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2012 Fiscal Year Final Research Report

Theelucidation of the relationship between structures and functions of bulkhetero thin films prepared by photoprecursor method

Research Project

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Project/Area Number 22350083
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionNara Institute of Science and Technology

Principal Investigator

YAMADA Hiroko  奈良先端科学技術大学院大学, 物質創成科学研究科, 物質創成科学専攻 (20372724)

Co-Investigator(Kenkyū-buntansha) NAKAYAMA Ken-ichi  山形大学, 理工学研究科, 准教授 (20324808)
Co-Investigator(Renkei-kenkyūsha) UNO Hidemitsu  愛媛大学, 理工学研究科, 教授 (20168735)
OKUJIMA Tetsuo  愛媛大学, 理工学研究科, 准教授 (60359924)
Project Period (FY) 2010 – 2012
Keywordsペンタセン / 光前駆体 / 溶液プロセス / 有機薄膜トランジスタ / 有機薄膜太陽電池 / 結晶構造制御
Research Abstract

In order to confirm therelevance of the photoprecursor method, the preparation procedure of organic field effect transistor (OFET)devices of pentacene by the solution processof the photoprecursor of pentacene (PDK) followed by the photoirradiationwas optimized. The best FET mobility was 0.86 cm2V-1s-1, which is one of the best perforamance of pentacene prepared by the thermal-or photo-precursor methods. Furthermore a various new acene filmswereprepared usingthe photoprecursor method andthe correlation between the compound structures, the film structures, and the photovoltaic performances were investigated in detail.

  • Research Products

    (41 results)

All 2013 2012 2011 2010 Other

All Journal Article (12 results) Presentation (27 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Photo-conversion and structural properties of the drop-casted films of 6,13-pentacene diketone2013

    • Author(s)
      C. Ohashi, H. Yamada, and K. Nakayama
    • Journal Title

      Mol. Cryst. Liq. Cryst

  • [Journal Article] Hetero-Layered Organic Photovoltaic Devices Fabricated Using Soluble Pentacene Photoprecursors2013

    • Author(s)
      T. Motoyama, T. Kiyota, H. Yamada, and K. Nakayama
    • Journal Title

      Solar Energy Materials and Solar Cells

      Volume: 114 Pages: 156-160

    • DOI

      DOI:10.1016/j.solmat.2013.02.023

  • [Journal Article] In Situ Preparation of Highly Fluorescent Pyrene-Dyes from Non-luminous Precursors Upon Photoirradiation2013

    • Author(s)
      T. Aotake, H. Tanimoto, H. Hotta, D. Kuzuhara, T. Okujima, H. Uno, H. Yamada
    • Journal Title

      Chem. Commun

      Volume: 49 Pages: 3661-3663

    • DOI

      DOI:10.1039/C3CC40827B.

  • [Journal Article] Photochemical synthesis of naphthacene and its derivatives for irreversible photo-responsive fluorescent molecules2013

    • Author(s)
      T. Aotake, Y. Yamashita, T. Okujima, N. Shirasawa, Y. Jo, S. Fujimori, H. Uno, N. Ono, H. Yamada
    • Journal Title

      Tetrahedron Lett

      Volume: 54 Pages: 1790-1793

    • DOI

      DOI:10.1016/j.tetlet.2013.01.014.

  • [Journal Article] Synthesis,Structure,and Photochemistry of 5,14-Diketopentacene2012

    • Author(s)
      T. Aotake, S. Ikeda, D. Kuzuhara, S. Mori, T. Okujima, H. Uno, H. Yamada
    • Journal Title

      Eur. J. Org. Chem

      Pages: 1723-1729

    • DOI

      DOI:10.1002/ejoc. 201101736

  • [Journal Article] FET performance and substitution effect on 2,6-dithienyl anthracene devices prepared by photoirradiation of their diketone precursors2012

    • Author(s)
      H. Yamada, C. Ohashi, T. Aotake, S. Katsuta, Y. Honsho, H. Kawano, T. Okujima, H. Uno, N. Ono, S. Seki, K. Nakayama
    • Journal Title

      Chem. Commun

      Volume: 48 Pages: 11136-11138

    • DOI

      DOI:10.1039/ C2CC35439J.

  • [Journal Article] 革新的塗布型材料による有機薄膜太陽電池の構築2012

    • Author(s)
      山田容子, 中山健一
    • Journal Title

      化学工業

      Volume: 63 Pages: 823-829

    • URL

      http://www.kako-sha.co.jp/

  • [Journal Article] Synthesis of pentacene-, tetracene-and antracene bisimides using double-cyclization reaction mediated by nbismuth(III) triflate2011

    • Author(s)
      S. Katsuta, K. Tanaka, Y. Maruya, S. Mori, S. Masuo, T. Okujima, H. Uno, K. Nakayama, H. Yamada
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 10112-10114

    • DOI

      DOI:10.1039/c1cc13980k.

