2012 Fiscal Year Final Research Report
Synthesis of Cyclic Oligomers by the Dynamic Covalent Chemistry Mechanism and their Application for Resist Materials
| Project/Area Number |
22350088
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic industrial materials
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| Research Institution | Kansai University (2012)
Kanagawa University (2010-2011) |
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Principal Investigator |
KUDO Hiroto 関西大学, 化学生命工学部, 准教授 (30343635)
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| Project Period (FY) |
2010 – 2012
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| Keywords | レジスト |
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| Research Abstract |
A new dynamic covalent chemistry (DCC) system in the reaction of resorcinol and 1,5-pentanedial could be achieved, yielding a only soluble oligomer noria (noria means water wheel in Latin) in high yield, resembling a water-wheel in appearance. Application of the noria derivatives with pendant photo-reactive groups were examined for UV-curing materials and photo-resist materials. The obtained noria derivatives had good solubility, good film-forming ability, high thermal stability, and high photo-chemical reactivity. Furthermore, certain new ladder cyclic oligomers could be synthesized using a similar approach to that employed for the synthesis of noria and their application as next generation resist materials was also investigated
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