• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2012 Fiscal Year Final Research Report

Shape and Size Controlled Syntheses of Metallic Nanocrystals Using Structural Correlation between Core and Shell

Research Project

  • PDF
Project/Area Number 22310060
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural science
Research InstitutionKyushu University

Principal Investigator

TSUJI Masaharu  九州大学, 先導物質化学研究所, 教授 (30038608)

Co-Investigator(Kenkyū-buntansha) TSUJI Takeshi  九州大学, 先導物質化学研究所, 助教 (50284568)
Co-Investigator(Renkei-kenkyūsha) AGO Hiroki  九州大学, 先導物質化学研究所, 准教授 (10356355)
Project Period (FY) 2010 – 2012
Keywordsナノ材料 / マイクロ波加熱 / 結晶成長 / 複合金属材料 / コア・シェル構造
Research Abstract

Shape and size controlled syntheses of metallic nanocrystals were studied using structural correlation between core and shell.We succeeded in epitaxialgrowth of not only Au@Ag and Au@ Pd core-shell particles having small lattice mismatches below 5 % but also of Au@Cu and Au@Ni ones having large lattice mismatchesabove 10% for the first time. Epitaxial growth mechanisms of each metallic nanocrystal were examined using TEM and TEM-EDS analyses.

  • Research Products

    (50 results)

All 2013 2012 2011 2010 Other

All Journal Article (35 results) (of which Peer Reviewed: 35 results) Presentation (9 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Near-infrared photoluminescence in the femtosecond time region in monolayer graphene on SiO22013

    • Author(s)
      T. Koyama, Y. Ito, K. Yoshida, M. Tsuji, H. Ago, H. Kishida, and A. Nakamura
    • Journal Title

      ACS Nano

      Volume: 7 Pages: 2335-2343

    • DOI

      DOI:10.1021/nn305558r

    • Peer Reviewed
  • [Journal Article] Preparation and investigation of the formation mechanism of submicron-sized spherical particles of gold using laser ablation and laser irradiation in liquids2013

    • Author(s)
      T. Tsuji, M. Tsuji , 他
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 15 Pages: 3099-3107

    • DOI

      DOI:10.1039/c2cp44159d

    • Peer Reviewed
  • [Journal Article] Synthesis of Au@Ag@Cu trimetallic core-shell nanocrystals using three-step reduction2013

    • Author(s)
      M. Tsuji, 他6名
    • Journal Title

      CrystEngComm

      Volume: 15 Pages: 1345-1351

    • DOI

      DOI:10.1039/C2CE26895G

    • Peer Reviewed
  • [Journal Article] Synthesis of cubic Pd-Ag random alloy nanocrystal in an aqueous solution in the presence of CTAB2013

    • Author(s)
      M. Tsuji, 他5名
    • Journal Title

      Mater. Lett.

      Volume: 95 Pages: 201-204

    • URL

      http://dx.doi.org/ 10.1016/j.matlet.2012.12.093

    • Peer Reviewed
  • [Journal Article] Crystal structures and growth mechanisms of octahedral and decahedral Au@Ag core-shell nanocrystals prepared by two-step reduction method2012

    • Author(s)
      M. Tsuji, N. Nakamura, M. Ogino, 他2名
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 7639-7647

    • DOI

      DOI:10.1039/C2CE25569C

    • Peer Reviewed
  • [Journal Article] Rapid transformation from spherical nanoparticles, nanorods, cubes, or bipyramids to triangular prisms of silver with PVP, citrate, and H2O22012

    • Author(s)
      M. Tsuji, S. Gomi, Y. Maeda, 他4名, T. Tsuji
    • Journal Title

      Langmuir

      Volume: 28 Pages: 8845-8861

    • DOI

      DOI:10.1021/la3001027

    • Peer Reviewed
  • [Journal Article] Syntheses of Au-Cu-rich AuAg(AgCl)Cu alloy and Ag-Cu-rich AuAgCu@Cu core-shell and AuAgCu alloy nanoparticles using polyol method2012

    • Author(s)
      M. Tsuji, M. Matsunaga, 他2名
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 3623-3632

