2012 Fiscal Year Final Research Report
Development and functionalization of Mobius aromaticity
| Project/Area Number |
22245006
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (A)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
OSUKA Atsuhiro 京都大学, 大学院・理学研究科, 教授 (80127886)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Keywords | ポルフィリン / 環拡張ポルフィリン / メビウス芳香族性 / メビウス反芳香族性 |
|---|
| Research Abstract |
In order to reveal fundamental insights about Mobius aromatic molecules, we’ve achieved 1) the syntheses of Mobius antiaromatic molecules 2) developments of new synthetic methods, and 3) peripheral functionalizations of Mobius molecules. In addition, we have developed typical element complexes, novel metal complexes, and stable antiaromatic molecules with intriguing physical properties.
|
-
-
-
-
-
-
-
-
-
[Journal Article] Neutral Radical and Singlet Biradical Forms of Meso-Free, -Keto, and -Diketo Hexaphyrins(1.1.1.1.1.1): Effects on Aromaticity and Photophysical Properties2011
Author(s)
Ishida, M.; Shin, J.-Y.; Lim, J.M.; Lee,B.S.; Yoon,M.-C.; Koide,T,; Sessler, J.; Osuka, A.
-
Journal Title
Kim,D, J. Am. Chem. Soc.
Volume: 133
Pages: 15533-15544
DOI
Peer Reviewed
-
-
-
-
-
[Journal Article] A Stable Non-Kekul Singlet Biradicaloid from meso-Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)2010
Author(s)
Koide, T.; Furukawa, K.; Shinokubo, H.; Shin, J.-Y.; Kim, K. S.; Kim, D.; Osuka, A.
-
Journal Title
J. Am. Chem. Soc.
Volume: 132
Pages: 7246-7247
DOI
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
