2013 Fiscal Year Final Research Report
Development of Innovative Synthetic Reactions Using Group 7 Metals as Catalysts, Reagents, or Probes
| Project/Area Number |
22245017
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Okayama University |
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Principal Investigator |
TAKAI KAZUHIKO 岡山大学, 自然科学研究科, 教授 (00144329)
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| Co-Investigator(Kenkyū-buntansha) |
KUNINOBU Yoichiro 東京大学, 大学院薬学系研究科, 准教授 (40372685)
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| Project Period (FY) |
2010-04-01 – 2014-03-31
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| Keywords | レニウム / マンガン / Ｃ－Ｈ結合活性化 / Ｃ－Ｃ結合切断 / 均一系錯体 / 触媒反応 |
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| Research Abstract |
Rhenium is not a popular element in organic synthesis. Through this research, we tried to clarify the features of the metal, especially unknown and useful reactivities for organic synthesis. We have found the following synthetic reactions by using rhenium complexes as probes. (1) Lewis-acid catalyzed reactions with rhenium complexes. (2) Reactions based on the C(sp2)-H bond activation with rhenium complexes. (3) Reactions based on the C-C bond cleavage between carbonyl and -carbons with rhenium complexes. (4) Formation of heteroatom-carbon bonds by activation of heteroatom-hydrogen and C-H bonds at proximity positions. (5) Novel C-C bond cleavage reactions catalyzed by other transition metals than rhenium.
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Research Products
(50 results)
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[Presentation] Indium-Catalyzed Retro- Claisen Rearrangement2010
Author(s)
Shun-ichi Yamamoto, Atsushi Kawata, Taihei Noborio, Takashi Matsuki, Kazumi Takata, Yoichiro Kuninobu, Kazuhiko Takai
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
Place of Presentation
Honolulu
Year and Date
20101215-20
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