    • DOI

      DOI:10.1039/C2CE06119H

    • Peer Reviewed
  • [Journal Article] Epitaxial growth of Au@Pd core-shell nanocrystals prepared using PVP-assisted polyol reduction method2012

    • Author(s)
      M. Tsuji, 他
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 3411-3423

    • DOI

      DOI:10.1039/C2CE00037G

    • Peer Reviewed
  • [Journal Article] Influence of Cu metal on the domain structure and carrier mobility in single-layer graphene2012

    • Author(s)
      C. M. Orofeo, 他3名, H. Ago, K. Ikeda, S. Mizuno, and M. Tsuji
    • Journal Title

      Carbon

      Volume: 50 Pages: 2189-2196

    • URL

      http://dx.doi.org/10.1016/ j.carbon.2012.01.030

    • Peer Reviewed
  • [Journal Article] Catalytic growth of graphene: Towards large-area single-crystalline graphene2012

    • Author(s)
      H. Ago, Y. Ogawa, M. Tsuji, S. Mizuno, and H. Hibino
    • Journal Title

      J. Phys. Chem. Lett

      Volume: 3 Pages: 2228-2236

    • DOI

      DOI:10.1021/jz3007029

    • Peer Reviewed
  • [Journal Article] Epitaxial growth of large-area single-layer graphene over Cu(111)/sapphire by atmospheric pressure CVD2012

    • Author(s)
      B. Hu, H. Ago, Y. Ito, K. Kawahara, M. Tsuji, 他
    • Journal Title

      Carbon

      Volume: 50 Pages: 57-65

    • DOI

      DOI:10.1016/j.carbon.2011.08.002

    • Peer Reviewed
  • [Journal Article] Preparation and shape-modification of silver colloids by laser ablation in liquids2012

    • Author(s)
      T. Tsuji, M. Nakanishi, T. Mizuki, S. Ozono, M. Tsuji, and Y. Tsuboi
    • Journal Title

      Sci. Adv. Mater.

      Volume: 4 Pages: 391-400

    • URL

      http://dx.doi.org/10.1166/ sam.2012.1295

    • Peer Reviewed
  • [Journal Article] Step-templated CVD growth of aligned graphene nanoribbons supported by a single-layer graphene film2012

    • Author(s)
      H. Ago, Y. Ito, M. Tsuji, and K. Ikeda
    • Journal Title

      Nanoscale

      Volume: 4 Pages: 5178-5182

    • DOI

      DOI:10.1039/C2NR30770G

    • Peer Reviewed
  • [Journal Article] Influence of surface plasmon resonance on shape changes of nanostructures: Investigation using gold nanoblocks in halide solution2012

    • Author(s)
      T. Tsuji, 他2名, M. Tsuji, and H. Misawa
    • Journal Title

      J. Photochem. Photobiol. A: Chemistry

      Volume: 212 Pages: 20-26

    • DOI

      DOI:10.1016/j.jphotochem.2010.03.007

    • Peer Reviewed
  • [Journal Article] Synthesis of large-area, homogeneous, single layer graphene films by annealing amorphous carbon on Co and Ni2011

    • Author(s)
      C. M. Orofeo, H. Ago, B. Hu, and M. Tsuji
    • Journal Title

      Nano Research

      Volume: 4 Pages: 531-540

    • DOI

      DOI:10.1007/s12274-011-0109-x

    • Peer Reviewed
  • [Journal Article] Epitaxial growth of Au@Ni core-shell nanocrystals prepared by a two-step reduction method2011

    • Author(s)
      M. Tsuji, D. Yamaguchi, 他5名
    • Journal Title

      Cryst. Growth Des.

