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2012 Fiscal Year Final Research Report

Materials research and development for functional transition metal oxides

Research Project

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Project/Area Number 22246083
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

BELIK Alexei  独立行政法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, MANA独立研究者 (20421430)

Co-Investigator(Kenkyū-buntansha) 磯部 雅朗  独立行政法人物質・材料研究機構, 超伝導物性ユニット, グループリーダー (10354309)
新井 正男  独立行政法人物質・材料研究機構, 理論計算科学ユニット, 主幹研究員 (40222723)
山浦 一成  独立行政法人物質・材料研究機構, 超伝導物性ユニット, 主幹研究員 (70391216)
橘 信  独立行政法人物質・材料研究機構, 超伝導物性ユニット, 主任研究員 (40442727)
櫻井 裕也  独立行政法人物質・材料研究機構, 超伝導物性ユニット, 主任研究員 (60421400)
川嶋 哲也  独立行政法人物質・材料研究機構, 先端材料プロセスユニット, 主任研究員 (00354308)
Project Period (FY) 2010 – 2012
Keywordsコバルト酸化物 / パイロクロア型酸化物 / 強誘電転移 / 高圧合成
Research Abstract

We have conducted new materials research under high-pressure and high-temperature conditions for various transition metal oxide to develop materials properties toward possible applications as well as greater understanding for solid state science. The aim was achieved in part by successful synthesis of new materials, more than 10, and by identifying those crystal structures and magnetic and electrical properties. Some of them are likely applicable for practical uses.

  • Research Products

    (35 results)

All 2013 2012 2011 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (15 results)

  • [Journal Article] Carbon-Induced Ferromagnetism in the Antiferromagnetic Metallic Host Material Mn3ZnN2013

    • Author(s)
      Y. Sun, Y. F. Guo, Y. Tsujimoto, J. J. Yang, B. Shen, W. Yi, Y. Matsushita, C. Wang, X. Wang, J. Li, C. I. Sathish, and K. Yamaura
    • Journal Title

      Inorganic Chemistry

      Volume: 52 Pages: 800-806

    • DOI

      doi: 10.1021/ic3019265

    • Peer Reviewed
  • [Journal Article] Origin of Magnetization Reversal and Exchange Bias Phenomena in Solid Solutions of BiFeO3-BiMnO3: Intrinsic or Extrinsic?2013

    • Author(s)
      A. A. Belik
    • Journal Title

      Inorganic Chemistry

      Volume: 52 Pages: 2015-2021

    • DOI

      doi: 10.1021/ic302384j

    • Peer Reviewed
  • [Journal Article] High-Pressure Synthesis, Crystal Structure, and Properties of BiPd2O4 with Pd2+ and Pd4+ Ordering and PbPd2O42012

    • Author(s)
      W. Yi, Y. Matsushita, M. Tanaka, and A. A. Belik
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Pages: 7650-7656

    • DOI

      doi: 10.1021/ic3006579

    • Peer Reviewed
  • [Journal Article] High-Pressure Synthesis, Crystal Structure, and Electromagnetic Properties of CdRh2O4: an Analogous Oxide of the Postspinel Mineral M9Al2O42012

    • Author(s)
      X. Wang, Y. F. Guo, Y. G. Shi, A. A. Belik, Y. Tsujimoto, W. Yi, Y. Sun, Y. Shirako, M. Arai, M. Akaogi, Y. Matsushita, and K. Yamaura
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Pages: 6868-6875

    • DOI

      doi: 10.1021/ic300628m

    • Peer Reviewed
  • [Journal Article] Resistive switching phenomenon driven by antiferromagnetic phase separation in an antiperovskite nitride Mn3ZnN2012

    • Author(s)
      Y. S. Sun, Y. F. Guo, X. X. Wang, Y. Tsujimoto, Y. Matsushita, Y. G. Shi, C. Wang, A. A. Belik, and K. Yamaura
    • Journal Title

      Applied Physics Letters

      Volume: 100

    • DOI

      doi: 10.1063/1.4704664

    • Peer Reviewed
  • [Journal Article] Neutron Diffraction Study of Unusual Phase Separation in the Antiperovskite Nitride Mn3ZnN2012

    • Author(s)
      Y. Sun, C. Wang, Q. Z. Huang, Y. F. Guo, L. H. Chu, M. Arai, and K. Yamaura
    • Journal Title

