従来型ガスクロマトグラフィーで分離不能な隕石中炭化水素混合物の分離と同定の試み

2022 Fiscal Year Research-status Report

• Project/Area Number: 21K18659
• Research Institution: Hiroshima University
• Principal Investigator: 薮田 ひかる 広島大学, 先進理工系科学研究科(理), 教授 (30530844)
• Project Period (FY): 2021-07-09 – 2024-03-31
• Keywords: 二次元ガスクロマトグラフィー / 地球外有機物 / 脂肪族炭化水素 / シクロアルカン / 分岐鎖アルカン / 二次元ガスクロマトグラフィー質量分析 / 隕石 / UCM

Outline of Annual Research Achievements

本研究では、地球外起源のUnresolved Complex Mixture（ガスクロマトグラフィーでは分離できない複雑な混合物; UCM）の構造決定を目的として、炭素質隕石に含まれる脂肪族炭化水素の二次元ガスクロマトグラフィー（GCxGC）質量分析を行い、共溶出化合物の分離・同定を行うことを目的としている。当該年度は、小惑星探査計画「はやぶさ2」で帰還した小惑星リュウグウサンプルの初期分析および成果発表を最優先する必要があったため、当該研究を十分に進めることができなかったが、試料の前処理は前年度に完了している。

Current Status of Research Progress

4: Progress in research has been delayed.

Reason

当該年度は、研究代表者がはやぶさ２初期分析固体有機物チームのリーダーとしての任務に専心する必要があったため、個人の研究としての本研究課題の進捗は遅れている。

Strategy for Future Research Activity

試料の抽出は完了したので、次年度は二次元ガスクロマトグラフィー質量分析測定を行う。

Causes of Carryover

当該年度は、研究代表者がはやぶさ２初期分析固体有機物チームのリーダーとしての任務に専心する必要があったため、個人の研究としての本研究課題の進捗は遅れ、次年度使用額が生じた。
今後、抽出試料の二次元ガスクロマトグラフィー質量分析測定を行う。

