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2012 Fiscal Year Final Research Report

Mechanism of large piezoelectric response due to special anisotropy near the morphotropic phase boundary in ferroelectric materials

Research Project

  • PDF
Project/Area Number 22340081
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics I
Research InstitutionNagoya Institute of Technology

Principal Investigator

IWATA Makoto  名古屋工業大学, 工学研究科, 准教授 (40262886)

Co-Investigator(Kenkyū-buntansha) MAEDA Masaki  名古屋工業大学, 工学研究科, 教授 (10091745)
Research Collaborator ISHIBASHI Yoshihiro  名古屋大学, 名誉教授
IIJIMA Naoya  名古屋工業大学, 工学研究科, 大学院生
ISHIBASHI Yoshihiro  名古屋工業大学, 工学研究科, 大学院生
MAEKAWA Naoki  名古屋工業大学, 工学研究科, 大学院生
TANAKA Kazuki  名古屋工業大学, 工学研究科, 大学・生
ANDO Kenichiro  名古屋工業大学, 工学研究科, 大学院生
YOKOI Ryuta  名古屋工業大学, 工学研究科, 大学院生
Project Period (FY) 2010 – 2012
Keywords誘電体
Research Abstract

The purpose of our study is that stable phases as an average structure in complex perovskite ferroelectrics Pb(Zn1i3 Nb2,3)O3- PbTiO3 (PZN-PT) are clarified. In the present study, the equipment to measure the dielectric dispersion between 100 Hz to 1MHz under the DC biasing voltage of about 800 V was composed. The electric field-temperature phase diagrams in the electric field along the [001], [011], [111] directions in PZN-PT were clarified. Along [001] direction, the critical end point at about 1 kV/cm, which is considerably small, was found. It was also found that aspect of phase diagrams strongly depends on the direction of the electric field.

  • Research Products

    (56 results)

All 2013 2012 2011 2010 Other

All Journal Article (32 results) (of which Peer Reviewed: 31 results) Presentation (22 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Structural Phase Transition and Symmetry Change in Bi_4Ti_3O_122013

    • Author(s)
      M. Iwata, K. Ando, M. Maeda, and Y. Ishibashi
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82 Pages: 025001/1-2

    • DOI

      DOI:10.7566/JPSJ.82.025001

    • Peer Reviewed
  • [Journal Article] A New Type of Incommensurate Phase Transition Caused by Parabolic Splitting of the Degenerate Modes2013

    • Author(s)
      Y. Ishibashi and M. Iwata
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 82 Pages: 044703/1-5

    • DOI

      DOI:10.7566/JPSJ.82.044703

    • Peer Reviewed
  • [Journal Article] Temperature-field phase diagrams in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3 II2013

    • Author(s)
      M. Iwata, N. Iijima, M. Maeda, and Y. Ishibashi
    • Journal Title

      Ceram. Inter.

      Volume: 39 Pages: S75-S79.

    • DOI

      DOI:10.1016/j.ceramint.2012.10.038

    • Peer Reviewed
  • [Journal Article] Modulated internal electric field, dielectric susceptibility and polarization in ferroelectric superlattices2013

    • Author(s)
      K.-G Lim, K.-H. Chew, L.-H. Ong, and M. Iwata
    • Journal Title

      Ceram. Inter.

      Volume: 39 Pages: S307-S310

    • DOI

      DOI:10.1016/j.ceramint.2012.10.083

    • Peer Reviewed
  • [Journal Article] Influence of interface intermixing and periodicity on internal electric field and polarization in ferroelectric superlattices2013

    • Author(s)
      K.-H. Chew, K.-G Lim, L.-H. Ong, M. Iwata
    • Journal Title

      Ceram. Inter.

      Volume: 39 Pages: S301-S305

    • DOI

      DOI:10.1016/j.ceramint.2012.10.082

    • Peer Reviewed
  • [Journal Article] Possible Commensurate Phases in LuFe_2O_42012

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 81 Pages: 035003/1-2.

