2011 Fiscal Year Final Research Report
Synthesis of novel substituted micas and interlayer pillared nanoporous solids
| Project/Area Number |
21750206
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Shinshu University |
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Principal Investigator |
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| Research Collaborator |
OZAWA Reiji 信州大学, 工学系研究科, 学生
IKUTA Kazuya 信州大学, 工学系研究科, 学生
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| Project Period (FY) |
2009 – 2011
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| Keywords | 膨潤性マイカ / 架橋マイカ / インターカレーション / 多孔体 / フラックス |
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| Research Abstract |
Synthesis of novel substituted swellable micas was undertaken. Preparation of interlayer pillared microporous solids, i. e. pillared micas, was also undertaken using the substituted micas as host crystals. Series of Ge-substituted and B-substituted swellable micas were successfully synthesized and allowed to use as host crystals for intercalation. The pore properties of the pillared micas thus obtained by the intercalation changed, depending on the composition of host substituted micas. Raw materials containing NaCl as a flux yielded swellable mica crystals having a hexagonal, plate-like morphology with a larger aspect ratio.
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