Research Products

• [Int'l Joint Research] パリ自然史博物館/グルノーブル大学/パリ＝サクレー大学(フランス)
  • Country Name: FRANCE
  • Counterpart Institution: パリ自然史博物館/グルノーブル大学/パリ＝サクレー大学
• [Int'l Joint Research] カーネギー研究所/バークレー国立研究所 Advanced Light Source/アメリカ海軍調査研究所(米国)
  • Country Name: U.S.A.
  • Counterpart Institution: カーネギー研究所/バークレー国立研究所 Advanced Light Source/アメリカ海軍調査研究所
• [Journal Article] Hydrogen Isotopic Composition of Hydrous Minerals in Asteroid Ryugu (2023)
  • Author(s): Piani L., Nagashima K., Kawasaki N., Sakamoto N., Bajo K.-I., Yabuta H. et al.
  • Journal Title: The Astrophysical Journal Letters Volume: 946 Pages: L43～L43
  • DOI: 10.3847/2041-8213/acc393
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Uracil in the carbonaceous asteroid (162173) Ryugu (2023)
  • Author(s): Oba Y., Koga T., Takano Y., Ogawa N. O., Ohkouchi N., Sasaki K., Sato H., Glavin D. P., Dworkin J. P., Naraoka H., Tachibana S., Yurimoto H., Nakamura T., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: Nature Communications Volume: 14 Pages: -
  • DOI: 10.1038/s41467-023-36904-3
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Interaction between clay minerals and organics in asteroid Ryugu (2023)
  • Author(s): Viennet J.-C., Roskosz M., Nakamura T., Beck P., Baptiste B., Lavina B., Alp E. E., Hu M. Y., Zhao J., Gounelle M., Brunetto R., Yurimoto H., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: Geochemical Perspectives Letters Volume: 25 Pages: 8～12
  • DOI: 10.7185/geochemlet.2307
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Chemical composition of carbonaceous asteroid Ryugu from synchrotron spectroscopy in the mid- to far-infrared of Hayabusa2-returned samples (2023)
  • Author(s): Dartois E., Kebukawa Y., Yabuta H., Mathurin J., Engrand C., Duprat J., Bejach L., Dazzi A., Deniset-Besseau A. et al.
  • Journal Title: Astronomy & Astrophysics Volume: 671 Pages: A2～A2
  • DOI: 10.1051/0004-6361/202244702
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] PAHs, hydrocarbons, and dimethylsulfides in Asteroid Ryugu samples A0106 and C0107 and the Orgueil (CI1) meteorite (2023)
  • Author(s): Aponte J. C., Dworkin J. P., Glavin D. P., Elsila J. E., Parker E. T., McLain H. L., Naraoka H., Okazaki R., Takano Y., Tachibana S., Dong G., Zeichner S. S., Eiler J.M., Yurimoto H., Nakamura T., Yabuta H. et al.
  • Journal Title: Earth, Planets and Space Volume: 75 Pages: -
  • DOI: 10.1186/s40623-022-01758-4
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Extraterrestrial amino acids and amines identified in asteroid Ryugu samples returned by the Hayabusa2 mission (2023)
  • Author(s): Parker E. T., McLain H. L., Glavin D. P., Dworkin J. P., Elsila J. E., Aponte J.C., Naraoka H., Takano Y., Tachibana S., Yabuta H. et al.
  • Journal Title: Geochimica et Cosmochimica Acta Volume: 347 Pages: 42～57
  • DOI: 10.1016/j.gca.2023.02.017
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Macromolecular organic matter in samples of the asteroid (162173) Ryugu (2023)
  • Author(s): Yabuta, H. et al.
  • Journal Title: Science Volume: 379 Pages: -
  • DOI: 10.1126/science.abn9057
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Soluble organic molecules in samples of the carbonaceous asteroid (162173) Ryugu (2023)
  • Author(s): Naraoka H., Takano Y., Dworkin J. P., Oba Y., Hamase K., Furusho A., Ogawa N. O., Hashiguchi M., Fukushima K., Aoki D., Schmitt-Kopplin P., Aponte J. C., Yurimoto H., Nakamura T., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: Science Volume: 379 Pages: -
  • DOI: 10.1126/science.abn9033
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Chondrule-like objects and Ca-Al-rich inclusions in Ryugu may potentially be the oldest Solar System materials (2023)
  • Author(s): Nakashima D., Nakamura T., Zhang M., Kita N. T., Mikouchi T., Yoshida H., Enokido Y., Morita T., Kikuiri M., Amano K., Kagawa E., Yada T., Nishimura M., Nakato A., Miyazaki A., Yogata K., Abe M., Okada T., Usui T., Yoshikawa M., Saiki T., Tanaka S., Nakazawa S., Terui F., Yurimoto H., Noguchi T., Yabuta H. et al.