    • DOI

      DOI:10.1143/JPSJ.81.035003

    • Peer Reviewed
  • [Journal Article] On the Eight Pseudo-Spin Model of KH_2PO_4-Type Crystals2012

    • Author(s)
      Y. Ishibashi, M. Iwata, and R. Blinc
    • Journal Title

      Ferreoelectrics

      Volume: 427 Pages: 56-62

    • DOI

      DOI:10.1080/00150193.2012.673921

    • Peer Reviewed
  • [Journal Article] Temperature-Field Phase Diagramsin Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32012

    • Author(s)
      M. Iwata, N. Iijima, and Y. Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 428 Pages: 1-7

    • DOI

      DOI:10.1080/00150193.2012.675251

    • Peer Reviewed
  • [Journal Article] Electrostatic Coupling and Interface Intermixing in Ferroelectric Superlattices2012

    • Author(s)
      K-G. Lim, K.-H. Chew, L.-H. Ong, and M. Iwata
    • Journal Title

      Euro. Phys. Lett.

      Volume: 99 Pages: 46001/1-6

    • DOI

      DOI:10.1209/0295-5075/99/46004

    • Peer Reviewed
  • [Journal Article] Lattice Vibrations in Finite Discrete Systems with Symmetric and Asymmetric Boundary Conditions2012

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 433 Pages: 12-21

    • DOI

      DOI:10.1080/00150193.2012.678099

    • Peer Reviewed
  • [Journal Article] The Grain-restricted Switching Model2012

    • Author(s)
      Y. Ishibashi and M. Iwata
    • Journal Title

      Ferroelectrics

      Volume: 433 Pages: 41-44

    • DOI

      DOI:10.1080/00150193.2012.678107

    • Peer Reviewed
  • [Journal Article] Low frequency optical phonons in Bi_<4-x>Sm_xTi_3O_<12>2012

    • Author(s)
      I. Kusunoki, Y. Tsujimi, and M. Iwata
    • Journal Title

      Ferroelectrics

      Volume: 433 Pages: 34-40

    • DOI

      DOI:10.1080/00150193.2012.678104

    • Peer Reviewed
  • [Journal Article] Coexistence State near the Morphotropic Phase Boundary2012

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 51 Pages: 09LE03/1-5

    • DOI

      DOI:10.1143/JJAP.51.09LE03

    • Peer Reviewed
  • [Journal Article] Lattice Vibrations and Dispersion Relations near the Conical Points2012

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 81 Pages: 114703/1-6

    • DOI

      DOI:10.1143/JPSJ.81.114703

  • [Journal Article] Detailed Investigation of Temperature-Field Phase Diagrams in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32012

    • Author(s)
      M. Iwata, K. Tanaka, M. Maeda, and Y. Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 440 Pages: 67-74

    • DOI

      DOI:10.1080/00150193.2012.678104

    • Peer Reviewed
  • [Journal Article] Switching Dynamics in Ferroelectric Superlattices2011

    • Author(s)
      K.-H. Chew, L.-H. Ong and M. Iwata
    • Journal Title

      Current Appl. Phys.

      Volume: 11 Pages: 755-761

    • DOI

      DOI:10.1016/j.cap.2010.11.058

    • Peer Reviewed
  • [Journal Article] The Eight-Pseudo-Spin Model of KH_2PO_4-Type Crystal2011

    • Author(s)
      Y. Ishibashi, M. Iwata, and R. Blinc
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 80 Pages: 024602

    • DOI

      DOI:10.1143/JPSJ.80.024602

    • Peer Reviewed
  • [Journal Article] Indicatrix Rotation in Domains Far from the 90° Wall in Ferroelectrics2011

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 36 Pages: 31-34

    • Peer Reviewed
  • [Journal Article] The Phase Front near the Critical End Point as the Boundary of the Polar Nano-Regions in Relaxor Ferroelectrics2011

    • Author(s)
      M. Iwata, Z. Kutonjak, Y. Ishibashi, and R. Blinc
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 80 Pages: 044702/1-4

    • DOI

      DOI:10.1143/JPSJ.80.044702

    • Peer Reviewed
  • [Journal Article] The Eight Pseudo-Spin Model of KH_2PO_4-Type Crystals II. Phase Transitions and Dielectric Susceptibility2011

    • Author(s)
      Y. Ishibashi, M. Iwata, and R. Blinc
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 80 Pages: 054703/1-5.

