2012 Fiscal Year Final Research Report
Synthesis of unusual conducting nano-ribbons by catenating non-planar singlet biradicals
| Project/Area Number |
22350058
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
ITO Shigekazu 東京工業大学, 大学院・理工学研究科, 准教授 (00312538)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 電気 / 磁気的機能 |
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| Research Abstract |
Highly stabilized localized biradicals composed of the four-membered phosphorus heterocycle skeleton possess three-dimensional characteristics and exhibit remarkably high electron-donating ability. In this project we examined molecular design and synthesis of oligo(biradicals) using catenation of the P-heterocyclic biradical units, which induces through-space electrostatic intramolecular interaction. Characterization of the corresponding mixed-valent radical cations upon oxidation was also performed.
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