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2011 Fiscal Year Final Research Report

Fabrication of nano-structure using liquid crystal phase and its application to organic solar cells

Research Project

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Project/Area Number 21750188
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionTokyo Institute of Technology

Principal Investigator

IINO Hiroaki  東京工業大学, 像情報工学研究所, 助教 (50432000)

Project Period (FY) 2009 – 2011
Keywords太陽電池 / ナノ材料 / 電気・電子材料 / 液晶相 / バルクへテロ接合
Research Abstract

I have tried to investigate the fabrication of P-N-nano-structure and its application to organic thin film solar cells. I chose the fullerene derivative and liquid crystalline materials as N-type and P-type semiconductors, respectively. In the materials having lower ordered liquid crystal phases, the liquid crystal phase disappeared in low-concentration mixture with fullerene derivative(less than several%). On the other hand, in the material having highly ordered liquid crystal phase, mesophase appeared in spite of high-concentration mixture with fullerene. This fact indicates that the highly ordered liquid crystal is very effective for fabrication of nano-structure using liquid crystal phase. I also developed liquid crystalline materials having highly ordered liquid crystal phase and measured their carrier transport properties, and developed fabrication of very uniform thin film using liquid crystal phases.

  • Research Products

    (24 results)

All 2012 2011 2010 2009

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (13 results)

  • [Journal Article] Improved thermalstability in organic FET fabricated witha soluble BTBT derivative2012

    • Author(s)
      Hiroaki Iino, Takeo Kobori, andJun-ichi Hanna
    • Journal Title

      J. Non Cryst. Solid

      Volume: (In Press)

    • Peer Reviewed
  • [Journal Article] Availability of Liquid Crystallinity in Solution Processing for Polycrystalline Thin Films2011

    • Author(s)
      Hiroaki Iino and Jun-ichi Hanna
    • Journal Title

      Adv. Mater

      Volume: 23 Pages: 1748-1751

    • Peer Reviewed
  • [Journal Article] Liquid crystalline thin films asa precursor for polycrystalline thinfilms aimed at field effect transistors2011

    • Author(s)
      Hiroaki Iino and Jun-ichiHanna
    • Journal Title

      J. Appl. Phys

      Volume: 109 Pages: 0745505

    • Peer Reviewed
  • [Journal Article] Bulk mobility of polycrystalline thin films of quaterthiophene derivatives2011

    • Author(s)
      Kyohei Nakano, Hiroaki Iino, TakayukiUsui, and Jun-ichi Hanna
    • Journal Title

      Appl. Phys. Lett

      Volume: 98 Pages: 103302

    • Peer Reviewed
  • [Journal Article] Charge Injection Enhanced by Guest Material in Molecularly Doped Liquid Crystalline Thin Films2011

    • Author(s)
      Kyohei Nakano, Hiroaki Iino, TakayukiUsui, Yukiko Takayashiki, Jun-ichi Hanna
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51 Pages: 011701

    • Peer Reviewed
  • [Journal Article] Liquid Crystalline Materials for Organic Polycrystalline Field Effect Transistors2011

    • Author(s)
      Hiroaki Iino and Jun-ichi Hanna
    • Journal Title

      Mol. Cryst. Liq. Cryst

      Volume: 542 Pages: 237-243

    • Peer Reviewed
  • [Journal Article] Polycrystalline Organic TFT Fabricated by Solution Process Using Liquid Crystalline Material2009

    • Author(s)
      Hiroaki Iino and Jun-ichi Hanna
    • Journal Title

      Mol. Cryst. Liqd. Cryst

      Volume: 510 Pages: 259-267

    • Peer Reviewed
  • [Journal Article] Electronic conduction in nematic phase of small molecules2009

    • Author(s)
      Keiji Tokunaga, Yukiko Takayashiki, Hiroaki Iino, Jun-ichi Hanna
    • Journal Title

      Phys. Rev. B, 79

      Volume: 79 Pages: 033201

    • Peer Reviewed
  • [Journal Article] Charge Carrier Transport Properties in Liquid Crystalline2-Phenylbenzothiazole Derivatives2009

    • Author(s)
      Keiji Tokunaga, Hiroaki Iino, Jun-ichiHanna
    • Journal Title

      Mol. Cryst. Liq, Cryst

      Volume: 510 Pages: 241-249

    • Peer Reviewed
  • [Journal Article] One-Dimensional to Three-Dimensional Electronic Conduction in Liquid Crystalline Mesophases2009