    • DOI

      DOI:10.1143/JPSJ.80.054703

    • Peer Reviewed
  • [Journal Article] The Critical End Point in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32011

    • Author(s)
      M. Iwata, S. Kato, and Y. Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 415 Pages: 20-23

    • DOI

      DOI:10.1080/00150193.2011.577363

    • Peer Reviewed
  • [Journal Article] Field Induced Transition and Behavior of the Phase Front in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32011

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      Phase Transition

      Volume: 84 Pages: 753-759

    • DOI

      DOI:10.1080/01411594.2011.558266

    • Peer Reviewed
  • [Journal Article] Phase Diagram in Bi_<4_x>Gd_xTi_3O_122011

    • Author(s)
      M. Iwata, T. Inohara, and Y. Ishibashi
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 50 Pages: 09NE09/1-3

    • DOI

      DOI:10.1143/JJAP.50.09NE09

    • Peer Reviewed
  • [Journal Article] Phase Diagram in (Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3 under an Electric Field2011

    • Author(s)
      m. Iwata, S. Kato, and Y. Ishibashi
    • Journal Title

      J. Korean. Phys. Soc

      Volume: 59 Pages: 2449-2451

    • DOI

      DOI:10.3938/jkps.59.2449

    • Peer Reviewed
  • [Journal Article] The Effect of Pressure on the Poling Condition in Lead-based Relaxor Ferroelectric Solid Solutions2011

    • Author(s)
      N. Yasuda, N. Miyazono, H. Ohwa, Y. Tachi, Y. Yamashita, K. Fujita, M. Iwata, and Y.Ishibashi
    • Journal Title

      J. Korean. Phys. Soc.

      Volume: 59 Pages: 2468-2491

    • DOI

      DOI:10.3938/jkps.59.2486

    • Peer Reviewed
  • [Journal Article] Field Induced Phase Transition in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32011

    • Author(s)
      m. Iwata, S. Kato, and Y. Ishibashi
    • Journal Title

      Current Appl. Phys

      Volume: 11 Pages: S42-S44

    • DOI

      DOI:10.1016/j . cap.2011.03.007

    • Peer Reviewed
  • [Journal Article] Influence of Dielectric Stiffness, Interface and Layer Thickness on Hysteresis Loops ofFerroelectric Superlattices2011

    • Author(s)
      K.-H. Chew, L.-H. Ong, and M. Iwata
    • Journal Title

      J. Appl. Phys

      Volume: 110 Pages: 054108/1-8

    • DOI

      DOI:10.1063/1.3630016

    • Peer Reviewed
  • [Journal Article] Field-Induced Phase Transition between Tetragonal and Rhombohedral Phases in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M. Iwata, N. lijima, and Y. Ishibashi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 49 Pages: 091VIE01/1-3.

    • DOI

      DOI:10.1143/JJAP.49.09ME01

    • Peer Reviewed
  • [Journal Article] Structural and Elastic Aspects in Phase Transitions of Superconducting Pyrochlore Oxide Cd_2Re_2O_72010

    • Author(s)
      Y. Ishibashi and M. Iwata
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 79 Pages: 044604/1-5

    • DOI

      DOI:10.1143/JPSJ.79.044604

    • Peer Reviewed
  • [Journal Article] Lattice Vibrations in Finite Systems with the Boundary Conditions Given with the Extrapolation Length II. Discrete Model2010

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 79 Pages: 074709/1-7.

