Investigation of deep fluid using maluti-solid-phase inclusions

2013 Fiscal Year Final Research Report

• Project/Area Number: 22244067
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: Kyoto University
• Principal Investigator: HIRAJIMA Takao 京都大学, 理学(系)研究科(研究院), 教授 (90181156)
• Co-Investigator(Kenkyū-buntansha): HIRATA Takefumi (10251612) ; OHSAWA Shinji (30243009) ; KAWKAMI Tetsuo (70415777) ; SHIMOBAYASHI Norimasa (70235688) ; MIYAKE Akira (10324609)
• Project Period (FY): 2010-04-01 – 2013-03-31
• Keywords: 変成岩 / 深部流体 / 多相固体包有物 / ICP-MS

Research Abstract

Multi-solidphase inclusions (MSIs) composed of clinozoisite (Czo) + ky + qz have been found within garnets and in the matrix of metapelits from the Makbal complex in Kyrgyz. The reconstructed compositions of MSIs are consistent with lawsonite (Lws). Petrological study showed that Lws was stable at UHP stage (ca. 3 GPa and 550C) and decomposed to the MSIs during isothermal decompression around 1.6 GPa and 550C. Trace element characteristics of Czo grains in the MSIs show a flat REE chondrite-normalized pattern, identical to the typical REE pattern of Lws. Thus, the REE content of Czo in the MSIs included in garnet was likely inherited from the former Lws as the decomposition reaction took place isolated from the matrix. Lws decomposition and Czo-forming reactions accompany fluid release during the isothermal decompression stage, implying that the fluids can be generated not only during subduction, but also during exhumation of UHP rocks in cold subduction settings.

