2012 Fiscal Year Final Research Report
Construction of Functional Self-Assembled Systems based on DynamicProperty of Metal Ions
| Project/Area Number |
22350025
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
HIRAOKA Shuichi 東京大学, 大学院・総合文化研究科, 教授 (10322538)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 超分子化学 / 自己集合 / 多核錯体 |
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| Research Abstract |
In this study we developed a novel synthetic method of C3 symmetric hexaphenylbenzene derivatives from hexaphenylbenzene in two steps. Applying this method, a C3 symmetric tris-monodentate ligand bearing three pyridyl groups was prepared, and was utilized for the construction of an octahedron-shaped self-assembled Zn(II)-capsule complex. The Zn(II)-capsule has anionic monodentate ligands inside the cavity, which were replaced with sulfonate ligands selectively, and thus the inner space of the resulting coordination capsule was easily modified with a variety of functional groups.
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