Synthesis of Novel Materials Based on Square Planar Iron and Exploringof Room Temperature Functionality

2012 Fiscal Year Final Research Report

• Project/Area Number: 22245009
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Kyoto University
• Principal Investigator: KAGEYMA Hiroshi 京都大学, 大学院・工学研究科, 教授 (40302640)
• Co-Investigator(Kenkyū-buntansha): TAKANO Mikio 京都大学, 物質-細胞統合システム拠点, 教授 (70068138) ; KAWAKAMI Takateru 日本大学, 理工学部, 講師 (20366561) ; HAYASHI Naoaki 京都大学, 学際融合教育研究推進センター, 特定業務専門職員 (70346047) ; OKADA Taku 東京大学, 物性研究所, 助教 (90343938)
• Project Period (FY): 2010 – 2012
• Keywords: スピン転移 / 平面四配位鉄 / 高圧 X 線回折 / 高圧メスバウアー

Research Abstract

We have obtained novel square planar iron oxides by Mn, Co, Lanthanoides substitution of SrFeO2. We have revealed origin of the pressure-induced spin transition (S = 2 to 1) in square planar iron oxides, and observed further pressure-induced spin transition (S = 1 to 0) in SrFeO2. Moreover, we have revealed that Eu substitution of SrFeO2 significantly decreases the spin transition pressure. We synthesized a new cubic Fe 4+ perovskite BaFeO3, and revealed that BaFeO3 is the first reported Fe oxide that shows ferromagnetism at ambient pressure

Research Products

• [Journal Article] Bulk modulus and structural changes of carbon nitride C2N2(CH2) under pressure: The strength of C–N single bond (2013)
  • Author(s): M. Sougawa, K. Takarabe, Y. Mori, T. Okada, T. Yagi, H. Kariyazaki, K. Sueoka
  • Journal Title: Journal of Applied Physics Volume: 113 Pages: 1-5
  • DOI: DOI:10.1063/1.4789020
  • Peer Reviewed
• [Journal Article] Anomalous behavior of cristobalite in heliumunder high pressure (2013)
  • Author(s): T. Sato, H. Takada, T. Yagi, H. Gotou, T. Okada, D. Wakabayashi, N. Funamori
  • Journal Title: Physics and Chemistry of Minerals Volume: 40 Pages: 3-10
  • DOI: DOI:10.1007/s00269-012-0540-x
  • Peer Reviewed
• [Journal Article] Square Planar Coordinate Iron Oxides (2012)
  • Author(s): Cedric Tassel and Hiroshi Kageyama
  • Journal Title: Chem. Soc. Rev Volume: 41 Pages: 2025-2035
  • DOI: DOI:10.1039/C1CS15218A
  • Peer Reviewed
• [Journal Article] High-pressure phase of vanadium pentaoxide (2012)
  • Author(s): A. K. Arora, T. Sato, T. Okada and T. Yagi
  • Journal Title: PHYSICAL REVIEW B Volume: 85巻 Pages: 94413
  • DOI: DOI:10.1103/PhysRevB.85.094113
  • Peer Reviewed
• [Journal Article] Stripelike magnetismin a mixed- valence insulating state of the Fe- based ladder compound CsFe2Se3 (2012)
  • Author(s): F. Du, K. Ohgushi, Y. Nambu, T. Kawakami, M. Avdeev, Y. Hirata, Y. Watanabe, T. J Sato, and Y. Ueda
  • Journal Title: Phys. Rev. B Volume: 85巻 Pages: 214436
  • DOI: DOI:10.1103/PhysRevB.85.214436
  • Peer Reviewed
• [Journal Article] Pressure Effect on Intersite Charge Transfer in A- site- Ordered DoublePerovskite- Structure Oxide (2012)
  • Author(s): Y. W. Long, T. Kawakami, W. T. Chen, T. Saito, T. Watanuki, Y. Nakakura, Q.Q. Liu, C. Q. Jin, and Y. Shimakawa
  • Journal Title: Chem. Mater Volume: 24巻 Pages: 2235-2239
