterization of their structure and properties

Research Project

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Project/Area Number 21750142
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionNagoya University

Principal Investigator

KITAURA Ryo  Nagoya University, 理学研究科, 准教授 (50394903)

Project Period (FY) 2009 – 2010
Keywordsナノチューブ / 透過型電子顕微鏡 / デバイス特性
Research Abstract

Atomic nanowires have been synthesized using ultra-thin 1-dimensional nanospace of carbon nanotubes. One of the key to achieve the formation of atomic wire inside nanotube nanospace is to use high quality and high purity carbon nanotubes synthesized by laser vaporization and chemical vapor deposition method. Synthesized atomic wires have a diameter of one atom thick at thinnest, which is the world thinnest wires among ever synthesized. In the case of atomic wires whose diameter is two-atom thick, I have found that the reversible structural transformation from zigzag structure and helical structure occurs during TEM observations at room temperature. In addition to synthesis of novel nanocarbon materials, I have developed characterization technique using micro-gap electrodes with channel penetrating though the substrate to elucidate correlation between structure and properties of atomic wires in detail. Using this method, atomic structure characterization using electron microscopy and device characteristics measurement on individual and specific nanotubes have been successfully carried out.

  • Research Products

    (8 results)

All 2011 2010 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Templating rare-earth hybridization via ultrahigh vacuum annealing of ErCl3 nanowires inside carbon nanotubes2011

    • Author(s)
      P.Ayala, R.Kitaura, R.Nakanishi, H.Shiozawa, D.Ogawa, P.Hoffmann, H.Shinohara, T.Pichler
    • Journal Title

      Physical Review B 83

      Pages: 085407-1-085407-6

    • Peer Reviewed
  • [Journal Article] Irregular Modulation of Density-of-States of Nano-Peapods Encapsulating Gd@C-822011

    • Author(s)
      K.Ohashi, N.Imazu, R.Kitaura, H.Shinohara
    • Journal Title

      Metallofullerenes 115

      Pages: 3968-3972

    • Peer Reviewed
  • [Presentation] 新規カーボンナノチューブハイブリッド物質の創製2011

    • Organizer
      カーボンナノ材料研究会
    • Year and Date
      2011-03-04
  • [Presentation] 新規ハイブリッドナノカーボン物質の創製と機能探索2010

    • Author(s)
      北浦良
    • Organizer
      分子アンサンブル2010
    • Year and Date
      2010-11-17
  • [Presentation] 放射光X線回折を用いたナノカーボン材料の構造研究2010

    • Organizer
      SPring-8コンファレンス
    • Year and Date
      2010-11-04
  • [Presentation] Synthesis of one-dimensional coordination nanowires in nano-space of carbon nanotubes2010

    • Author(s)
      R.Kitaura
    • Organizer
      第60回記念錯体化学OSAKA国際会議
    • Year and Date
      2010-09-28
  • [Presentation] Fabrication and characterization of novel nanotube-based hybrid materials2010

    • Author(s)
      R.Kitaura
    • Organizer
      the 1^<st> china-japan young chemist forum
    • Year and Date
      2010-06-20
  • [Remarks] ホームページ等

    • URL

      http://nano.chem.nagoya-u.ac.jp/japanese/

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Published: 2012-02-13   Modified: 2016-04-21  

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