      Volume: 11 Pages: 1995-2005

    • DOI

      DOI:dx.doi.org/10.1021/cg200199b

    • Peer Reviewed
  • [Journal Article] Effects of gas bubbling for shape, size, and composition changes in Au-Ag bimetallic nanoparticles including polygonal Au seeds under oil-bath heating at 150°C2011

    • Author(s)
      Md. J. Alam and M. Tsuji
    • Journal Title

      CrystEngComm

      Volume: 13 Pages: 6499-6506

    • DOI

      DOI:10.1039/c1ce05550j

    • Peer Reviewed
  • [Journal Article] Shape changes in Au-Ag bimetallic systems involving polygonal Au nanocrystals to spherical Au/Ag alloy and excentered Au core Ag/Au alloy shell particles under oil-bath heating2011

    • Author(s)
      Md. J. Alam, M. Tsuji, 他
    • Journal Title

      CrystEngComm

      Volume: 13 Pages: 2984-2993

    • DOI

      DOI:10.1039/c0ce00899k

    • Peer Reviewed
  • [Journal Article] Synthesis of Au core Au/Ag alloy shell nanoparticles using branched Au nanoparticles as seeds2011

    • Author(s)
      X. Tang and M. Tsuji
    • Journal Title

      CrystEngComm

      Volume: 13 Pages: 72-76

    • DOI

      DOI:10.1039/cOceOO018c

    • Peer Reviewed
  • [Journal Article] Utilization of laser ablation in aqueous solution for observation of photoinduced shape conversion of silver nanoparticles in citrate solutions2011

    • Author(s)
      T. Tsuji, M. Tsuji, 他1名
    • Journal Title

      J. Photochem. Photobiol., A: Chemistry

      Volume: 221 Pages: 224-231

    • DOI

      DOI:10.1016/j.jphotochem.2011.02.020

    • Peer Reviewed
  • [Journal Article] Ultrahigh-vacuum-assisted control of metal nanoparticles for horizontally aligned single-walled CNT with extraordinary uniform diameters2011

    • Author(s)
      H. Ago, M. Tsuji, 他
    • Journal Title

      J. Phys. Chem. C

      Volume: 115 Pages: 13247-13253

    • DOI

      DOI:dx.doi.org/10.1021/jp2038448

    • Peer Reviewed
  • [Journal Article] Combinatorial catalyst approach for high-density growth of horizontally aligned single-walled carbon nanotubes on sapphire2011

    • Author(s)
      H. Ago, 他 , and M. Tsuji
    • Journal Title

      Carbon

      Volume: 49 Pages: 176-186

    • DOI

      DOI:10.1016/j.carbon.2010.09.001

    • Peer Reviewed
  • [Journal Article] Shape evolution of flag types of silver nanostructures from nanorods seeds in PVP-assisted DMF solution2010

    • Author(s)
      M. Tsuji, X. Tang, M. Matsunaga, 他2名
    • Journal Title

      Cryst. Growth Des.

      Volume: 10 Pages: 5238-5243

    • DOI

      DOI:10.1021/cg101041m

    • Peer Reviewed
  • [Journal Article] Synthesis of Ag/Cu alloy and Ag/Cu@Cu core shell nanoparticles using a polyol method2010

    • Author(s)
      M. Tsuji, R. Tanabe, 他3名
    • Journal Title

      CrystEngComm

      Volume: 12 Pages: 3900-3908

    • DOI

      DOI:10.1039/c0ce00064g

    • Peer Reviewed
  • [Journal Article] Epitaxial growth of Au@Cu core-shell nanocrystals prepared by PVP-assisted polyol reduction method2010

    • Author(s)
      M. Tsuji, D. Yamaguchi, 他2名
    • Journal Title

      Cryst. Growth Des.

      Volume: 10 Pages: 5129-5135

    • DOI

      DOI:10.1021/cg100860d

    • Peer Reviewed
  • [Journal Article] Crystal structures and growth mechanisms of icosahedral Au@Ag core-shell and Au/Ag twin nanocrystals prepared by PVP-assisted N,N-dimethylformamide reduction2010

    • Author(s)
      M. Tsuji, M. Ogino, 他
    • Journal Title

      Cryst. Growth Des.

      Volume: 10 Pages: 4085-4090

    • DOI

      DOI:10.1021/cg100748g

    • Peer Reviewed
  • [Journal Article] Stepwise growth of decahedral and icosahedral silver nanocrystals in DMF2010

    • Author(s)
      M. Tsuji, M. Ogino, 他5 名
    • Journal Title

      Cryst. Growth Des.

