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2023 Fiscal Year Final Research Report

In operando observation of solid oxide cells under real operating conditions

Research Project

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Project/Area Number 21H01258
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 19020:Thermal engineering-related
Research InstitutionThe University of Tokyo

Principal Investigator

Shikazono Naoki  東京大学, 生産技術研究所, 教授 (30345087)

Co-Investigator(Kenkyū-buntansha) 谷口 淳  東京理科大学, 先進工学部電子システム工学科, 教授 (40318225)
岡部 貴雄  東京大学, 生産技術研究所, 特任助教 (80649400)
Project Period (FY) 2021-04-01 – 2024-03-31
Keywords燃料電池
Outline of Final Research Achievements

Operando experiments were carried out in which nickel was sputtered in a pattern onto yttria stabilized zirconia (YSZ) electrolyte substrates, and laser confocal microscopy images were acquired during power generation and electrolysis conditions. The effects of operating conditions such as fuel cell operation, electrolysis operation and reversible operation, as well as the effect of the electrolyte substrate, on the dynamic shape change of the nickel were observed and evaluated using laser and optical microscopy images.

Free Research Field

熱工学

Academic Significance and Societal Importance of the Research Achievements

本研究では,多孔体を模擬した微細凹凸つきパターン電極のoperando実験を行い,固体酸化物形セル多孔体燃料極中のニッケルの移動現象における,分極の向き(発電か電解か),電流密度の大きさ,電解質材料,幾何学形状等の影響を系統的に実験評価した.実際の多孔体電極では得られない,ダイナミックな直接観察に成功しているのは当グループだけである.

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Published: 2025-01-30  

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