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2013 Fiscal Year Final Research Report

The development of innovative fast photo-switching materials based on chiral fast photochromic molecules

Research Project

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Project/Area Number 22245025
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionAoyama Gakuin University

Principal Investigator

ABE Jiro  青山学院大学, 理工学部, 教授 (70211703)

Project Period (FY) 2010-04-01 – 2014-03-31
Keywordsフォトクロミズム / イミダゾール二量体 / 液晶 / 光学活性 / 光スイッチ / ホログラム
Research Abstract

From the viewpoint of the development of innovative fast photo-switching materials based on chiral fast photochromic molecules, we promoted the development of the real-time dynamic hologram materials, real-time control of the helical pitch of chiral nematic liquid crystalline phase, and fast photochromic fluorescence switch molecules for the application of fluorescence probes of super-resolution microscopy. The outstanding research result is the success of the real-time dynamic hologram of a 3D object.

  • Research Products

    (39 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (14 results) (of which Invited: 10 results) Book (3 results) Remarks (1 results)

  • [Journal Article] Electrochemistry of photochromic [2.2] paracyclophane-bridged imidazole dimers : Rational understanding of the electronic structures2014

    • Author(s)
      Emi Nakano, Katsuya Mutoh, Yoichi Kobayashi, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 118(12) Pages: 2288-2297

    • DOI

      10.1021/jp412672a

    • Peer Reviewed
  • [Journal Article] Enhancing the versatility and functionality of fast photochromic bridged-imidazole dimers by flipping imidazole rings2014

    • Author(s)
      Kentaro Shima, Katsuya Mutoh, Yoichi Kobayashi, Jiro Abe
    • Journal Title

      J. Am. Chem. Soc

      Volume: 136(10) Pages: 3796-3799

    • DOI

      10.1021/ja501028v

    • Peer Reviewed
  • [Journal Article] Remarkable solvatochromic color change via proton tautomerism of a phenol-linked imidazole derivative2014

    • Author(s)
      Hiroaki Yamashita, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 118(8) Pages: 1430-1438

    • DOI

      10.1021/jp5007928

    • Peer Reviewed
  • [Journal Article] Multistate photochromism of 1-phenylnaphthalene-bridged imidazole dimer that has three colorless isomers and two colored isomers2014

    • Author(s)
      Tetsuo Yamaguchi, Sayaka Hatano, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 118(1) Pages: 134-143

    • DOI

      10.1021/jp411190d

    • Peer Reviewed
  • [Journal Article] Insights into the recombination of radical pair in hexaarylbiimidazoles2013

    • Author(s)
      Stephanie Delbaere, Maylis Orio, Jerome Berthet, Michel Sliwa, Sayaka Hatano, Jiro Abe
    • Journal Title

      Chem. Commun

      Volume: 49 Pages: 5841-5843

    • DOI

      10.1039/C3CC43037E

    • Peer Reviewed
  • [Journal Article] Photochromism of a naphthalene-bridged imidazole dimer constrained to the "anti" conformation2013

    • Author(s)
      Katsuya Mutoh, Kentaro Shima, Tetsuo Yamaguchi, Masayuki Kobayashi, Jiro Abe
    • Journal Title

      Org. Lett

      Volume: 15(12) Pages: 2938-2941

    • DOI

      10.1021/ol401012u

    • Peer Reviewed
  • [Journal Article] Fast photochromism in polymer matrix with plasticizer and real-time dynamic holographic properties2013

    • Author(s)
      Norihito Ishii, Jiro Abe
    • Journal Title

      Appl. Phys. Lett

      Volume: 102 Pages: 163301

    • DOI

      10.1063/1.4803025

    • Peer Reviewed
  • [Journal Article] Rapid fluorescence switching by using a fast photochromic [2.2] paracyclophane-bridged imidazole dimer2013

    • Author(s)
      Katsuya Mutoh, Michel Sliwa, Jiro Abe
    • Journal Title

      J. Phys. Chem. C

      Volume: 117(9) Pages: 4808-4814

    • DOI

      10.1021/jp309917s

    • Peer Reviewed
  • [Journal Article] Unusual negative photochromism via a short-lived imidazolyl radical of 1,1'-binaphthyl-bridged imidazole dimer2013

    • Author(s)
      Sayaka Hatano, Takeru Horino, Atsuhiro Tokita, Toyoji Oshima, Jiro Abe
    • Journal Title

      J. Am. Chem. Soc

      Volume: 135(8) Pages: 3164-3172

    • DOI

      10.1021/ja311344u

    • Peer Reviewed
  • [Journal Article] A real-time dynamic holographic material using a fast photochromic molecule2012

    • Author(s)
      Norihito Ishii, Tetsuya Kato, Jiro Abe
    • Journal Title

      Sci. Rep

      Volume: 2 Pages: 819

    • DOI

      10.1038/srep00819

    • Peer Reviewed
  • [Journal Article] Spectroelectrochemistry of a photochromic [2.2] paracyclophane-bridged imidazole dimer : Clarification of the electrochemical behavior of HABI2012