      Volume: 10 Pages: 296-301

    • DOI

      DOI:10.1021/cg9009042

    • Peer Reviewed
  • [Journal Article] Growth of horizontally aligned single-walled carbon nanotubes on anisotropically etched silicon substrate2010

    • Author(s)
      C. M. Orofeo, H. Ago, T. Ikuta, K. Takahashi, and M. Tsuji
    • Journal Title

      Nanoscale

      Volume: 2 Pages: 1708-1714

    • DOI

      DOI:10.1039/c0nr00170h

    • Peer Reviewed
  • [Journal Article] Shape changes from polygonal gold nanocrystals to spherical nanoparticles induced by bubbling N2or O2gas in polyol synthesis of gold nanostructures2010

    • Author(s)
      Md. J. Alam, M. Tsuji, 他
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 83 Pages: 92-100

    • URL

      http://dx.doi.org/10.1246/ bcsj.20090227

    • Peer Reviewed
  • [Journal Article] Effective patterning of metal nanoparticles on sapphire surface for aligned single-walled carbon nanotubes2010

    • Author(s)
      H. Ago, R. Ohdo, M. Tsuji, 他
    • Journal Title

      J. Nanosci. Nanotech.

      Volume: 10 Pages: 3867-3872

    • DOI

      DOI:10.1166/jnn.2010.1977

    • Peer Reviewed
  • [Journal Article] Rapid synthesis of Ag@Ni core-shell nanoparticles using a microwave-polyol method2010

    • Author(s)
      M. Tsuji, S. Hikino, 他4名
    • Journal Title

      Mater. Lett.

      Volume: 64 Pages: 1793-1797

    • DOI

      DOI:10.1016/j.matlet.2010.05.032

    • Peer Reviewed
  • [Journal Article] Synthesis of Ag@Cu core-shell nanoparticles in high yield using a polyol method2010

    • Author(s)
      M. Tsuji, S. Hikino, 他2名
    • Journal Title

      Chem. Lett.

      Volume: 39 Pages: 334-336

    • DOI

      DOI:10.1246/cl.2010.334

    • Peer Reviewed
  • [Journal Article] Epitaxial CVD growth of single-layer graphene over cobalt film crystalized on sapphire2010

    • Author(s)
      H. Ago, M. Tsuji 他5名
    • Journal Title

      ACS Nano

      Volume: 4 Pages: 7407-7414

    • DOI

      DOI:10.1021/nn102519b

    • Peer Reviewed
  • [Journal Article] Patterned growth of graphene over epitaxial catalyst2010

    • Author(s)
      H. Ago, I. Tanaka, C. M. Orofeo, M. Tsuji, and K. Ikeda
    • Journal Title

      Small

      Volume: 6 Pages: 1226-1233

    • DOI

      DOI:10.1002/smll.200902405

    • Peer Reviewed
  • [Journal Article] Orthogonal growth of horizontally-aligned single-walled carbon nanotube arrays2010

    • Author(s)
      H. Ago, M. Tsuji, 他
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Pages: 12925-12930

    • DOI

      DOI:10.1021/jp1032993

    • Peer Reviewed
  • [Presentation] Shape-controlled synthesis of bimetallic core-shell nanocrystals in liquid phase2012

    • Author(s)
      Masaharu Tsuji
    • Organizer
      The 13th RIES-Hokudai International Symposium, and Ist Alliance International Symposium
    • Place of Presentation
      札幌
    • Year and Date
      2012-12-14
  • [Presentation] Epitaxial growth of Au@M (M=Cu, Ni) core-shell nanocrystals having large lattice mismatches2012

    • Author(s)
      Masaharu Tsuji
    • Organizer
      Gold 2012, 6th International conference
    • Place of Presentation
      東京
    • Year and Date
      2012-09-07
  • [Presentation] Syntheses of AuAg(AgCl)Cu alloy and AuAgCu@Cu core-shell and AuAgCu alloy nanoparticles by polyol method2012