  • [Journal Article] Properties and Ambipolar Organic Field-Effect Transistor Performances of Symmetrically Cyanated Pentacene and Naphthacene as Air-Stable Acene Derivatives2011

    • Author(s)
      S. Katsuta, D.i Miyagi, H. Yamada, T. Okujima, S. Mori, K. Nakayama, H. Uno,Synthesis
    • Journal Title

      Org. Lett

      Volume: 13 Pages: 1454-1457

    • DOI

      DOI:10.1021/ol200145r.

  • [Journal Article] 前駆体法を利用した機能性π共役拡張化合物の合成と物性2011

    • Author(s)
      山田容子, 葛原大軌, 勝田修平, 奥島鉄雄, 宇野英満
    • Journal Title

      有機合成化学協会誌

      Volume: 69 Pages: 802-813

    • URL

      https://www.jstage. jst.go.jp/browse/yukigoseikyokaishi/69/7/_contents/-char/ja/

  • [Journal Article] Photochemical synthesis of tetraaryl- substituted pentacenes2010

    • Author(s)
      S. Katsuta, H. Yamada, T. Okujima, H. Uno
    • Journal Title

      Tetrahedron Lett

      Volume: 51 Pages: 1397-1400

    • DOI

      DOI:10.1016/j.tetlet.2010. 01.009

  • [Journal Article] Synthesis and photochemical -diketoporphyrins as -expandedporphyrins2010

    • Author(s)
      H. Yamada, D. Kuzuhara, K. Ohkubo, T. Takahashi, T. Okujima, H. Uno, N. Ono, S. Fukuzumi
    • Journal Title

      J. Mater. Chem

      Volume: 20 Pages: 3011-3024

    • DOI

      DOI:10.1039/b923220f.

  • [Presentation] 光変換前駆体法を用いた対称型アントラセンーチオフェンオリゴマーの合成と物性評価2013

    • Author(s)
      池田慎也、杉井秀平、元山貴雄、中山健一、山田容子
    • Organizer
      2013年日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] 光変換法によるオリゴチオフェン連結アントラセンの合成と物性2013

    • Author(s)
      杉井秀平,池田慎也,元山貴雄,葛原大軌,荒谷直樹,中山健一,山田容子
    • Organizer
      2013年日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] 末端部位に置換基を有するペンタセンの光による合成2013

    • Author(s)
      勝田修平,大橋知佳,元山貴雄,増尾貞弘,中山健一,山田容子
    • Organizer
      2013年日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] チオフェン縮環アントラセンのジケトン前駆体の合成と物性比較2013

    • Author(s)
      兼重吉孝,立中佑希,勝田修平,大橋知佳,葛原大軌,荒谷直樹,中山健一,山田容子
    • Organizer
      2013年日本化学会第93春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] Syntheses and Photovoltaic Properties of Anthracene-Thiophene Oligomers Using Photo-Convertible Soluble Precursors2013

    • Author(s)
      S. Ikeda, S. Sugii, T. Aotake, T. Motoyama, K. Nakayama, H. Yamada
    • Organizer
      7th Inter. Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      Fukuoka
    • Year and Date
      2013-03-18
  • [Presentation] Photochemical Synthesis and FET Performance of Acene Derivatives Using Soluble Precursors (Invited)2012

    • Author(s)
      H. Yamada, T. Aotake, S. Katsuta, C. Ohashi, K. Nakayama
    • Organizer
      A-COE2012
    • Place of Presentation
      米沢
    • Year and Date
      2012-12-21
  • [Presentation] Synthesis and Properties of Acenes Photochemically Prepared from Diketone Precursors (Invited)2012

    • Author(s)
      H. Yamada, T. Aotake, S. Katsuta, Y. Kaneshige, C. Ohashi, K. Nakayama
    • Organizer
      PRiME2012, Hawaii
    • Place of Presentation
      Honolulu.
    • Year and Date
      2012-10-10
  • [Presentation] Synthesis and properties of pentacenes having alkyl-chains at 2,3,9,10-positions2012

    • Author(s)
      S. Katsuta, C. Ohashi, K. Nakayama, H. Yamada
    • Organizer
      PRiME2012, Hawaii
    • Place of Presentation
      Honolulu
    • Year and Date
      2012-10-10
  • [Presentation] チオフェン縮環アセン類の前駆体による合成と光物性2012

    • Author(s)
      立中佑希,勝田修平,大橋知佳,中山健一,山田容子
    • Organizer
      2012年基礎有機化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2012-09-21
  • [Presentation] 光反応を用いた2,3,9,10-テトラアルキルペンタセンの合成と半導体特性2012

    • Author(s)
      勝田修平,大橋知佳,中山健一,山田容子
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-12
  • [Presentation] アントラ[1,2-b:5,6-b']ジチオフェン-ジケトン前駆体の 光反応を用いた塗布変換型OFETデバイスの作製2012