    • Author(s)
      Katsuya Mutoh, Emi Nakano, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 116(25) Pages: 6792-6797

    • DOI

      10.1021/jp3038973

    • Peer Reviewed
  • [Journal Article] A peroxide-bridged imidazole dimer formed from a photochromic naphthalene-bridged imidazole dimer2012

    • Author(s)
      Sayaka Hatano, Jiro Abe
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 14 Pages: 5855-5860

    • DOI

      10.1039/C2CP40239D

    • Peer Reviewed
  • [Journal Article] Entropy-controlled thermal back-reaction of photochromic [2.2] paracyclophane-bridged imidazole dimer2012

    • Author(s)
      Shigekazu Kawai, Tetsuo Yamaguchi, Tetsuya Kato, Sayaka Hatano, Jiro Abe
    • Journal Title

      Dyes Pigm

      Volume: 92(2) Pages: 872-876

    • DOI

      10.1016/j.dyepig.2011.04.009

    • Peer Reviewed
  • [Journal Article] Photochromic properties of [2.2] paracyclophane-bridged imidazole dimer with increased photosensitivity by introducing pyrenyl moiety2011

    • Author(s)
      Hiroaki Yamashita, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 115(46) Pages: 13332-13337

    • DOI

      10.1021/jp204440s

    • Peer Reviewed
  • [Journal Article] Reversible photogeneration of a stable chiral radical-pair from a fast photochromic molecule2011

    • Author(s)
      Sayaka Hatano, Kana Fujita, Nobuyuki Tamaoki, Takashi Kaneko, Takuya Nakashima, Masanobu Naito, Tsuyoshi Kawai, Jiro Abe
    • Journal Title

      J. Phys. Chem. Lett

      Volume: 2(21) Pages: 2680-2682

    • DOI

      10.1021/jz2012935

    • Peer Reviewed
  • [Journal Article] Photochromism of a water-soluble vesicular [2.2] paracyclophane-bridged imidazole dimer2011

    • Author(s)
      Katsuya Mutoh, Jiro Abe
    • Journal Title

      Chem. Commun

      Volume: 47(31) Pages: 8868-8870

    • DOI

      10.1039/C1CC12640G

    • Peer Reviewed
  • [Journal Article] Comprehensive understanding of structure-photosensitivity relationships of photochromic [2.2] paracyclophane-bridged imidazole dimers2011

    • Author(s)
      Katsuya Mutoh, Jiro Abe
    • Journal Title

      J. Phys. Chem. A

      Volume: 115(18) Pages: 4650-4656

    • DOI

      10.1021/jp201969q

    • Peer Reviewed
  • [Journal Article] Photochromic Organogel Based on [2.2] Paracyclophane-Bridged ImidazoleDimer with Tetrapodal Urea Moieties2011

    • Author(s)
      Masahiro Takizawa, Atsushi Kimoto, Jiro Abe
    • Journal Title

      Dyes Pigm

      Volume: 89(3) Pages: 254-259

    • DOI

      10.1016/j.dyepig.2010.03.019

    • Peer Reviewed
  • [Journal Article] Unprecedented radical-radical reaction of a [2.2] paracyclophane derivative containing an imidazolyl radical moiety2010

    • Author(s)
      Sayaka Hatano, Ken Sakai, Jiro Abe
    • Journal Title

      Org. Lett

      Volume: 12(18) Pages: 4152-4155

    • DOI

      10.1021/ol1017933

    • Peer Reviewed
  • [Journal Article] Pentaarylbiimidazole, PABI : An easily synthesized fast photohromic molecules with superior durability

    • Author(s)
      Hiroaki Yamashita, Jiro Abe
    • Journal Title

      Chem. Commun

      Volume: (印刷中)

    • DOI

      10.1039/c4cc03137g

    • Peer Reviewed
  • [Journal Article] Chiral BINOL-bridged imidazole dimer possessing sub-millisecond fast photochromism

    • Author(s)
      Takahiro Iwasaki, Tetsuya Kato, Yoichi Kobayashi, Jiro Abe
    • Journal Title

      Chem. Commun

      Volume: (印刷中)

    • DOI

      10.1039/c4cc02710h

    • Peer Reviewed
  • [Presentation] 架橋型イミダゾール二量体の高速および逆フォトクロミズム2014

    • Author(s)
      阿部二朗
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(愛知県)
    • Year and Date
      2014-03-30
  • [Presentation] Unusual negative photochromism via a biradical of biaryl-bridged imidazole dimer2013

    • Author(s)
      Jiro Abe
    • Organizer
      International Symposium on Photochromism 2013 (ISOP-2013)
    • Place of Presentation
      Humoldt-Universitat zu Berlin (ドイツ)
    • Year and Date
      2013-09-23
    • Invited
  • [Presentation] 高速フォトクロミック分子の開発2013

