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2010 Fiscal Year Final Research Report

Elucidation of mechanism of relaxor ferroelectrics -polar nano region and random field-

Research Project

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Project/Area Number 21760524
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

KIGUCHI Takanori  東北大学, 金属材料研究所, 准教授 (70311660)

Project Period (FY) 2009 – 2010
Keywordsリラクサー / 強誘電体 / 極性ナノ領域(PNR) / 化学的秩序領域(COR) / ランダム場 / 電子顕微鏡 / 幾何学的位相解析 / 歪みマッピング
Research Abstract

The deposition condition for the epitaxial growth of Pb(Mg_<1/3>Nb_<2/3>)O_3(PMN) on SrTiO_3(STO) substrate was conducted. Epitaxial PMN thin film was obtained. The aberration-corrected transmission electron microscopy (HRTEM) analysis has elucidated the structure of PMN thin films by the atomic-resolution. In particular, Pb-O atomic columns randomly displaced in <111> direction. The result indicates that the direct observation of the characteristic atomic displacement by the random field from the B-site randomness. The HRTEM and the related strain mapping has elucidated that the detailed structure of the polar nano region (PNR).

  • Research Products

    (43 results)

All 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (26 results) Remarks (7 results)

  • [Journal Article] Nanostructure and strain analysis of CeO_2/YSZ strained superlattice2010

    • Author(s)
      Takanori Kiguchi, Toyohiko J. Konno, Naoki Wakiya, Hitoshi Morioka, Keisuke Saito, Kazuo Shinozaki
    • Journal Title

      Materials Science and Engineering B

      Volume: 173 Pages: 220-228

    • Peer Reviewed
  • [Journal Article] Geometric Phase Analysis of Nano-Scale Strain Fields Around 90° Domains in PbTiO_3/SrTiO_3 Epitaxial Thin Film2010

    • Author(s)
      Takanori Kiguchi, Kenta Aoyagi, Toyohiko J. Konno, Satoru Utsugi, Tomoaki Yamada, Hiroshi Funakubo
    • Journal Title

      Materials Research Society Symposium Proceeding

      Volume: 1199 Pages: 1199-F09-08-01-1199-F09-08-06

    • Peer Reviewed
  • [Journal Article] Ferroelectric Properties of epitaxial BiFe_<0.97>Mn_<0.03>O_3 thin films with dioeerent crystal orientations deposited on buoeered Si substrate2010

    • Author(s)
      Hyun-young Go, Naoki Wakiya, Takanori Kiguchi, Tomohiko Yoshioka, Osamu Sakurai, Jeoerey S. Cross, Junzo Tanaka, Kazuo Shinozaki
    • Journal Title

      Key Engineering Materials

      Volume: 445 Pages: 111-114

    • Peer Reviewed
  • [Journal Article] Crystal Structure and Dielectric Property of Bismuth Layer-Structured Dielectric Films with c-Axis Preferential Crystal Orientation2010

    • Author(s)
      Y. Mizutani, T. Kiguchi, T. J. Konno, H. Funakubo, H. Uchida
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49 Pages: 09MA02-1-09MA02-6

    • Peer Reviewed
  • [Journal Article] Antiferrodistortive Structural Phase Transition in Compressively-strained Epitaxial SrTiO_3 Film Grown on (La, Sr)(Al, Ta)O_3 Substrate2010

    • Author(s)
      T. Yamada, T. Kiguchi, A.K. Tagantsev, H. Morioka, T. Iijima, H. Ohsumi. Kimura, M. Osada, N. Setter, H. Funakubo
    • Journal Title

      Integrated Ferroelectrics

      Volume: 115 Pages: 57-62

    • Peer Reviewed
  • [Journal Article] Aberration-Corrected HRTEM Analysis of Transition Structure in Phase Boundary of ZrO_2 Ultra-Thin Film2010

    • Author(s)
      Takanori Kiguchi, Toyohiko J. Konno, Naoki Wakiya, Kazuo Shinozaki
    • Journal Title

      Materials Research Society Symposium Proceeding

      Volume: 1231 Pages: 1231-NN03-12-01-1231-NN03-12-06

    • Peer Reviewed
  • [Journal Article] Valence-EELS analysis of local electronic and optical properties of PMN-PT epitaxial film2009

    • Author(s)
      Takanori Kiguchi, Naoki Wakiya, Kazuo Shinozaki, Toyohiko J. Konno
    • Journal Title

      Materials Science and Engineering B

      Volume: 161 Pages: 160-165

    • Peer Reviewed
  • [Journal Article] Doping eoeect of Dy on leakage current and oxygen sensing property of SrTiO_3 thin film prepared by PLD2009

    • Author(s)
      Naoki WAKIYA, Yusuke KIMURA, Naonori SAKAMOTO, Desheng FU, Toru HARA, Takashi ISHIG-URO, Takanori Kiguchi, Kazuo SHINOZAKI, Hisao SUZUKI
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 117 Pages: 1004-1008

    • Peer Reviewed
  • [Journal Article] Preparation of Epitaxial LiNbO_3 Thin Film by MOCVD and Its Properties2009

    • Author(s)
      Rintarou Morohashi, Naoki Wakiya, Takanori Kiguchi, Tomohiko Yoshioka, Junzo Tanaka, Kazuo Shinozaki
    • Journal Title

      Key Engineering Materials

      Volume: 388 Pages: 179-182

    • Peer Reviewed
  • [Journal Article] 収差補正TEMによるZrO_2超薄膜における構造遷移層の解明2009

    • Author(s)
      木口賢紀, 今野豊彦、脇谷尚樹、篠崎和夫
    • Journal Title

      日本金属学会まてりあ

      Volume: 48 Pages: 599

    • Peer Reviewed
  • [Presentation] Pb(Mg_<1/3>Nb_<2/3>)O_3薄膜の作製と極性ナノ領域の解析2011

    • Author(s)
      中村崇昭、青柳健大、木口賢紀、内田寛、坂元尚紀、脇谷尚樹、鈴木久男、宇佐美徳隆、今野豊彦
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      浜松
    • Year and Date
      2011-03-18
  • [Presentation] PbTiO_3膜における積層欠陥形成による歪み緩和2011

    • Author(s)
      青柳健大、兒玉裕美子、木口賢紀、宇佐美徳隆、今野豊彦、江原祥隆、舟窪浩、山田智
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      浜松
    • Year and Date
      2011-03-18
  • [Presentation] Pb系強誘電体薄膜における極性構造の原子分解能観察2011

    • Author(s)
      木口賢紀、青柳健大、中村崇昭、宇佐美徳隆、今野豊彦、江原祥隆、舟窪浩、山田智
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      浜松
    • Year and Date
      2011-03-18
  • [Presentation] 鉛系緩和型強誘電体薄膜の作製と局所構造評価2011

    • Author(s)
      中村崇昭, 木口賢紀, 内田寛, 坂元尚紀, 脇谷尚樹, 鈴木久男, 宇佐美徳隆, 今野豊彦
    • Organizer
      日本セラミックス協会第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-01-12
  • [Presentation] 鉛系強誘電体薄膜の局所弾性場イメージングによる格子欠陥相互作用の解明2011

    • Author(s)
      木口賢紀、青柳健大、中村崇昭、 内田寛、舟窪浩、宇佐美徳隆、今野豊彦
    • Organizer
      日本セラミックス協会第49回セラミックス基礎科学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-01-12
  • [Presentation] 強誘電体薄膜における格子欠陥の弾性相互作用のナノイメージング2010

    • Author(s)
      木口賢紀, 青柳健大、宇佐美徳隆、舟窪浩、今野豊彦
    • Organizer
      金属材料研究所第120回講演会(2010年秋季)
    • Place of Presentation
      金属材料研究所
    • Year and Date
      2010-11-24
  • [Presentation] CSD法による緩和型強誘電体の局所構造評価2010

    • Author(s)
      中村祟昭、木口賢紀, 内田寛、宇佐美徳隆、今野豊彦
    • Organizer
      金属材料研究所第120回講演会(2010年秋季)
    • Place of Presentation
      金属材料研究所
    • Year and Date
      2010-11-24
  • [Presentation] TEM暗視野像によるPbTiO_3薄膜ドメイン構造の極性判定2010