      Inorganic Chemistry

      Volume: 51 Pages: 7232-7236

    • DOI

      doi: 10.1021/ic300978x

    • Peer Reviewed
  • [Journal Article] Superconductivity suppression of Ba(0.5)K(0.5)Fe2-2xM2xAs(2) single crystals by substitution of transition metal (M = Mn, Ru, Co, Ni, Cu, and Zn)2012

    • Author(s)
      J. Li, Y. F. Guo, S. B. Zhang, J. Yuan, Y. Tsujimoto, X. Wang, C. I. Sathish, Y. Sun, S. Yu, W. Yi, K. Yamaura, E. Takayama-Muromachiu, Y. Shirako, M. Akaogi, and H. Kontani
    • Journal Title

      Physical Review B

      Volume: 85

    • DOI

      doi: 10.1103/PhysRevB.85.214509

    • Peer Reviewed
  • [Journal Article] Continuous critical temperature enhancement with gradual hydrogen doping in LaFeAsO0.85Hx (x=0-0.85)2012

    • Author(s)
      Y. F. Guo, X. Wang, J. Li, Y. Sun, Y. Tsujimoto, A. A. Belik, Y. Matsushita, K. Yamaura, and E. Takayama-Muromachi
    • Journal Title

      Physical Review B

      Volume: 86 Pages: 54523

    • DOI

      doi: 10.1103/PhysRevB.86.054523

    • Peer Reviewed
  • [Journal Article] Magnetic structure determination of Ca3LiOsO6 using neutron and x-ray scattering2012

    • Author(s)
      S. Calder, M. D. Lumsden, V. O. Garlea, J. W. Kim, Y. G. Shi, H. L. Feng, K. Yamaura, and A. D. Christianson
    • Journal Title

      Physical Review B

      Volume: 86

    • DOI

      doi: 10.1103/PhysRevB.86.054403

    • Peer Reviewed
  • [Journal Article] Magnetically Driven Metal-Insulator Transition in NaOsO32012

    • Author(s)
      S. Calder, V. O. Garlea, D. F. McMorrow, M. D. Lumsden, M. B. Stone, J. C. Lang, J. W. Kim, J. A. Schlueter, Y. G. Shi, K. Yamaura, Y. S. Sun, Y. Tsujimoto, and A. D. Christianson
    • Journal Title

      Physical Review Letters

      Volume: 108

    • DOI

      doi: 10.1103/PhysRevLett.108.257209

    • Peer Reviewed
  • [Journal Article] BiGaO3-Based Perovskites: A Large Family of Polar Materials2012

    • Author(s)
      A. A. Belik, D. A. Rusakov, T. Furubayashi, and E. Takayama-Muromachi
    • Journal Title

      Chemistry of Materials

      Volume: 24 Pages: 3056-3064

    • DOI

      doi: 10.1021/cm301603v

    • Peer Reviewed
  • [Journal Article] Crystal Structures and Properties of Perovskites ScCrO3 and InCrO3 with Small Ions at the A Site2012

    • Author(s)
      A. A. Belik, Y. Matsushita, M. Tanaka, and E. Takayama-Muromachi
    • Journal Title

      Chemistry of Materials

      Volume: 24 Pages: 2197-2203

    • DOI

      doi: 10.1021/cm3009144

    • Peer Reviewed
  • [Journal Article] Magnetic and electrical properties and carrier doping effects on the iron-based host compound Sr2ScFeAsO32011

    • Author(s)
      S. B. Zhang, Y. F. Guo, Y. G. Shi, S. Yu, J. J. Li, X. X. Wang, M. Arai, K. Yamaura, and E. Takayama-Muromachi
    • Journal Title

      Physical Review B

      Volume: 83

    • DOI

      doi: 10.1103/PhysRevB.83.024505

    • Peer Reviewed
  • [Journal Article] Structure and magnetism of the postlayered perovskite Sr3Co2O6: A possible frustrated spin-chain material2011

    • Author(s)
      X. X. Wang, J. J. Li, Y. G. Shi, Y. Tsujimoto, Y. F. Guo, S. B. Zhang, Y. Matsushita, M. Tanaka, Y. Katsuya, K. Kobayashi, K. Yamaura, and E. Takayama-Muromachi
    • Journal Title

      Physical Review B

      Volume: 83

    • DOI

      doi: 10.1103/PhysRevB.83.100410

    • Peer Reviewed
  • [Journal Article] Integer spin-chain antiferromagnetism of the 4d oxide CaRuO3 with post-perovskite structure2011

    • Author(s)
      Y. Shirako, H. Satsukawa, X. X. Wang, J. J. Li, Y. F. Guo, M. Arai, K. Yamaura, M. Yoshida, H. Kojitani, T. Katsumata, Y. Inaguma, K. Hiraki, T. Takahashi, and M. Akaogi
    • Journal Title

      Physical Review B

      Volume: 83

    • DOI

      doi: 10.1103/PhysRevB.83.174411

    • Peer Reviewed
  • [Journal Article] Structural Evolution and Properties of Solid Solutions of Hexagonal InMnO3 and InGaO32011

    • Author(s)
      D. A. Rusakov, A. A. Belik, S. Kamba, M. Savinov, D. Nuzhnyy, T. Kolodiazhnyi, K. Yamaura, E. Takayama-Muromachi, F. Borodavka, and J. Kroupa
    • Journal Title

      Inorganic Chemistry

      Volume: 50 Pages: 3559-3566

    • DOI

      doi: 10.1021/ic102477c

    • Peer Reviewed
  • [Journal Article] Pressure-induced metal-insulator transition in the spin-orbit Mott insulator Ba2IrO42011

    • Author(s)
      H. Okabe, N. Takeshita, M. Isobe, E. Takayama-Muromachi, T. Muranaka, and J. Akimitsu
    • Journal Title

      Physical Review B

      Volume: 84

    • DOI

      doi: 10.1103/PhysRevB.84.115127

    • Peer Reviewed
  • [Journal Article] Linear decrease of critical temperature with increasing Zn substitution in the iron-based superconductor BaFe1.89-2xZn2xCo0.11As22011

    • Author(s)
      J. Li, Y. F. Guo, S. B. Zhang, S. Yu, Y. Tsujimoto, H. Kontani, K. Yamaura, and E. Takayama-Muromachi
    • Journal Title

      Physical Review B

      Volume: 84

    • DOI

      doi: 10.1103/PhysRevB.84.020513

    • Peer Reviewed
  • [Journal Article] Crystal structure and magnetic properties of 6H-SrMnO32011

    • Author(s)
      A. A. Belik, Y. Matsushita, Y. Katsuya, M. Tanaka, T. Kolodiazhnyi, M. Isobe, and E. Takayama-Muromachi
    • Journal Title

      Physical Review B

      Volume: 84

    • DOI

      doi: 10.1103/PhysRevB.84.094438

    • Peer Reviewed
  • [Journal Article] Observation of persistent centrosymmetricity in the hexagonal manganite family

    • Author(s)
      Y. Kumagai, A. A. Belik, M. Lilienblum, N. Leo, M. Fiebig, and N. A. Spaldin
    • Journal Title

      Physical Review B

      Volume: 85 Pages: 2012

    • DOI

      doi: 10.1103/PhysRevB.85.174422

    • Peer Reviewed
  • [Presentation] High-pressure synthesis and properties of new perovskites with small ions at the A site2013

    • Author(s)
      A.A. Belik, W. Yi, T. Furubayashi, Y. Matsushita, M. Tanaka, S. Hishita, H.i Yusa, E. Takayama-Muromachi
    • Organizer
      Study of Matter at Extreme Conditions, SMEC 2013
    • Place of Presentation
      Miami, USA
    • Year and Date
      20130323-30
  • [Presentation] Chemistry and synthesis of new polar perovskites with small tolerance factors2013

    • Author(s)
      A. A. Belik
    • Organizer
      APS March Meeting 2013
    • Place of Presentation
      Baltimore, USA
    • Year and Date
      20130318-22
  • [Presentation] ペロブスカイト型オスミウム酸化物および関連物質の電子物性2013

    • Author(s)
      山浦一成
    • Organizer
      学振研究開専門委員会「産業応用をめざした新物質機能の設計と実証」拡大幹事会‐4d、5d電子系材料に関する研究の現状と可能性を探る‐
    • Place of Presentation
      東京大学山上会館
    • Year and Date
      2013-03-02
  • [Presentation] Strong, tough high temperature superconducting nanowires: synthesis and characterization of whisker crystals of iron-based superconductor2012

    • Author(s)
      K. Yamaura
    • Organizer
      The 8th Hokkaido University ? Nanjing University Joint Symposium
    • Place of Presentation
      Conference Hall, Hokkaido University, and Hotel Milione, Jozankei, Sapporo, Japan
    • Year and Date
      20121206-08
  • [Presentation] Strong, tough high-Tc superconducting nanowires: synthesis and characterization of whisker crystals of Fe-based superconductor2012

    • Author(s)
      K. Yamaura
    • Organizer
      1st International Conference on Emerging Advanced Nanomaterials (ICEAN)
    • Place of Presentation
      Mercure Hotel, Brisbane, Australia
    • Year and Date
      20121022-25
  • [Presentation] High-pressure synthesis and magnetic properties of new composite perovskite and related oxides2012

    • Author(s)
      K. Yamaura
    • Organizer
      The 4th International Symposium on Structure-Property Relationships in Solid State Materials
    • Place of Presentation
      University of Bordeaux, Bordeaux, France
    • Year and Date
      20120624-29
  • [Presentation] Impurity effects on the Fe-based superconductor A(Fe1-yCoy)2As2 (A = Ba and Sr)2012

    • Author(s)
      K. Yamaura
    • Organizer
      International Conference and Workshop on Nanostructured Ceramics University of Delhi
    • Place of Presentation
      New Delhi, India
    • Year and Date
      20120313-16
  • [Presentation] High-pressure synthesis of new ferroelectric and multiferroic perovskite materials2012

    • Author(s)
      A. A. Belik
    • Organizer
      Fundamental Physics of Ferroelectrics and Related Materials 2012
    • Place of Presentation
      Argonne National Laboratory, Argonne, IL USA
    • Year and Date
      20120129-0201
  • [Presentation] NaCr2O4の巨大磁気抵抗効果2012

    • Author(s)
      Conference Hall, Hokkaido University, and Hotel Milione, Jozankei, Sapporo, Japan,
    • Organizer
      ISSPワークショップ「強相関物質開発の最前線」
    • Place of Presentation
      東大物性研
    • Year and Date
      2012-10-23
  • [Presentation] カルシウムフェライト型酸化物NaM2O4 (M:3d遷移金属)の電子物性2012

    • Author(s)
      桜井裕也
    • Organizer
      NIMS-東北大多元研連携ラボ
    • Place of Presentation
      東北大多元研
    • Year and Date
      2012-02-23
  • [Presentation] 高圧合成法による新材料シーズの探索:ペロブスカイト型関連酸化物2011

    • Author(s)
      山浦一成,
    • Organizer
      GRC研究推進プロジェクト・キックオフシンポジウム「高圧下における材料合成」
    • Place of Presentation
      愛媛大学、松山
    • Year and Date
      20111014-15
  • [Presentation] Continuous metal-insulator transition at 410 K of the 5d oxide NaOsO32011

    • Author(s)
      K. Yamaura
    • Organizer
      26th International Conference on Low Temperature Physics (LT26) Beijing International Convention Center
    • Place of Presentation
      China
    • Year and Date
      20110810-17
  • [Presentation] High-pressure synthesis and magnetic properties of the novel post-perovskite oxide CaRuO32011

    • Author(s)
      K. Yamaura
    • Organizer
      The 18th American Conference on Crystal Growth and Epitaxy (ACCGE-18)
    • Place of Presentation
      Hyatt regency, Monterey, California, USA
    • Year and Date
      20110731-0805
  • [Presentation] High-pressure synthesis of new composite oxides related to perovskite structure: primary properties and possible applications2011

    • Author(s)
      K. Yamaura
    • Organizer
      International Discussion Meeting on Thermoelectrics and Related Functional Materials
    • Place of Presentation
      School of Chemical Technology, Aalto University, Finland
    • Year and Date
      20110614-17
  • [Presentation] Exploration of Functional Perovskites Employing Calorimetry2011

    • Author(s)
      M. Tachibana
    • Organizer
      The 66th Calorimetry Conference
    • Place of Presentation
      Oahu, Hawaii, USA
    • Year and Date
      2011-06-16

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Published: 2014-08-29  

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