Research Products

• [Journal Article] Ion microprobe U-Th-Pb geochronology and study of micro-inclusions in zircon from the Himalayan high- and ultrahigh-pressure eclogites, Kaghan Valley of Pakistan (2013)
  • Author(s): Hafiz Ur Rehman, Katsura Kobayashi, Tatsuki Tsujimori, Tsutomu Ota, Hiroshi Yamamoto, Eizo Nakamura, Yoshiyuki Kaneko, Tahseenullah Khan Masaru Terabayashi, Kenta Yoshida, Takao Hirajima
  • Journal Title: Journal of Asian Earth Sciences Volume: 63 Pages: 179-196
• [Journal Article] Eclogitic clasts with omphacite and pyrope-rich garnet in the NWA 801 CR2 chondrite (2013)
  • Author(s): Makoto Kimura, Naoji Sugiura, Takashi Mikouchi, Takao Hirajima, Hajime Hiyagon, and Yoshie Takehana
  • Journal Title: Am. Min Volume: 98 Pages: 387-393
• [Journal Article] Evidence of the lawsonite eclogite facies metamorphism from an epidote-glaucophane eclogite in the Kotsu area of the Sanbagawa belt, Japan (2013)
  • Author(s): Shigeki TSUCHIYA and Takao HIRAJIMA
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 108 Pages: 166-171
• [Journal Article] Discovery of diamond in the Tromsø Nappe, Scandinavian Caledonides (N.Norway) (2013)
  • Author(s): Marian Janák, Erling Krogh Ravna, Kåre Kullerud, Kenta Yoshida, Rastislav Milovský and Takao Hirajima
  • Journal Title: Journal of metamorphic Geology Volume: 31 Pages: 691-703
• [Journal Article] Behavior of zircon in the upper-amphibolite to granulite facies schist/migmatite transition, Ryoke metamorphic belt, SW Japan : constraints from the melt inclusions in zircon (2013)
  • Author(s): Kawakami, T., Yamaguchi, I., Miyake, A., Shibata, T., Maki, K., Yokoyama, T. D. & Hirata, T
  • Journal Title: Contributions to Mineralogy and Petrology Volume: 165 Pages: 575-591
• [Journal Article] Chlorine-rich fluid or melt activity during granulite facies metamorphism in the Late Proterozoic to Cambrian continental collision zone–an example from the Sør Rondane Mountains, East Antarctica (2013)
  • Author(s): Higashino, F., Kawakami, T., Satish-Kumar, M., Ishikawa, M., Maki, K., Tsuchiya, N., Grantham, G. & Hirata, T
  • Journal Title: Precambrian Research Volume: 234 Pages: 229-246
• [Journal Article] Annular fluid inclusion found from a quartz vein intercalated with metapelites from the Besshi area of the Sanbagawa belt, SW Japan (2012)
  • Author(s): YOSHIDA, K. and HIRAJIMA, T
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 107 Pages: 50-55
• [Journal Article] Prehnite-pumpellyite facies metabasites found from the Kurosegawa belt in Yatsushiro area, Kyushu, Japan (2012)
  • Author(s): KAMIMURA, K., HIRAJIMA, T. and FUJIMOTO, Y
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 107 Pages: 99-104
• [Journal Article] Exsolution of garnet and clinopyroxene from higj-Al pyroxenes in Xugou peridotite (2012)
  • Author(s): Spengler, D., Obata, M., Hirajima, T., Ottolini, L., Ohfuji, H., Tamura, A. & Arai, S
  • Journal Title: E China. Journal of Petrology Volume: 53 Pages: 1477-1504
• [Journal Article] Conformity and precision of CO2 densimetry in CO_2 inclusions : microthermometry versusRaman microspectroscopic densimetry (2012)
  • Author(s): Kobayashi, T., Yamamoto, J., Hirajima, T., Ishibashi, H., Hirano, N., Lai, Y., Prikhod'kog, V.S. and Arai, S
  • Journal Title: Journal of Raman Spectroscopy Volume: 43 Pages: 1126-1133
• [Journal Article] Geological map of the ultra-high pressure Brossasco-Isaca Unit, (Western Alps) (2012)
  • Author(s): Compagnoni, R., F. Rolfo, F. Groppo, T. Hirajima and R. Turello
  • Journal Title: Journal of Map Volume: 8 Pages: 465–472
• [Journal Article] Metamorphic history of garnet-rich gneiss at Ktišin the Lhenice shear zone, Moldanubian Zone of the southern Bohemian Massif, inferred from inclusions and compositional zoning of garnet (2011)
  • Author(s): Kobayashi, T., Hirajima, T., Kawakami, T. & Svojtka, M
  • Journal Title: Lithos Volume: 124 Pages: 46-65
• [Journal Article] Diamond and other possible ultra-deep evidence discovered in the orogenic spinel-garnet peridotite from the Moldanubian Zone of the Bohemian Massif, Czech Republic (2011)
  • Author(s): Naemura, K., Ikuta, D., Kagi, H., Odake, S., Uyeda, T., Ohi, S., Kobayashi, T., Svojtka, M., and Hirajima, T
  • Journal Title: In "Ultrahigh-Pressure Metamorphism : 25 Years After the Discovery of Coesite and Diamond" Eds : L. Dobrzhinetskaya, S.W. Faryad, S. Wallis and S. Cuthbert Volume: (Elsevier insights) Pages: 77-111
• [Journal Article] Fluid inclusions with high Li/B ratio in a quartz vein from the Besshi area of the Sambagawa metamorphic belt : implications for deep geofluid evolution (2011)
  • Author(s): YOSHIDA, K., SENGEN, Y., TSUCHIYA, S., MINAGAWA, K., KOBAYASHI, T., MISHIMA, T., OHSAWA, S., and HIRAJIMA, T
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 106 Pages: 164-168
• [Journal Article] Preiswerkite and högbomite within garnets of Aktyuz eclogite, Northern Tien Shan, Kyrgyzstan (2011)