    • Author(s)
      青柳健大, 木口賢紀, 宇佐美徳隆, 舟窪浩, 今野豊彦
    • Organizer
      金属材料研究所第120回講演会(2010年秋季)
    • Place of Presentation
      金属材料研究所
    • Year and Date
      2010-11-24
  • [Presentation] Atomic-Resolution Imaging of Domain Polarity and Domain Wall Structure of PbTiO_3 Thin Film2010

    • Author(s)
      Takanori Kiguchi, Kenta Aoyagi, Noritaka Usami, Toyohiko J. Konno, Yoshitaka Ehara, Tomoaki Yamada, Hiroshi Funakubo
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      Osaka
    • Year and Date
      2010-11-15
  • [Presentation] 種々の膜厚を有するPbTiO_3エピタキシャル膜微細組織の電子顕微鏡観察2010

    • Author(s)
      青柳健大、木口賢紀、今野豊彦、江原祥隆、山田智明、舟窪浩
    • Organizer
      第30回エレクトロセラミックス研究討論会
    • Place of Presentation
      市ヶ谷
    • Year and Date
      2010-10-30
  • [Presentation] 種々の膜厚を有するPbTiO_3膜微細組織の電子顕微鏡観察2010

    • Author(s)
      青柳健大、木口賢紀、今野豊彦、江原祥隆、山田智明、舟窪浩
    • Organizer
      平成22年度日本セラミックス協会東北北海道支部研究発表会
    • Place of Presentation
      仙台市
    • Year and Date
      2010-10-28
  • [Presentation] Nanoscale Analysis of Elastic Interaction between 90° Domain and Misfit Dislocation in PbTiO_3/SrTiO_3 Epitaxial Thin Film2010

    • Author(s)
      T. Kiguchi, K. Aoyagi, T.J. Konno, S. Utsugi, T. Yamada, H. Funakubo
    • Organizer
      The 4th International Conference on Science and Technology for Advanced Ceramics (STAC-4) 2010
    • Place of Presentation
      Yokohama
    • Year and Date
      2010-06-22
  • [Presentation] 歪みの少ないエピタキシャル正方晶分極軸配向Pb(Zr,Ti)O_3厚膜を用いたソフトモードによる強誘電性の見積もり2010

    • Author(s)
      江原祥隆, 宇津木覚, 中島光雅, 山田智明, 舟窪浩, 飯島高志, 木口賢紀, 今野豊彦
    • Organizer
      第27回強誘電体応用会議(FMA27)
    • Place of Presentation
      京都
    • Year and Date
      2010-05-28
  • [Presentation] 配向性ビスマス層状構造酸化物薄膜の結晶構造と誘電特性2010

    • Author(s)
      水谷佑樹, 木口賢紀, 今野豊彦, 舟窪浩, 内田寛
    • Organizer
      第27回強誘電体応用会議(FMA-27)
    • Place of Presentation
      京都
    • Year and Date
      2010-05-28
  • [Presentation] PbTiO_3薄膜90°ドメイン構造における局所歪み場の解析2010

    • Author(s)
      木口賢紀, 今野豊彦, 青柳健大, 宇津木悟, 山田智明, 舟窪
    • Organizer
      日本顕微鏡学会第66回学術講演会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-05-25
  • [Presentation] PbTiO_3/SrTiO_3薄膜における90°ドメイン構造の歪み場イメージング2010

    • Author(s)
      木口賢紀, 青柳健大, 今野豊彦, 宇津木悟, 山田智明, 舟窪浩
    • Organizer
      日本セラミックス協会2010年年会
    • Place of Presentation
      東京
    • Year and Date
      2010-03-22
  • [Presentation] 幾何学的位相解析によるPbTiO_3薄膜90°ドメインの局所歪み場解析2010

    • Author(s)
      木口賢紀, 今野豊彦, 青柳健大, 宇津木悟, 山田智明, 舟窪浩
    • Organizer
      第57回応用物理学会関係連合講演会(春期)
    • Place of Presentation
      平塚市
    • Year and Date
      2010-03-19
  • [Presentation] Geometric Phase Analysis of Nano- Scale Strain Fields around 90° Domains in PbTiO_3/SrTiO_3 Epitaxial Thin Film2009