  • Peer Reviewed
• [Journal Article] Ion- Exchange Reaction for Two- Dimensional QunatumAntiferromagnetism (2012)
  • Author(s): Yoshihiro Tsujimoto and Hiroshi Kageyama
  • Journal Title: INTECH Volume: Chapter2 Pages: 9-34
  • Peer Reviewed
• [Journal Article] Selective Preparation of Conducting Macroporous Monoliths of Reduced TitaniumOxides TinO2n- 1 (n=2,3,4,6) (2012)
  • Author(s): Atsushi Kitada, George Hasegawa, Yoji Kobayashi, Kazuyoshi Kanamori, Kazuki Nakanishi, and Hiroshi Kageyama
  • Journal Title: J. Am. Chem. Soc Volume: 134巻 Pages: 10894-10898
  • DOI: DOI:10.1021/ja302083n
  • Peer Reviewed
• [Journal Article] (Sr1- xBax)FeO2 (0.4 ≤ x ≤ 1): a New Oxygen Deficient Perovskite Structure (2012)
  • Author(s): Takafumi Yamamoto, Yoji Kobayashi, Naoaki Hayashi, Cédric Tassel, Takashi Saito, Shoji Yamanaka, Mikio Takano, Kenji Ohoyama, Yuichi Shimakawa, Kazuyoshi Yoshimura, and Hiroshi Kageyama
  • Journal Title: J. Am. Chem. Soc. Volume: 134 (28) Pages: 11444- 11454
  • DOI: DOI:10.1021/ja3007403
  • Peer Reviewed
• [Journal Article] First Single-Crystal Synthesis and Low Temperature Structural Determination of the Quasi-2D Quantum Spin Compound (CuCl)LaNb2O7 (2011)
  • Author(s): Olivier J. Hernandez
  • Journal Title: Dalton Trans., published online
  • DOI: DOI:10.1039/C0DT01665A
  • Peer Reviewed
• [Journal Article] Highly-Reduced Anatase TiO2-δ Thin Films via Low-Temperature Reduction (2011)
  • Author(s): A. Kitada
  • Journal Title: App. Phys. Exp Volume: 4 Pages: 035801, 1-3
  • DOI: DOI:10.1143/APEX.4.035801
  • Peer Reviewed
• [Journal Article] BaFeO3, a Ferromagnetic Iron Oxide, Angewandte Chemie (2011)
  • Author(s): Naoaki Hayashi,* Takafumi Yamamoto, Hiroshi Kageyama, Masakazu Nishi, Yoshitaka Watanabe, Takateru Kawakami, Yoshitaka Matsushita, Atsushi Fujimori, and Mikio Takano
  • Journal Title: International Edition Volume: 123巻 Pages: 12755-12758
  • DOI: DOI:10.1002/ange.201105276
  • Peer Reviewed
• [Journal Article] Compression behaviors of binary skutterudite CoP3 in noble gases up to 40 GPa at room temperature (2011)
  • Author(s): K. Niwa, D. Nomichi, M. Hasegawa, T. Okada, T. Yagi and T. Kikegawa
  • Journal Title: INORGANIC CHEMISTRY Volume: 50巻 Pages: 3281-3285
  • DOI: DOI:10.1021/ic101916c
  • Peer Reviewed
• [Journal Article] Pressure-induced structural, magnetic, and transport transitions in the two-legged ladder Sr3Fe2O5 (2011)
  • Author(s): T. Yamamoto, C. Tassel, Y. Kobayashi, T. Kawakami, T. Okada, T. Yagi, H. Yoshida, T. Kamatani, Y. Watanabe, T. Kikegawa, M. Takano, K. Yoshimura and H. Kageyama
  • Journal Title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Volume: 133巻 Pages: 6036-6043
  • DOI: DOI:10.1021/ja200410z
  • Peer Reviewed
• [Journal Article] B1-to-B2 Structural Transitions in Rock Salt Intergrowth Structures (2011)
  • Author(s): T. Yamamoto, Y. Kobayashi, T. Okada, T. Yagi, T. Kawakami, C. Tassel, S. Kawasaki, N. Abe, K. Niwa, T. Kikegawa, N. Hirao, M. Takano, and H. Kageyama