  • Author(s): OROZBAEV, R.T., YOSHIDA, K., BAKIROV, A.B., HIRAJIMA, T., TAKASU, A., SAKIEV, K.S. and TAGIRI, M
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 106 Pages: 320-325
• [Journal Article] Analysis of Mn-bearing lawsonite occurring in meta-siliceous rocks in Hakoishi serpentinite mélange of Kurosegawa Belt, Central Kyushu, Japan (2010)
  • Author(s): Ibuki, M., Ohi, S., Tsuchiyama, A. and Hirajima, T
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 105 Pages: 340-345
• [Presentation] First evidence of the lawsonite eclogite facies metamorphism from an epidote- glaucophane eclogite in the Kotsu area of the Sanbagawa belt, Japan (2013)
  • Author(s): Takao HIRAJIMA, Shigeki TSUCHIYA
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Microdiamonds in crustal rocks of the Tromsø Nappe, Scandinavian Caledonides (N.Norway) (2013)
  • Author(s): Marian Janák, Erling J. Krogh Ravna, Kåre Kullerud, Kenta Yoshida, Rastislav Milovský, Takao Hirajima
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] High-pressure melting and rapid exhumation of Grt-rich gneiss at Ktišin the Lhenice shear zone (Moldanubian Zone of the southern Bohemian Massif) (2013)
  • Author(s): T. KOBAYASHI , S. L. HARLEY, Y. HIROI, T. HIRAJIMA, and M. SVOJTKA
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Garnet zonings created under open-system environments and short-lived heating of Nové Dvory UHP-UHT eclogite (2013)
  • Author(s): Daisuke Nakamura, Norimasa Shimobayashi, Tadashi Usuki, Takao Hirajima, Martin Svojtka
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Subduction history of the garnet lherzolites in the Moldanubian zone of the Bohemian Massif (2013)
  • Author(s): Naemura, K., Hirajima, T., Wei, C.J. and Svojtka, M
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Trace element characteristics of lawsonite pseudomorphs in talc-garnet-chloritoid schists, Makbal UHP complex, Kyrgyz Tien-Shan (2013)
  • Author(s): Orozbaev, R., Hirajima, T., Bakirov, A., Takasu, A., Maki, K., Yoshida, K., Sakiev, K. and Hirata, T
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Trace element characteristics of multiphase solid inclusions in garnets of Aktyuz eclogite, Kyrgyz Tien-Shan : implications for fluids activity at high-pressure conditions (2013)
  • Author(s): Orozbaev, R., Hirajima, T., Bakirov, A., Takasu, A., Maki, K., Yoshida, K., Sakiev, K. and Hirata, T
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Variation and significance of chemical zoning patterns of garnet in Nove Dvory eclogite, Moldanubian Zone of the Bohemian Massif (2013)
  • Author(s): Atsushi YASUMOTO, Takao HIRAJIMA, Daisuke NAKAMURA, Martin Svojtka
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Chemical facies and B-Li-Cl relative compositions of deep-fluids trapped in HP/LT metamorphic rocks : a case study in the Sanbagawa metamorphic belt, SW Japan (2013)
  • Author(s): YOSHIDA, K., T. HIRAJIMA, S. OHSAWA , T. KOBAYASHI, T. MISHIMA, and Y. SENGEN
  • Organizer: X International Ecologite Conf.Abstract
  • Place of Presentation: Courmayeur, Italy
  • Year and Date: 20130902-10
• [Presentation] Naに富む白雲母の組成改変から読み取った三波川変成帯上昇期の流体流入, Exhumation stage fluid migration recorded in Na-rich phengite in Sanbagawa metamorphic rocks (2013)
  • Author(s): Yoshida Kenta and Hirajima Takao
  • Organizer: 地球惑星科学連合大会2013年大会
  • Place of Presentation: 千葉, 幕張メッセ国際会議場
  • Year and Date: 20130520-24
• [Presentation] Variation and significance of chemical zoning pattern of Grt in Nove Dvory eclogoite, Moldanubian Zone of the Bohemian Massif (2013)
  • Author(s): Atsushi YASUMOTO, Takao Hirajima & Daisuke Nakamura
  • Organizer: 地球惑星科学連合大会2013年大会
  • Place of Presentation: 千葉, 幕張メッセ国際会議場
  • Year and Date: 20130520-24
• [Presentation] Behaviour of REE-rich minerals during Cl-rich fluid activity under granulite facies metamorphism (2013)
  • Author(s): 東野文子, 河上哲生, サティシュ・クマール, 石川正弘, 土屋範芳, ジェフ・グランサム
  • Organizer: 地球惑星科学連合大会2013年大会
  • Place of Presentation: 千葉, 幕張メッセ国際会議場
  • Year and Date: 20130520-24
• [Presentation] Rare-earth and trace element characteristics of pseudomorphs after lawsonite in Tlc-Grt-Cld schists of Makbal Complex (2013)
  • Author(s): Orozbaev, R., Hirajima, T., Bakirov, A., Takasu, A., Maki, K., Yoshida, K., Sakiev, K. and Hirata, T
  • Organizer: 地球惑星科学連合大会2013年大会
  • Place of Presentation: 千葉, 幕張メッセ国際会議場
  • Year and Date: 20130520-24
• [Presentation] 大陸衝突帯で見られる複数段階の塩素に富む流体活動と希土類元素に富む鉱物の挙動 (2013)
  • Author(s): 東野文子, 河上哲生, サティシュ・クマール, 土屋範芳, 石川正弘, ジェフ・グランサム
  • Organizer: 日本鉱物科学会2013年年会
  • Place of Presentation: つくば
  • Year and Date: 2013-09-14
• [Presentation] Grantham, G.H.,: Multi-stage Cl-rich fluid activity and behavior of REE-bearing minerals in a Neoproterozoic granulite terrane., Mineralogical Magazine, 77(5) 1298 (2013)
  • Author(s): Higashino, F., Kawakami, T., Satish-Kumar, M., Ishikawa, M., Tsuchiya, N
  • Organizer: Goldschmidt2013
  • Place of Presentation: Florence
  • Year and Date: 2013-08-29