    • Author(s)
      阿部二朗
    • Organizer
      2013 年光化学討論会
    • Place of Presentation
      愛媛大学城北地区(愛媛県)
    • Year and Date
      2013-09-12
  • [Presentation] Unusual negative photochromism of biaryl-bridged imidazole dimer2013

    • Author(s)
      Jiro Abe
    • Organizer
      International Conference on Photochemistry 2013 (ICP2013)
    • Place of Presentation
      Leuven (Belgium)
    • Year and Date
      2013-07-25
    • Invited
  • [Presentation] 実用化を目指した高速フォトクロミック分子の高機能化2013

    • Author(s)
      阿部二朗
    • Organizer
      第13回リング・チューブ超分子研究会シンポジウム
    • Place of Presentation
      東工大すずかけ台キャンパス(神奈川県)
    • Year and Date
      2013-02-22
    • Invited
  • [Presentation] 高速フォトクロミック分子の開発2012

    • Author(s)
      阿部二朗
    • Organizer
      東北ポリマー懇話会いわき地区講演会
    • Place of Presentation
      株式会社クレハ いわき事業所(福島県)
    • Year and Date
      2012-12-14
    • Invited
  • [Presentation] Real-time photocontrol of chiral nematic liquid crystalline phases by the fast photochromic molecules2012

    • Author(s)
      阿部二朗
    • Organizer
      6th Japanese-Italian Workshop on Liquid Crystals
    • Place of Presentation
      東京理科大学森戸記念館(東京都)
    • Year and Date
      2012-07-26
    • Invited
  • [Presentation] Recent development of the fast photochromic [2.2] paracyclophane-bridged imidazole dimers2012

    • Author(s)
      Jiro Abe
    • Organizer
      XXIVth IUPAC Symposium on Photochemistry
    • Place of Presentation
      コインブラ(ポルトガル)
    • Year and Date
      2012-07-17
  • [Presentation] Development of fast photochromic molecules2012

    • Author(s)
      Jiro Abe
    • Organizer
      The 16th International Symposium on Advanced Display Materials and Devices (ADMD 2012)
    • Place of Presentation
      チェジュ(韓国)
    • Year and Date
      2012-06-28
    • Invited
  • [Presentation] 高速フォトクロミック分子の開発と新機能創成2011

    • Author(s)
      阿部二朗
    • Organizer
      第5回有機π電子系シンポジウム
    • Place of Presentation
      ホテルアウィーナ大阪(大阪府)
    • Year and Date
      2011-11-25
    • Invited
  • [Presentation] Fast Photochromism of [2.2] paracyclophane-Bridged Imidazole Dimers2011

    • Author(s)
      Jiro Abe
    • Organizer
      14th Asian Chemical Congress (14ACC)
    • Place of Presentation
      Queen Sirikit National Convention Center バンコク(タイ王国)
    • Year and Date
      2011-09-08
    • Invited
  • [Presentation] 高速フォトクロミック分子の開発と将来展望2010

    • Author(s)
      阿部二朗
    • Organizer
      分子研所長招聘研究会「2020 年の物質分子科学を語る」
    • Place of Presentation
      分子科学研究所(愛知県)
    • Year and Date
      2010-12-01
    • Invited
  • [Presentation] Fast Photochromism of [2.2] Paracyclophane-Bridged Imidazole Dimers2010

    • Author(s)
      Jiro Abe
    • Organizer
      6th International Symposium on Organic Photochromism (ISOP-2010)
    • Place of Presentation
      日石横浜ホール
    • Year and Date
      2010-10-18
    • Invited
  • [Presentation] 実用的高速フォトクロミック材料の開発2010

    • Author(s)
      阿部二朗
    • Organizer
      27th International Conference of Photopolymer Science and Technology (ICPST-27)
    • Place of Presentation
      千葉大学
    • Year and Date
      2010-06-25
  • [Book] New Frontiers in Photochromism ; Eds. Masahiro Irie, Yasushi Yokoyama, Takahiro Seki, Chapter 9 "Fast photochromism of bridged imidazole dimers"2013

    • Author(s)
      Jiro Abe
    • Total Pages
      21
    • Publisher
      Springer
  • [Book] フォトクロミズムの新展開と光メカニカル機能材料 高分子学会編集・最先端材料システムOne Point 8巻「フォトクロミズム」2012

    • Author(s)
      阿部二朗
    • Total Pages
      9
    • Publisher
      共立出版
  • [Book] フォトクロミズムの新展開と光メカニカル機能材料2011

    • Author(s)
      阿部二朗
    • Total Pages
      7
    • Publisher
      シーエムシ-出版
  • [Remarks]

    • URL

      http://www.chem.aoyama.ac.jp/Chem/ChemHP/phys3/top/abe.html

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Published: 2015-06-25  

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