  • Journal Title: Inorg. Chem. Volume: 50巻 Pages: 11787-11794
  • DOI: DOI:10.1021/ic201901a
  • Peer Reviewed
• [Journal Article] Fe-Site Substitution Effect on the Structural and Magnetic Properties in SrFeO2 (2011)
  • Author(s): Liis Seinberg, Takafumi Yamamoto, Cedric Tassel, Yoji Kobayashi, Naoaki Hayashi, Atsushi Kitada, Yuji Sumida, Takashi Watanabe, Masakazu Nishi, Kenji Ohoyama, Kazuyoshi Yoshimura, Mikio Takano, Werner Paulus, and Hiroshi Kageyama
  • Journal Title: Inorg. Chem Volume: 50巻 Pages: 3998-3995
  • DOI: DOI:10.1021/ic102467u
  • Peer Reviewed
• [Journal Article] Synthesis and Thermal Stability of the Solid Solution AFeO2 (A = Ba, Sr, Ca) (2010)
  • Author(s): Takafumi Yamamoto
  • Journal Title: Inorg. Chem Volume: 49 Pages: 5957-5962
  • DOI: DOI:10.1021/ic100452m
  • Peer Reviewed
• [Journal Article] 57Fe Mossbauer Spectroscopic Study on Fe2+-Oxides with Infinite-Layer and Ladder Structures (2010)
  • Author(s): NaoakiHayashi
  • Journal Title: J. Phys. Soc. Jpn Volume: 79巻 Pages: 123709, 1-4
  • DOI: DOI:10.1143/JPSJ.79.123709
• [Journal Article] High-spin to Intermediate-spin Transition, Insulator-metalTransition,and Antiferro- to Ferromagnetic Transition in SrFeO2 under High Pressure (2010)
  • Author(s): Takateru Kawakami and Hiroshi Kageyama
  • Journal Title: Zeitschrift fur Kristallographie Volume: 225 Pages: 504-507
  • DOI: DOI:10.1524/zkri.2010.1311
• [Journal Article] Structural analysis of pressure-amorphized zirconium tungstate (2010)
  • Author(s): Arora AK
  • Journal Title: PHYSICAL REVIEW B Volume: 81 Pages: 134103
  • DOI: DOI:10.1103/PhysRevB.81.134103
  • Peer Reviewed
• [Presentation] Ferromagnetic Iron Oxide: BaFeO3 (2013)
  • Author(s): Naoaki Hayashi, Tetsuharu Kawakami, and Mikio Takano
  • Organizer: The 11th International Conference on Ferrites(招待講演)
  • Place of Presentation: 沖縄コンベンションセンター(沖縄県)
  • Year and Date: 20130415-19
• [Presentation] 平面四配位構造をもつ鉄酸化物の圧力誘起スピン転移 (2013)
  • Author(s): 川上隆輝
  • Organizer: 第14回メスバウアー研究会シンポジウム
  • Place of Presentation: 東レリサーチセンター(滋賀県)
  • Year and Date: 20130325-26
• [Presentation] 平面四配位鉄酸化物の合成、構造、物性 (2013)
  • Author(s): 山本隆文,小林洋治,陰山洋
  • Organizer: 日本化学会第93 春季年会
  • Place of Presentation: 立命館大学(京都府)
  • Year and Date: 20130322-25
• [Presentation] Structure and Reactivity of TitaniumPerovskite Oxyhydrides (2013)
  • Author(s): Hiroshi Kageyama
  • Organizer: Mardi Gras Symposium2013 – Reaction Strategies for Directing Structure and Properties in the Solid State(招待講 演)
  • Place of Presentation: University of NewOrleans, USA
  • Year and Date: 20130208-09
• [Presentation] 酸化物の配位コントロール (2013)
  • Author(s): 陰山洋
  • Organizer: 分子研研究会「無機化学の現状と未来:若い世代が切り開く新 しいサイエンス」(招待講演)
  • Place of Presentation: 岡崎コンファレンスセンター(愛知県)
  • Year and Date: 20130117-19
• [Presentation] Anionic Control of Function in Metal Oxides (2013)
  • Author(s): Hiroshi Kageyama
  • Organizer: 1st Bristol-Kyoto Symposium
  • Place of Presentation: University of Bristol, UK