    • Author(s)
      Takanori Kiguchi, Kenta Aoyagi, Toyohiko J. Konno, Satoru Utsugi, Tomoaki Yamada, Hiroshi Funakubo
    • Organizer
      Materials Research Society 2009 Fall Meeting
    • Place of Presentation
      USA, Boston
    • Year and Date
      2009-12-02
  • [Presentation] Aberration-Corrected HRTEM Analysis of Transition Structure in Phase Boundary of ZrO_2 Ultra-Thin Film2009

    • Author(s)
      Takanori Kiguchi, Toyohiko J. Konno, Naoki Wakiya, Kazuo Shinozaki
    • Organizer
      aterials Research Society 2009 Fall Meeting
    • Place of Presentation
      USA, Boston
    • Year and Date
      2009-11-30
  • [Presentation] 顕微鏡による結晶化メカニズムの解明2009

    • Author(s)
      木口賢紀
    • Organizer
      金属材料研究所第118回講演会(2009年秋季)
    • Place of Presentation
      金属材料研究所
    • Year and Date
      2009-11-27
  • [Presentation] Possibility of NO_x Sensing by using Titania Doped Ferrite Epitaxial Thin Film2009

    • Author(s)
      Kazuo Shinozaki, Yusuke Inaba, Toru Hara, Takanori Kiguchi, Naoki Wakiya, Jeffrey S. Cross, Osamu Sakurai
    • Organizer
      The 26th International Japan-Korea Seminar on Ceramics
    • Place of Presentation
      Japan, Tsukuba
    • Year and Date
      2009-11-06
  • [Presentation] Crystal orientation control of epitaxial Pb(Zr,Ti)O_3 and BiFeO_3 thin film deposited on atomic layer buffered Si and YSZ substrates2009

    • Author(s)
      K. Shinozaki, H-Y. Go, T. Kiguchi, N. Wakiya, J. S. Cross and O. Sakurai
    • Organizer
      GJ-NST2009 (International Conference on Nano Science and Nano Technology 2009)
    • Place of Presentation
      Korea, Mokpo
    • Year and Date
      2009-11-06
  • [Presentation] 酸化物薄膜のナノ歪み場解析2009

    • Author(s)
      木口賢紀, 今野豊彦, 脇谷尚樹, 篠崎和夫、宇津木悟、山田智明、舟窪浩
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      松山市
    • Year and Date
      2009-09-17
  • [Presentation] 収差補正電子顕微鏡によるセラミック薄膜の界面構造解析2009

    • Author(s)
      木口賢紀, 今野豊彦、脇谷尚樹、篠崎和夫
    • Organizer
      日本機械学会2009年度年次大会
    • Place of Presentation
      盛岡
    • Year and Date
      2009-09-14
  • [Presentation] Aberration-Corrected HRTEM Analysis of Transition Layer Structure in ZrO_2 Ultra-Thin Film2009

    • Author(s)
      T. Kiguchi, T. J. Konno, N. Wakiya, K. Shinozaki
    • Organizer
      Microscopy Conference 2009 in Graz
    • Place of Presentation
      Austria, Graz
    • Year and Date
      2009-09-01
  • [Presentation] 収差補正電子顕微鏡によるZrO_2超薄膜の相境界構造遷移層の解明2009

    • Author(s)
      木口賢紀、今野豊彦、脇谷尚樹、篠崎和夫
    • Organizer
      日本顕微鏡学会第65回学術講演会
    • Place of Presentation
      仙台市
    • Year and Date
      2009-05-29
  • [Remarks] コニカミノルタ画像科学進歩賞(2011)

  • [Remarks] 第35回日本セラミックス協会学術写真賞 特別賞(2010)

  • [Remarks] 第35回日本セラミックス協会学術写真賞 優秀賞(2010)

  • [Remarks] Poster Award in 3rd International Congress on Ceramics (ICC3) (2010)

  • [Remarks] 第30回エレクトロセラミックス研究討論会 奨励賞

  • [Remarks] 平成22年度日本セラミックス協会東北北海道支部研究発表会優秀ポスター賞

  • [Remarks] 日本顕微鏡学会第10回奨励賞(2009)

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Published: 2013-07-31  

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