    • Author(s)
      Masaharu Tsuji et al.
    • Organizer
      Gold 2012, 6th International conference
    • Place of Presentation
      東京
    • Year and Date
      2012-09-07
  • [Presentation] Epitaxial growth of Au@Ni core-shell nanocrystals having a large lattice mismatches of13.6%2011

    • Author(s)
      Masaharu Tsuji et al.
    • Organizer
      3rd Asian Symposium on Advanced Materials/ASAM3
    • Place of Presentation
      福岡
    • Year and Date
      2011-09-21
  • [Presentation] Epitaxial growth of Au@M (M=Cu, Ni) core-shell nanocrystals having large lattice mismatches2011

    • Author(s)
      Masaharu Tsuji et al.
    • Organizer
      Carbon Materials for Energy Devices and Environmental Protections (CSE2011)
    • Place of Presentation
      済州島、韓国
    • Year and Date
      2011-08-26
  • [Presentation] Shape evolution of novel silver nanostructures in pvp-assisted dmf solution2010

    • Author(s)
      Masaharu Tsuji
    • Organizer
      Carbon Materials for Energy Devices and Environmental Protections (CSE2010)
    • Place of Presentation
      別府
    • Year and Date
      2010-11-26
  • [Presentation] Syntheses and growth mechanisms of metallic nanoparticles in solutions2010

    • Author(s)
      Masaharu Tsuji
    • Organizer
      2010 Korean-Japan Bilateral Symposium on Frontier Photoscience
    • Place of Presentation
      大邱,Korea
    • Year and Date
      2010-10-25
  • [Presentation] Syntheses of Ag/Cu alloy and Ag/Cu alloy core Cu shell nanoparticles by a polyol method2010

    • Author(s)
      Masaharu Tsuji et al.
    • Organizer
      NCSS2010 International Conference on Nanoscopic Colloid and Surface Science
    • Place of Presentation
      幕張
    • Year and Date
      2010-09-21
  • [Presentation] Crystal structures and growth mechanisms of icosahedral Au@Ag core-shell and Au/Ag twin nanocrystals prepared by PVP-assisted N,N-dimethylformamide reduction2010

    • Author(s)
      Masaharu Tsuji et al.
    • Organizer
      NCSS2010 International Conference on Nanoscopic Colloid and Surface Science
    • Place of Presentation
      幕張
    • Year and Date
      2010-09-21
  • [Book] 竹内和彦"マイクロ波化学プロセス技術II2012

    • Author(s)
      辻 正治, 監修 和田雄二、竹内和彦
    • Total Pages
      232-238
    • Publisher
      シーエムシー出版
  • [Book] Syntheses of silver nanowires in liquid phase2010

    • Author(s)
      X.-L. Tang and M. Tsuji
    • Total Pages
      25-42
    • Publisher
      IN-TECH Web book
  • [Remarks]

    • URL

      http://nano.cm.kyushu-u.ac.jp/TSUJI/

  • [Patent(Industrial Property Rights)] 導電材料、その製造方法、およびそれを用いたトランスデューサ2013

    • Inventor(s)
      田口祐太朗、吉川 均、鳥原英嗣、松野亮介、辻 正治
    • Industrial Property Rights Holder
      田口祐太朗、吉川 均、鳥原英嗣、松野亮介、辻 正治
    • Industrial Property Number
      特願2013-004682
    • Filing Date
      2013-01-15
  • [Patent(Industrial Property Rights)] 金属ナノ粒子担持カーボンナノチューブの製造方法2013

    • Inventor(s)
      辻 正治、児島清茂、吉原明彦
    • Industrial Property Rights Holder
      辻 正治、児島清茂、吉原明彦
    • Industrial Property Number
      特願2013-027366
    • Filing Date
      2013-02-15
  • [Patent(Industrial Property Rights)] 金属酸化物ナノ粒子担持カーボンナノチューブの製造方法2013

    • Inventor(s)
      辻 正治、児島清茂
    • Industrial Property Rights Holder
      辻 正治、児島清茂
    • Industrial Property Number
      特願2013-027363
    • Filing Date
      2013-02-15

URL: 

Published: 2014-08-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi