2012 Fiscal Year Final Research Report
Construction of Organic-Inorganic Complexes for Sorption and Reaction of Molecules and Ions
| Project/Area Number |
22310058
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Nanostructural science
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| Research Institution | The University of Tokyo |
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Principal Investigator |
UCHIDA Sayaka 東京大学, 大学院・総合文化研究科, 准教授 (10361510)
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| Project Period (FY) |
2010 – 2012
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| Keywords | ナノ材料 / 複合材料・物性 / 自己組織化 / 触媒・化学プロセス |
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| Research Abstract |
Synthesis of functional solids for the efficient use of energy and material is an important task. In this work, complexation of nano-sized metal-oxide clusters with macrocations and mononuclear metal cations was attempted. Ionic crystals (complexes) with controlled pore sizes, volumes, dimensionalities, and guest affinities were synthesized. Guest sorption properties were investigated with in situ spectroscopy, X-ray diffraction, quantum mechanics, and the compounds were applied as separation materials and catalysts.
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