    • Author(s)
      Keiji Tokunaga, Yukiko Takayashiki, Hiroaki Iino, Jun-ichi Hanna
    • Journal Title

      Mol. Cryst. Liq. Cryst

      Volume: 510 Pages: 250-258

    • Peer Reviewed
  • [Journal Article] カラムナー相における電荷輸送2009

    • Author(s)
      飯野裕明, 半那純一
    • Journal Title

      液晶

      Volume: 13 Pages: 133-143

    • Peer Reviewed
  • [Presentation] 高次Sm液晶相を活用した可溶性FET材料の耐熱性の改善2012

    • Author(s)
      飯野裕明,臼井孝之,小堀武夫,半那純一
    • Organizer
      日本化学会第92回春季年会
    • Place of Presentation
      慶應大学,神奈川県
    • Year and Date
      2012-03-27
  • [Presentation] Improved Efficiency and Molecular Orientation in Thermally Annealed Bulk Hetero-junction Solar Cells with Smectic Liquid Crystalline Material2012

    • Author(s)
      Kyohei Nakano, Hiroaki Iino, Yukiko Takayashiki, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      1st International Symposium on Self-Organizing Molecular Semiconductors
    • Place of Presentation
      蔵前会館,東京
    • Year and Date
      2012-02-22
  • [Presentation] Availability of liquid crystallinity in solution processing for polycrystalline thin films and their application to organic transistor2012

    • Author(s)
      Hiroaki Iino, Takeo Kobori, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      1st International Symposium on Self-Organizing Molecular Semiconductors
    • Place of Presentation
      蔵前会館,東京
    • Year and Date
      2012-02-21
  • [Presentation] Controlled Molecular Orientation in Organic Solar Cells2011

    • Author(s)
      Kyohei Nakano, Hiroaki Iino, Takayuki Usui, Jun-ichi Hanna
    • Organizer
      MRS Fall Meeting 2011
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-11-28
  • [Presentation] 高次の液晶相を発現するBTBT誘導体の多結晶材料としての有用性2011

    • Author(s)
      飯野裕明,小堀武夫,臼井孝之,半那純一
    • Organizer
      2011年日本液晶学会討論会
    • Place of Presentation
      東京都市大学,東京
    • Year and Date
      2011-09-13
  • [Presentation] 液晶性有機半導体を用いた薄膜太陽電池の作製と特性評価2011

    • Author(s)
      中野恭兵,飯野裕明,臼井孝之,半那純一
    • Organizer
      2011年日本液晶学会討論会
    • Place of Presentation
      東京都市大学,東京
    • Year and Date
      2011-09-13
  • [Presentation] 高次液晶相を有するBTBT誘導体を用いた多結晶薄膜の作製とFET応用2011

    • Author(s)
      飯野裕明,小堀武夫,臼井孝之,半那純一
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学,山形
    • Year and Date
      2011-09-01
  • [Presentation] 液晶性有機半導体を用いた薄膜太陽電池の作製と特性評価2011

    • Author(s)
      中野恭兵,飯野裕明,臼井孝之,半那純一
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学,山形
    • Year and Date
      2011-09-01
  • [Presentation] 液晶性有機半導体を用いた多結晶薄膜の作製とトランジスタへの応用2011

    • Author(s)
      飯野裕明
    • Organizer
      応用物理学会有機分子・バイオエレクトロニクス分科会研究会
    • Place of Presentation
      神戸大学,兵庫
    • Year and Date
      2011-06-25
  • [Presentation] Liquid Crystallinity in Organic Field effect transistor materials2011

    • Author(s)
      Hiroaki Iino and Jun-ichi Hanna
    • Organizer
      SPIE Photonic West2011
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2011-01-25
  • [Presentation] ミクロ相分離構造を用いた液晶性有機半導体へのチャージドーピングとそれを用いたFETのコンタクト改善2010

    • Author(s)
      飯野裕明,小西昇一,半那純一
    • Organizer
      2010年日本液晶学会討論会
    • Place of Presentation
      九州大学,福岡
    • Year and Date
      2010-09-08
  • [Presentation] BTBT系液晶性有機半導体の電荷輸送特性2010

    • Author(s)
      飯野裕明,小堀武夫,半那純一
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学、大阪
    • Year and Date
      2010-03-28
  • [Presentation] 液晶相におけるミクロ相分離を利用した液晶性有機半導体へのチャージドーピング2009

    • Author(s)
      飯野裕明,小西昇一,半那純一
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学、富山
    • Year and Date
      2009-09-08

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Published: 2013-07-31  

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