    • DOI

      DOI:10.1143/JPSJ.79.074709

    • Peer Reviewed
  • [Journal Article] Observation of Cleavage Surface in Tri-Glycine Sulfate by Atomic Force Microscopy2010

    • Author(s)
      M. Iwata, H. Itoh, R. Aoyagi, M. Maeda, and Y Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 400 Pages: 195-233

    • DOI

      DOI:10.1080/00150193.2010.505537

    • Peer Reviewed
  • [Journal Article] Phase Diagram in Poled Samples of Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3 MixedCrystals2010

    • Author(s)
      M. Iwata, K. Sakakibara, R. Aoyagi, M. Maeda, and Y. Ishibashi
    • Journal Title

      Ferroelectrics

      Volume: 405 Pages: 39-44

    • DOI

      DOI:10.1080/00150193.2010.482886

    • Peer Reviewed
  • [Presentation] モルフォトロピック相境界近傍の相共存状態II2013

    • Author(s)
      岩田 真,石橋善弘
    • Organizer
      強誘電体応用会議(FMA)
    • Place of Presentation
      京都
    • Year and Date
      20130523-26
  • [Presentation] Bi_4Ti_3O_12の相転移と対称性2013

    • Author(s)
      岩田 真,安藤兼一郎,前田雅輝,石橋善弘
    • Organizer
      日本物理学会年会
    • Place of Presentation
      広島大学
    • Year and Date
      20130326-29
  • [Presentation] Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3混晶の相図II2012

    • Author(s)
      岩田 真,飯島直也,前田雅輝,石橋善弘
    • Organizer
      日本物理学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      20120918-21
  • [Presentation] Temperature-Field Phase Diagrams in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32012

    • Author(s)
      M. Iwata, K. Tanaka, M. Maeda, and Y. Ishibashi
    • Organizer
      The Joint Symposium of the 11th International Symposium on Ferroic Domains and Micro- to Nanoscopic Structures (ISFD) and the l lth Russia/CIS/Baltic/ Japan Symposium on Ferroelectricity (RCBJSF)
    • Place of Presentation
      Ekaterinburg, Rossiya
    • Year and Date
      20120820-24
  • [Presentation] Temperature-Field Phase Diagrams in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32012

    • Author(s)
      M. Iwata, S. Kato, K. Tanaka, M. Maeda, and Y. Ishibashi
    • Organizer
      The Korea-Japan Conference on Ferroelectrics
    • Place of Presentation
      Ulsan, Korea
    • Year and Date
      20120807-10
  • [Presentation] Temperature-Field Phase Diagrams along [011]-and [111]-directions in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32012

    • Author(s)
      M. Iwata, N. Iijima, and Y. Ishibashi
    • Organizer
      The 8th Asian Meeting on Electroceramics 2012 (AMEC-8)
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      20120701-05
  • [Presentation] モルフォトロピック相境界近傍の相共存状態2012

    • Author(s)
      岩田 真,石橋善弘
    • Organizer
      強誘電体応用会議(FMA)
    • Place of Presentation
      京都
    • Year and Date
      20120523-26
  • [Presentation] モルフォトロピック相境界近傍の共存状態2012

    • Author(s)
      岩田 真,石橋善弘
    • Organizer
      日本物理学会
    • Place of Presentation
      関西学院大学
    • Year and Date
      20120324-27
  • [Presentation] Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3混晶の相図2011

    • Author(s)
      岩田 真,飯島直也,石橋善弘
    • Organizer
      日本物理学会
    • Place of Presentation
      富山大学
    • Year and Date
      20110921-24
  • [Presentation] Temperature-Field Phase Diagrams in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32011

    • Author(s)
      M. Iwata, K. Tanaka, and Y. Ishibashi
    • Organizer
      European Meeting of Ferroelectricity (EMF)
    • Place of Presentation
      Bordeaux, France
    • Year and Date
      20110626-27
  • [Presentation] Bi_<4-x>Gd_xTi_3O_<12>の相転移2011

    • Author(s)
      岩田 真,井ノ原智士,石橋善弘
    • Organizer
      強誘電体応用会議(FMA)
    • Place of Presentation
      京都
    • Year and Date
      20110525-28
  • [Presentation] Dielectric Constant under Biasing Field in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32011