  • Journal Title: Nature Communications Volume: 14 Pages: -
  • DOI: 10.1038/s41467-023-36268-8
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Nonequilibrium spherulitic magnetite in the Ryugu samples (2023)
  • Author(s): Dobrica E., Ishii H. A., Bradley J. P., Ohtaki K., Brearley A. J., Noguchi T., Yabuta et al.
  • Journal Title: Geochimica et Cosmochimica Acta Volume: 346 Pages: 65～75
  • DOI: 10.1016/j.gca.2023.02.003
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Measurement of Microscopic Thermal Diffusivity Distribution for Ryugu Sample by Infrared Lock-in Periodic Heating Method (2023)
  • Author(s): Ishizaki T., Nagano H., Tanaka S., Sakatani N., Nakamura T., Okada T., Fujita R., Alasli A., Morita T., Kikuiri M., Amano K., Kagawa E., Yurimoto H., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: International Journal of Thermophysics Volume: 44 Pages: -
  • DOI: 10.1007/s10765-023-03158-6
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] The noble gas and nitrogen relationship between Ryugu and carbonaceous chondrites (2023)
  • Author(s): Broadley M. W., Byrne D. J., Furi E., Zimmermann L., Marty B., Okazaki R., Yada T., Kitajima F., Tachibana S., Yogata K., Sakamoto K., Yurimoto H., Nakamura T., Noguchi T., Naraoka H., Yabuta H. et al.
  • Journal Title: Geochimica et Cosmochimica Acta Volume: 345 Pages: 62～74
  • DOI: 10.1016/j.gca.2023.01.020
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Small grains from Ryugu: handling and analysis pipeline for infrared synchrotron microspectroscopy (2023)
  • Author(s): Rubino S., Dionnet Z., Aleon-Toppani A., Brunetto R., Nakamura T., Baklouti D., Djouadi Z., Lantz C., Mivumbi O., Borondics F., Lefrancois S., Sandt C., Capitani F., Heripre; E., Troadec D., Matsumoto M., Amano K., Morita T., Yurimoto H., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: Earth, Planets and Space Volume: 75 Pages: -
  • DOI: 10.1186/s40623-022-01762-8
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Noble gases and nitrogen in samples of asteroid Ryugu record its volatile sources and recent surface evolution (2023)
  • Author(s): Okazaki R., Marty B., Busemann H., Hashizume K., Gilmour J. D., Meshik A., Yabuta et al.
  • Journal Title: Science Volume: 379 Pages: -
  • DOI: 10.1126/science.abo0431
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Formation and evolution of carbonaceous asteroid Ryugu: Direct evidence from returned samples (2023)
  • Author(s): Nakamura T., Matsumoto M., Amano K., Enokido Y., Zolensky M. E., Mikouchi T., Genda H., Tanaka S., Yabuta et al.
  • Journal Title: Science Volume: 379 Pages: -
  • DOI: 10.1126/science.abn8671
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Samples returned from the asteroid Ryugu are similar to Ivuna-type carbonaceous meteorites (2023)
  • Author(s): Yokoyama T., Tachibana S., Yurimoto H., Yabuta H. et al.
  • Journal Title: Science Volume: 379 Pages: -
  • DOI: 10.1126/science.abn7850
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] A dehydrated space-weathered skin cloaking the hydrated interior of Ryugu (2022)
  • Author(s): Noguchi T., Matsumoto T., Miyake A., Igami Y., Haruta M., Saito H., Hata S., Seto Y., Miyahara M., Tomioka N., Ishii H., Yabuta et al.
  • Journal Title: Nature Astronomy Volume: 7 Pages: -
  • DOI: 10.1038/s41550-022-01841-6
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Oxygen isotopes of anhydrous primary minerals show kinship between asteroid Ryugu and comet 81P/Wild2 (2022)
  • Author(s): Kawasaki N., Nagashima K., Sakamoto N., Matsumoto T., Bajo K., Wada S., Igami Y., Miyake A., Noguchi T., Yamamoto D., Russell S. S., Yabuta et al.
  • Journal Title: Science Advances Volume: 8 Pages: -
  • DOI: 10.1126/sciadv.ade2067
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Contribution of Ryugu-like material to Earth’s volatile inventory by Cu and Zn isotopic analysis (2022)
  • Author(s): Paquet M., Moynier F., T. Yokoyama, W. Dai, Y. Hu, Y., Yabuta et al.
