2012 Fiscal Year Final Research Report
Emergence of Functions in Self-Assembled Cavitand-Based Capsules
| Project/Area Number |
22350060
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
KOBAYASHI Kenji 静岡大学, 創造科学技術大学院, 教授 (40225503)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 超分子 / 分子自己集合 / カプセル / 水素結合 / 動的共有結合 / 包接 / 高分子 |
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| Research Abstract |
(1) We elucidated the unusual stability of our self-assembled hydrogen-bonded cavitand heterocapsule with encapsulation of 1,4-bis(1-propynyl)benzene. Based on this result, we designed and synthesized a dumbbell type of cavitand molecules directed to supramolecular capsule polymers.
(2) We found that our self-assembled boronic ester cavitand capsule serves as a guard nanocontainer against photochemical reactions of anthracene derivatives by the encapsulation. We also succeeded in the synthesis of a chiral boronic ester cavitand capsule.
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