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2023 Fiscal Year Annual Research Report

Observation of large tunnel magnetocapacitance effect and elucidation of its mechanism

Research Project

Project/Area Number 21H01397
Research InstitutionKeio University

Principal Investigator

海住 英生  慶應義塾大学, 理工学部(矢上), 教授 (70396323)

Co-Investigator(Kenkyū-buntansha) 介川 裕章  国立研究開発法人物質・材料研究機構, 磁性・スピントロニクス材料研究拠点, 主幹研究員 (30462518)
Project Period (FY) 2021-04-01 – 2024-03-31
Keywordsスピントロニクス / キャパシタンス / 交流インピーダンス特性 / 表面・界面物性 / ナノ構造
Outline of Annual Research Achievements

磁場によりキャパシタンス(=電気容量)が変化する磁気キャパシタンス(MC)効果は、高感度磁気センサ、省エネメモリ、大容量蓄電材料への応用が期待されていることから、国内外で大きな注目を集めている。MC効果は時間反転対称性と空間反転対称性が破れている系で観測されることから基礎物理学の観点からも興味深い。これまでにMC効果はマルチフェロイック材料、スピントロニクスデバイス、磁気スーパーキャパシタなど、様々な物質・材料・デバイスにおいて発見されてきた。最近では、有機ヘテロ接合、グラフェンベース2次元材料、3次元トポロジカル絶縁体などにおいても観測されている。本研究では、スピントロニクスデバイスにおける磁気トンネル接合(MTJ)に注目し、巨大なトンネル磁気キャパシタンス(TMC)効果の発現とそのメカニズム解明を目指す。
MTJは2層の磁性層の間に極薄の絶縁層が挟まれた構造を有する。当該年度では、磁性層としてFeCoを用い、絶縁層としてMgAlOを用いたFeCo/MgAlO/FeCoベースのMTJを作製し、磁場中交流4端子法によりTMC効果の周波数特性、及び電圧依存性を調べた。その結果、これまで報告されている中で最も大きい456%のTMC比の観測に成功した。これらの実験結果はデバイ・フレーリッヒ模型、シグモイド関数を取り入れたジャン理論、2次関数放物線バリア近似、スピン依存ドリフト拡散模型を用いた理論計算により定量的に説明することができた。本成果はIOP Publishingの学術論文誌Applied Physics Expressに掲載された他、Intermag 2023国際学会や応用物理学会においても発表を行った。

Research Progress Status

令和5年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和5年度が最終年度であるため、記入しない。

  • Research Products

    (26 results)

All 2024 2023 Other

All Int'l Joint Research (1 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 1 results) Presentation (20 results) (of which Int'l Joint Research: 14 results,  Invited: 7 results) Remarks (1 results)

  • [Int'l Joint Research] ブラウン大学(米国)

    • Country Name
      U.S.A.
    • Counterpart Institution
      ブラウン大学
  • [Journal Article] Emergent magneto-inductance effect in permalloy thin films on flexible polycarbonate substrates at room temperature2024

    • Author(s)
      Yu Matsushima, Zijing Zhang, Yuri Ohashi, Tsunagu Hatakeyama, Gang Xiao, Takumi Funato, Mamoru Matsuo, and Hideo Kaiju
    • Journal Title

      Applied Physics Letters

      Volume: 124 Pages: 022404 (1-7)

    • DOI

      10.1063/5.0181272

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Large magnetocapacitance of up to 456% at room temperature in FeCo/MgAl2O4/FeCo(001) magnetic tunnel junctions2023

    • Author(s)
      Yuto Shibata, Kenta Sato, Hiroaki Sukegawa, and Hideo Kaiju
    • Journal Title

      Applied Physics Express

      Volume: 16 Pages: 113003(1-6)

    • DOI

      10.35848/1882-0786/ad0b40

    • Peer Reviewed
  • [Journal Article] Site-specific Synthesis of Conductive Graphitic Nanomaterials on a NiFe Thin Film by Localized Laser Irradiation2023

    • Author(s)
      Hideki Fujiwara, Seigo Daikokuya, Tatsuki Mirokuin, Kyohei Hayashi, Mizuki Matsuzaka, Yuri Ohashi, Christophe Pin, Hideo Kaiju, Kenji Hirai, and Hiroshi Uji-i
    • Journal Title