    • Author(s)
      兼重吉孝,大橋知佳,中山健一,山田容子
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2012-09-12
  • [Presentation] 新しいπ共役拡張化合物の創出と機能2012

    • Author(s)
      山田容子
    • Organizer
      2012年秋季第73回応用物理学会学術講演会
    • Place of Presentation
      松山
    • Year and Date
      2012-09-11
  • [Presentation] ペンタセン光前駆体のドロップキャスト膜からの結晶成長2012

    • Author(s)
      大橋知佳,山田容子、中山健一
    • Organizer
      2012年秋季第73回応用物理学会学術講演会
    • Place of Presentation
      松山
    • Year and Date
      2012-09-11
  • [Presentation] Photo-conversion and structural properties of the drop-casted films of 6,13-pentacene diketone2012

    • Author(s)
      C. Ohashi, H. Yamada, K. Nakayama
    • Organizer
      KJFInter. Conference on Organic Materials for Electronics and Photonics 2012
    • Place of Presentation
      Sendai
    • Year and Date
      2012-08-31
  • [Presentation] 光変換型ペンタセンの半導体物性と太陽電池への応用2012

    • Author(s)
      中山健一, 大橋知佳, 元山貴雄, 清田達郎, 山田容子
    • Organizer
      第1回有機太陽電池ワークショップ
    • Place of Presentation
      山形
    • Year and Date
      2012-04-21
  • [Presentation] 可溶性前駆体を用いた含チオフェンアセン誘導体の合成とOFET特性2012

    • Author(s)
      青竹達也,大橋知佳,勝田修平,中山健一,山田容子
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-26
  • [Presentation] 可溶性ペンタセン前駆体を用いた積層型有機太陽電池2012

    • Author(s)
      元山貴雄, 清田達郎, 山田容子, 中山健一
    • Organizer
      2012春季第59回応用物理学会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-18
  • [Presentation] 光変換型ペンタセンFETにおける光照射条件の検討2012

    • Author(s)
      大橋知佳,山田容子, 中山健一
    • Organizer
      2012春季第59回応用物理学会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-18
  • [Presentation] Film structure and FET performance of pentacene from soluble photoprecursor2011

    • Author(s)
      K. Nakayama, Y. Oikawa, C. Ohashi, J. Kido, H. Yamada
    • Organizer
      2011 MRS Fall Meeting
    • Place of Presentation
      Boston(USA)
    • Year and Date
      2011-11-28
  • [Presentation] ペンタセン系塗布型有機電子材料の開発2011

    • Author(s)
      山田容子,勝田修平,青竹達也,及川悦誠,大橋知佳,中山健一
    • Organizer
      第60回高分子討論会(依頼講演)
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-28
  • [Presentation] Development of Small Molecular Organic Semiconductors for Printed Electronics2011

    • Author(s)
      山田容子
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-17
  • [Presentation] 光変換型ペンタセンFETにおける溶媒添加効果2011

    • Author(s)
      中山健一, 及川悦誠,大橋知佳,城戸淳二,山田容子
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形
    • Year and Date
      2011-09-02
  • [Presentation] 塗布型低分子有機半導体材料の開発2011

    • Author(s)
      山田容子・大橋知佳・及川悦誠・青竹達也・勝田修平・中山健一
    • Organizer
      CREST 有機太陽電池シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2011-07-15
  • [Presentation] ペンタセン骨格を有する塗布型有機電子材料の開発2011

    • Author(s)
      山田容子
    • Organizer
      応用物理学会有機分子・バイオエレクトロニクス分科会研究会
    • Place of Presentation
      神戸
    • Year and Date
      2011-06-25
  • [Presentation] 塗布型有機半導体材料の開発2011

    • Author(s)
      山田容子
    • Organizer
      SEMI Forum 2011 Japan
    • Place of Presentation
      大阪
    • Year and Date
      2011-05-31
  • [Presentation] 光変換型ペンタセン材料における薄膜作製条件の検討2011

    • Author(s)
      清田達郎, 及川悦誠, 中山健一, 城戸淳二, 山田容子
    • Organizer
      2011年春季大58回応用物理学関係連合講演会
    • Place of Presentation
      厚木
    • Year and Date
      2011-03-25
  • [Presentation] Preparation and FET Properties of Spun-Cast Pentacene Films Prepared from Diketone Precursors2010

    • Author(s)
      T.Aotake, J. Hashizume, T. Kusunoki, Y. Honsho, T. Okujima, H. Uno, S. Seki, K. Nakayama, and H. Yamada
    • Organizer
      International conference of Science and Technology of Synttic Metals 2010.
    • Place of Presentation
      Kyoto
    • Year and Date
      2010-07-08
  • [Book] 有機デバイスのための塗装技術2012

    • Author(s)
      山田容子、中山健一
    • Total Pages
      21-41
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://mswebs.naist.jp/LABs/env_photo_greenmat/Yamada_Research_Group/index.html

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Published: 2014-08-29  

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