2010 Fiscal Year Final Research Report
Development of catalytic formation of molecular skeletons using cobalt oxide supported gold nanoparticles
| Project/Area Number |
21850023
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Kyushu University |
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Principal Investigator |
HAMASAKI Akiyuki Kyushu University, 大学院・理学研究院, 助教 (00515174)
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| Project Period (FY) |
2008 – 2010
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| Keywords | 酸化物担持金ナノ粒子 / コバルトカルボニル / ニコラス反応 / 代替触媒 |
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| Research Abstract |
Cobalt oxide supported gold nanoparticles have been revealed to effectively provide a cobalt active species under syngas (a mixture of carbon monoxide and hydrogen) atmosphere. This cobalt species could be used as an alternative reagent for the traditional cobalt carbonyls. The Pauson?Khand reaction, the alkoxycarbonylation, and the formation of cobalt complex with alkynes smoothly proceeded by using cobalt oxide supported gold nanoparticles.
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