  • Year and Date: 20130110-11
• [Presentation] BaFeO2 の合成、構造、物性 (2013)
  • Author(s): 山本隆文,小林洋治,陰山洋
  • Organizer: 第51回セラミックス基礎科学討論会
  • Place of Presentation: 仙台国際センター(宮城県)
  • Year and Date: 20130109-10
• [Presentation] 遷移金属ヒドリド含有セラミックス (2012)
  • Author(s): 陰山洋
  • Organizer: 日本セラミックス協会第25回秋季シンポジウム(招待講演)
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 20120919-21
• [Presentation] 3d 遷移金属酸化物をベースとした低温反応 - ハイブリッドから酸水素化物まで - (2012)
  • Author(s): 陰山洋
  • Organizer: 日本化学会新領域研究グループ「低次元無機-有機複合系の 光化学」第5回研究講演会(招待講演)
  • Place of Presentation: 化学会館(東京都)
  • Year and Date: 20120511-12
• [Presentation] 平面四配位鉄酸化物の構造と磁性 (2012)
  • Author(s): 山本隆文,陰山洋
  • Organizer: Future Neutron Star 講演,日本中性子科学会第12回年会
  • Place of Presentation: 京都大学(京都府)
  • Year and Date: 2012-12-11
• [Presentation] 酸化物配位化学:低温合成 (2012)
  • Author(s): 陰山洋
  • Organizer: 第73回応用物理学会学術講演会 特別シンポジウム「ここまでき た酸化物材料科学:創造と成功の本質」(招待講演)
  • Place of Presentation: 松山大学(愛媛県)
  • Year and Date: 2012-09-12
• [Presentation] 低温化学による酸化物の組成、構造、物性制御 (2011)
  • Author(s): 陰山 洋
  • Organizer: 北海道大学 GCOE シンポジウム「物性・デバイスから見た無機物質化学」(招待講演)
  • Place of Presentation: 北海道大学(北海道)
  • Year and Date: 2011-11-18
• [Presentation] 高圧下におけるSrFe0.8Co0.2O2 のスピン転移 (2011)
  • Author(s): 石井穣、 川上隆輝、渡邉喜貴、山本隆文、陰山洋、高野幹夫
  • Organizer: 第52回高圧討論会
  • Place of Presentation: 那覇市・沖縄キリスト教学院(沖縄県)
  • Year and Date: 2011-11-09
• [Presentation] 酸素の通り道:ペロブスカイトを舞台とした低温反応 (2011)
  • Author(s): 陰山 洋
  • Organizer: 計算物質科学研究センター第1回シンポジウム～『京』と大型実験施設の連携に向けて～(招待講演)
  • Place of Presentation: 東京大学物性研究所(千葉県)
  • Year and Date: 2011-09-13
• [Presentation] ソフト化学による酸化物の構造・機能制御 (2011)
  • Author(s): 陰山 洋
  • Organizer: 日本セラミックス協会関西支部第6回学術講演会
  • Place of Presentation: イーグレ姫路(兵庫県)
  • Year and Date: 2011-07-29
• [Presentation] Reactivity and Physical Properties of Transition-Metal Perovskite Oxides (2011)
  • Author(s): Hiroshi Kageyama
  • Organizer: 17th International Symposium on the Reactivity of Solids(招待講演)
  • Place of Presentation: ICMCB(ボルドー・フランス)
  • Year and Date: 2011-06-28
• [Presentation] 金属水素化物による還元反応の現状 (2010)
  • Author(s): 陰山 洋
  • Organizer: 第3回ワークショップ「固体材料合成および評価技術の新展開」(招待講演)
  • Place of Presentation: 河口湖足和田ホテル(山梨県)
  • Year and Date: 2010-09-03
• [Presentation] Synthesis, Structure and Physical Properties of Square-Planar Coordinate Iron Oxides (2010)
  • Author(s): Hiroshi Kageyama
  • Organizer: 3rd International Symposium on Structure-Property Relationships in Solid State Materials (SPSSM-2010)(招待講演)
  • Place of Presentation: ドイツ、シュツガルト
  • Year and Date: 2010-06-28
• [Presentation] Spin Transition in Four-Coordinated Iron Oxides (2010)
  • Author(s): Hiroshi Kageyama
  • Organizer: Advances in Magnetism: Phenomena and Materials (AMPM 2010)(招待講演)
  • Place of Presentation: インド、マナリ
  • Year and Date: 2010-06-04
• [Presentation] 平面四配位鉄酸化物における異常な熱膨張 (2010)
  • Author(s): 陰山 洋
  • Organizer: 文部科学省ナノテクノロジー・ネットワーク/重点ナノテクノロジー支援 放射光利用研究成果報告会「ナノテクノロジー放射光利用研究の最前線2009」(招待講演)
  • Place of Presentation: 立命館大学(京都府)
  • Year and Date: 2010-05-07