      ACS Applied Nano Materials

      Volume: 6 Pages: 13885-13893

    • DOI

      10.1021/acsanm.3c01272

    • Peer Reviewed / Open Access
  • [Journal Article] Nano-crystal domains in Co-based fcc(111) epitaxial magnetic junctions and their impact on tunnel magnetoresistance2023

    • Author(s)
      Cong He, Keisuke Masuda, Jieyuan Song, Thomas Scheike, Zhenchao Wen; Yoshio Miura, Tadakatsu Ohkubo, Kazuhiro Hono, Seiji Mitani, and Hiroaki Sukegawa
    • Journal Title

      Acta Materialia

      Volume: 261 Pages: 119394(1-14)

    • DOI

      10.1016/j.actamat.2023.119394

    • Peer Reviewed
  • [Presentation] Emergent magneto-inductance effect at room temperature in Ni78Fe22 thin films on glass substrates2024

    • Author(s)
      Zijing Zhang, Yu Matsushima, Yuto Shibata, Tsunagu Hatakeyama, and Hideo Kaiju
    • Organizer
      CEMS Symposium on Emergent Quantum Materials 2024
    • Int'l Joint Research
  • [Presentation] 磁気トンネル接合を用いた発振制御型磁気センシング2024

    • Author(s)
      若本瑞葵、柴田有仁、Gang Xiao、海住英生
    • Organizer
      第71回応用物理学会春季学術講演会
  • [Presentation] FeCo/MgAl2O4/FeCo(001) magnetic tunnel junctions with a large magnetocapacitance ratio of 456%2024

    • Author(s)
      Yuto Shibata, Kenta Sato, Hiroaki Sukegawa, and Hideo Kaiju
    • Organizer
      The 71st JSAP Spring Meeting 2024
  • [Presentation] 巨大室温トンネル磁気抵抗比631%の観測2024

    • Author(s)
      介川裕章、T. Scheike、Z. Wen、三谷誠司
    • Organizer
      2024年第71回 応用物理学会春季学術講演会
    • Invited
  • [Presentation] Large Tunnel Magnetocapacitance Effect in FeCo/MgAlO/FeCo(001) Magnetic Tunnel Junctions2023

    • Author(s)
      Yuto Shibata, Kenta Sato, Hiroaki Sukegawa, and Hideo Kaiju
    • Organizer
      Intermag 2023
    • Int'l Joint Research
  • [Presentation] Room-Temperature Magnetoresistance in Nanojunctions Consisting of C8-BTBT Molecules Sandwiched Between Two Magnetic Thin-Film Edges2023

    • Author(s)
      Mizuki Matsuzaka, Yuma Sasaki, Kyohei Hayashi, Takahiro Misawa, Takashi Komine, Tomoyuki Akutagawa, Masaya Fujioka, Junji Nishii, and Hideo Kaiju
    • Organizer
      Intermag 2023
    • Int'l Joint Research
  • [Presentation] Emergent Magneto-Inductance Effect in Ni45Fe55 Thin Films on Polycarbonate Substrates2023

    • Author(s)
      Zijing Zhang, Yu Matsushima, Yuri Ohashi, Mizuki Matsuzaka, and Hideo Kaiju
    • Organizer
      Intermag 2023
    • Int'l Joint Research
  • [Presentation] Evaluation of structural, electrical and magnetic properties in nanoscale junctions using high-mobility molecules2023

    • Author(s)
      Mizuki Matsuzaka, Takahiro Misawa, Ryunosuke Miyamoto, Zijing Zhang, Kenta Sato, Yuma Sasaki, Junji Nishii, and Hideo Kaiju
    • Organizer
      The 84th JSAP Autumn Meeting 2023
  • [Presentation] Record for tunnel magnetoresistance of 631% at room temperature with barrier interface control technology2023

    • Author(s)
      Hiroaki Sukegawa
    • Organizer
      The 68th Annual Conference on Magnetism and Magnetic Materials (MMM2023)
    • Int'l Joint Research / Invited
  • [Presentation] Giant oscillatory tunnel magnetoresistance: an unsolved spin dependent tunneling puzzle2023

    • Author(s)
      Thomas Scheike, Cong He, Zhenchao Wen, Hiroaki Sukegawa, and Seiji Mitani
    • Organizer
      The 68th Annual Conference on Magnetism and Magnetic Materials (MMM2023)
    • Int'l Joint Research / Invited
  • [Presentation] Three Types of Nano Crystal Domain Structures in Fully Epitaxial fcc-Co/MgO/Co(111) Magnetic Tunnel Junctions.2023

    • Author(s)
      Cong He, Keisuke Masuda, Jieyuan Song, Thomas Scheike, Zhenchao Wen, Hiroaki Sukegawa, Yoshio Miura, Tadakatsu Ohkubo, Kazuhiro Hono, and Seiji Mitani
    • Organizer
      The 68th Annual Conference on Magnetism and Magnetic Materials (MMM2023)
    • Int'l Joint Research
  • [Presentation] CoFe/MgO/CoFe(001) magnetic tunnel junctions with giant tunnel magnetoresistance exceeding 630% at room temperature2023

    • Author(s)
      SCHEIKE, Thomas, WEN, ZhenChao, SUKEGAWA, Hiroaki, MITANI, Seiji
    • Organizer
      第47回日本磁気学会学術講演会
  • [Presentation] 630%を超える室温トンネル磁気抵抗比の観測2023

    • Author(s)
      シャイケ トーマス, 温 振超, 介川 裕章, 三谷 誠司
    • Organizer
      2023年第84回応用物理学会秋季学術講演会
  • [Presentation] Development of spinel barriers for high performance magnetic tunnel junctions2023

    • Author(s)
      Hiroaki Sukegawa
    • Organizer
      The 6th International Conference of Asian Union of Magnetics Societies (IcAUMS2023)
    • Int'l Joint Research / Invited
  • [Presentation] Room temperature tunnel magnetoresistance new record of 631%, toward new spintronic devices2023

    • Author(s)
      Hiroaki Sukegawa
    • Organizer
      The 34th Magnetic Recording Conference (TMRC 2023)
    • Int'l Joint Research / Invited
  • [Presentation] Analysis of large oscillations in tunnel magnetoresistance and resistance of Fe/Mg4Al-Ox/Fe magnetic tunnel junctions2023

    • Author(s)
      Thomas Scheike, Zhenchao Wen, Hiroaki Sukegawa, and Seiji Mitani
    • Organizer
      MML2023 (11th International Symposium on Metallic Multilayers)
    • Int'l Joint Research
  • [Presentation] Advancing TMR through Epitaxial Technology: Reaching 631% at Room Temperature2023

    • Author(s)
      Hiroaki Sukegawa
    • Organizer
      The 2023 Spintronics Workshop on LSI
    • Int'l Joint Research / Invited
  • [Presentation] Co90Fe10/Mg-Al-O/Co90Fe10 magnetic tunnel junctions with a fully epitaxial fcc (111) structure2023

    • Author(s)
      Jieyuan Song, Thomas Scheike, Cong He, Zhenchao Wen, Hiroaki Sukegawa, Tadakatsu Ohkubo, Kazuhiro Hono, and Seiji Mitani
    • Organizer
      Intermag 2023
    • Int'l Joint Research
  • [Presentation] Sawtooth-like giant oscillation of tunnel magnetoresistance in epitaxial Fe/Mg4Al-Ox/Fe(001) magnetic tunnel junctions2023

    • Author(s)
      Thomas Scheike, Zhenchao Wen, Shinya Kasai, Hiroaki Sukegawa, and Seiji Mitani
    • Organizer
      Intermag 2023
    • Int'l Joint Research
  • [Presentation] Frontier of giant tunnel magnetoresistance effect for future spintronic application2023

    • Author(s)
      Hiroaki Sukegawa
    • Organizer
      The 1st Y-KAST International Conference
    • Int'l Joint Research / Invited
  • [Remarks] 研究室HP

    • URL

      https://www.kaiju.appi.keio.ac.jp/

URL: 

Published: 2024-12-25  

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