    • Author(s)
      M. Iwata, K. Tanaka, and Y. Ishibashi
    • Organizer
      3rd International Conference on Nanoscience and Nanotechnology (NANO-SciTech 2011)
    • Place of Presentation
      Malaysia
    • Year and Date
      20110302-04
  • [Presentation] LuFe_2O_4のコメンシュレート相2011

    • Author(s)
      岩田 真,石橋善弘
    • Organizer
      東北大学金研研究会「電子自由度による強誘電体最前線」
    • Place of Presentation
      東北大学
    • Year and Date
      2011-11-02
  • [Presentation] 90°ドメイン壁から離れた位置でのインディカトリックスの回転2010

    • Author(s)
      岩田 真,石橋善弘
    • Organizer
      20回日本MRS学術シンポジウム セッションG
    • Place of Presentation
      横浜
    • Year and Date
      20101220-21
  • [Presentation] Field Induced Effect in (Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M.Iwata, S. Kato, A. Rintaro, M. Maeda, and YIshibashi
    • Organizer
      3rd Interntional Congress ofCeramics,招待講演
    • Place of Presentation
      Osaka International C onvention Center
    • Year and Date
      20101114-18
  • [Presentation] (Ca,Ba)Tio3混晶の相図へのコメント2010

    • Author(s)
      岩田 真
    • Organizer
      日本物理学会(シンポジウム:強誘電体に潜む新しい秩序)
    • Place of Presentation
      大阪府立大学
    • Year and Date
      20100923-26
  • [Presentation] Field Induced Transition and Behavior of the Phase Front in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M. Iwata and Y. Ishibashi
    • Organizer
      10-th International Symposium on Ferroic Domains and Micro- to Nanoscopic Structures
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      20100920-24
  • [Presentation] Phase Diagram under the Electric Field in (Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M. Iwata, S. Kato, A. Rintaro, M. Maeda, and Y. Ishibashi
    • Organizer
      The 8-th Japan-Korea Conference on Ferroelectrics
    • Place of Presentation
      Himeji
    • Year and Date
      20100803-06
  • [Presentation] Field Induced Phase Transition in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M. Iwata, S. Kato, A. Rintaro, M. Maeda, and Y. Ishibashi
    • Organizer
      AMF-AMEC-2010
    • Place of Presentation
      Jeju island, Korea
    • Year and Date
      20100627-0701
  • [Presentation] The Critical End Point in Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_32010

    • Author(s)
      M. Iwata, S. Kato, A. Rintaro, and M. Maeda, Y Ishibashi
    • Organizer
      RCBJSF-10
    • Place of Presentation
      Yokohama
    • Year and Date
      20100620-24
  • [Presentation] Pb(Zn_<1/3>Nb_<2/3>)O_3-8%PbTiO_3の電場誘起相転移2010

    • Author(s)
      岩田 真、飯島直也、青柳倫太郎、前田雅輝、石橋善弘
    • Organizer
      強誘電体応用会議(FMA)
    • Place of Presentation
      京都
    • Year and Date
      20100526-29
  • [Presentation] 強誘電体MPB近傍の電場誘起効果2010

    • Author(s)
      岩田 真
    • Organizer
      MPB研究会,招待講演
    • Place of Presentation
      物質・材料研究機構,筑波
    • Year and Date
      2010-06-01
  • [Remarks] 研究代表者ホームページ

    • URL

      http://researcher.nitech.ac.jp/html/39_ja.html?1=ja&k=iwata+&o=title-a&p=1

  • [Patent(Industrial Property Rights)] チューナブルキャパシタ2012

    • Inventor(s)
      岩田真、前田雅輝、田中数機
    • Industrial Property Rights Holder
      名古屋工業大学
    • Industrial Property Number
      特願2012-1744803
    • Filing Date
      2012-08-07

URL: 

Published: 2014-08-29  

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