| Outline of Annual Research Achievements |
In the final year of our project, we achieved significant milestones. We published five articles and conducted research on approximately 40 new transition metal complexes with various ligands. Moreover, we presented our findings at three conferences.
Among our noteworthy discoveries, we found intriguing spin crossover Fe(II)-Hg(II) networks whose spectroscopic properties change with temperature variations (published in Chem. Mater., 2023, 35, 9613). Currently, we are focusing on similar materials exhibiting responsiveness to light. Additionally, we identified analogous systems capable of mechanical exfoliation into nanosheets (published in J. Phys. Chem. Lett., 2023, 14, 10420). Furthermore, our exploration of Co(II)-octacyanidometallate complexes revealed their spin-modulating behavior in response to varying water content, suggesting potential applications in memory and sensing devices (published in Eur. J. Inorg., 2023, 26, e202300307).
Furthermore, our investigations into cocrystals (published in Inorg. Chem. 2024, 63, 1803) and Ln(III)-Cu(I) systems (published in J. Phys. Chem. C 2023, 127, 15500) unveiled their luminescent characteristics and nonlinear optical properties, particularly in second harmonic generation.
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