2012 Fiscal Year Final Research Report
Construction and Search for the Function of Novel Phosphole-Based π-Conjugated Molecules
| Project/Area Number |
22350016
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | ホスホール / チタナサイクル / クロスカップリング / 多量体 / キャリヤ移動度 / 有機太陽電池 |
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| Research Abstract |
New efficient methodsfor the synthesis of phosphole-containing π-conjugated molecules were established, and their structure-property relationships were unveiled by various spectroscopy and X-ray crystallography. In addition, some derivatives with high electron-transporting and/or visible-light absorbing abilities were utilized for organic photovoltaics. All the results represent high potential of the newly constructed phosphole derivatives as functional organic materials.
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Research Products
(14 results)
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[Journal Article] Fusion of Phosphole and 1,1'-Biacenaphthene: Phosphorus(V)-Containing Extended π-Systems with High Electron Affinity and Electron Mobility2011
Author(s)
Yoshihiro Matano, Arihiro Saito, Tatsuya Fukushima, Yasuaki Tokudome, Furitsu Suzuki, Daisuke Sakamaki, Hironori Kaji, Akihiro Ito, Kazuyoshi Tanaka, Hiroshi Imahori
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Journal Title
Angew. Chem. Int. Ed.
Volume: 50
Pages: 8016-8020
DOI
Peer Reviewed
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