2013 Fiscal Year Final Research Report
study on metal complexes with extended pi-conjugated system toward molecular circuits
| Project/Area Number |
22350026
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
AKITA Munetaka 東京工業大学, 資源化学研究所, 教授 (50167839)
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| Co-Investigator(Kenkyū-buntansha) |
KOIKE Takashi 東京工業大学, 資源化学研究所, 助教 (30451991)
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| Project Period (FY) |
2010-04-01 – 2014-03-31
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| Keywords | 分子回路 / 分子ワイヤー / 分子ジャンクション / ポルフィリン / 有機金属化学 |
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| Research Abstract |
The following three results relevant to molecular device have been obtained. 1) construction of 2-dimensional wiring system: Hexaarylbenzene turns out to be effective 2-dimensional linker for molecular wiring. 2) mechanism of photoswitching: Dependence of performance on the metal and ligand has been analyzed by quantum chemical method. The occurence is dependent on a process in the final part. 3) metal complexes with extended pi-conjugated systems: Mon-, di- and tetra-nuclear porphyrin complexes are prepared and their properties relevant to stacking, switching of luminescent properties, linker performance, and 2-dimensional M-M interaction have been studied.
These findings would lead to development of molecular devices in the future.
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