  • Journal Title: Nature Astronomy Volume: 7 Pages: 182～189
  • DOI: 10.1038/s41550-022-01846-1
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Trace-element analysis of mineral grains in Ryugu rock fragment sections by synchrotron-based confocal X-ray fluorescence (2022)
  • Author(s): Bazi B., Tack P., Lindner M., Vekemans B., De Pauw E., Tkalcec B., Brenker F. E., Garrevoet J., Falkenberg G., Yabuta H., Yurimoto H., Nakamura T. et al.
  • Journal Title: Earth, Planets and Space Volume: 74 Pages: -
  • DOI: 10.1186/s40623-022-01726-y
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Rock Magnetic Characterization of Returned Samples From Asteroid (162173) Ryugu: Implications for Paleomagnetic Interpretation and Paleointensity Estimation (2022)
  • Author(s): Sato M., Kimura Y., Tanaka S., Hatakeyama T., Sugita S., Nakamura T., Tachibana S., Yurimoto H., Noguchi T., Okazaki R., Yabuta H. et al.
  • Journal Title: Journal of Geophysical Research: Planets Volume: 127 Pages: -
  • DOI: 10.1029/2022JE007405
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] First asteroid gas sample delivered by the Hayabusa2 mission: A treasure box from Ryugu (2022)
  • Author(s): Okazaki R., Miura Y. N., Takano Y., Sawada H., Sakamoto K., Yada T., Yamada K., Yabuta H. et al.
  • Journal Title: Science Advances Volume: 8 Pages: -
  • DOI: 10.1126/sciadv.abo7239
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Ryugu’s nucleosynthetic heritage from the outskirts of the Solar System (2022)
  • Author(s): Hopp T., Dauphas N., Yabuta H. et al.
  • Journal Title: Science Advances Volume: 8 Pages: -
  • DOI: 10.1126/sciadv.add8141
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] The Solar System calcium isotopic composition inferred from Ryugu samples (2022)
  • Author(s): Moynier F., Dai W., Yokoyama T., Hu Y., Paquet M., Yabuta H. et al.
  • Journal Title: Geochemical Perspectives Letters Volume: 24 Pages: 1～6
  • DOI: 10.7185/geochemlet.2238
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Rare earth element identification and quantification in millimetre-sized Ryugu rock fragments from the Hayabusa2 space mission (2022)
  • Author(s): Tack P., De Pauw E., Tkalec B., Lindner M., Bazi B., Vekemans B., Brenker F., Di Michiel M., Uesugi M., Yurimoto H., Nakamura T., Yabuta et al.
  • Journal Title: Earth, Planets and Space Volume: 74 Pages: -
  • DOI: 10.1186/s40623-022-01705-3
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Presolar Stardust in Asteroid Ryugu (2022)
  • Author(s): Barosch J., Nittler L., Wang J, Yabuta H. et al.
  • Journal Title: The Astrophysical Journal Letters Volume: 935 Pages: L3～L3
  • DOI: 10.3847/2041-8213/ac83bd
  • Peer Reviewed / Int'l Joint Research
• [Presentation] Initial Analysis of Macromolecular Organic Matter in the C-type Asteroid Ryugu Samples Returned by Hayabusa2 (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: Astrobiology Science Conference (AbScicon 2022)
  • Int'l Joint Research / Invited
• [Presentation] Initial Analysis of Macromolecular Organic Matter in the Asteroid Ryugu samples: Overview (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: Goldschmidt Conference 2022
  • Int'l Joint Research
• [Presentation] Hayabusa2 initial analyses of organic matter in the asteroid Ryugu samples (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: COSPAR 2022
  • Int'l Joint Research / Invited
• [Presentation] Potentiality of small body explorations to develop planetary science to frontier material science (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: COSPAR 2022
  • Int'l Joint Research
• [Presentation] An updated overview of macromolecular organic matter in the C-type asteroid Ryugu samples (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: The 85th Annual Meeting of The Meteoritical Society (MetSoc 2022)
  • Int'l Joint Research
• [Presentation] Hayabusa2 Initial Analysis of Macromolecular Organic Matter in the Asteroid Ryugu Samples (2022)
  • Author(s): Yabuta, H. et al.
  • Organizer: Japan Geoscience Union 2022 (JpGU 2022)