2010 Fiscal Year Final Research Report
Catalytic degradation of cellulose using oxygen
| Project/Area Number |
21860004
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Hokkaido University |
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Principal Investigator |
KOBAYASHI Hirokazu Hokkaido University, 触媒化学研究センター, 助教 (30545968)
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| Project Period (FY) |
2009 – 2010
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| Keywords | バイオマス / セルロース / グルコース / グリセリン / アクロレイン / 触媒化学プロセス / 再生可能エネルギー |
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| Research Abstract |
Oxidative degradation of cellulose was performed using oxygen and water in a high pressure reactor. By changing the reaction conditions and catalysts, the ratio of glucose, gluconic acid, and formic acid can be controlled, and they are useful in the chemical industry. I applied the catalytic system to the conversion of glycerol and found that mesoporous sulfated zirconia-silica dehydrates glycerol to acrolein in 81% yield. The synthesis of acrolein is one of the significant reactions as it is a versatile precursor to functional polymers and pharmaceuticals.
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Research Products
(10 results)
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[Book] シーエムシー2009
Author(s)
小林広和,福岡淳
Total Pages
176-182
Publisher
木質系有機資源の新展開II(セルロースの解重合)
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