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2012 Fiscal Year Final Research Report

Thin film preparation and its extension to photofunctional devices of low-density organic polymer with transparency

Research Project

  • PDF
Project/Area Number 22350099
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

NAGAI Keiji  東京工業大学, 資源化学研究所, 准教授 (30280803)

Co-Investigator(Renkei-kenkyūsha) IYODA Tomokazu  東京工業大学, フロンティア研究機構, 教授 (90168534)
HADANO Shingo  高知大学, 理学部, 助教 (70397157)
ABE Toshiyuki  弘前大学, 大学院・理工学研究科, 准教授 (20312481)
NORIMATSU Takayoshi  大阪大学, レーザーエネルギー学研究センター, 教授 (50135753)
Project Period (FY) 2010 – 2012
Keywords高分子機能材料
Research Abstract

Low density plastic materials have long history and reaches to transparency based on its small pore size less than wavelength of light. In comparison to inorganic aeregel, organic one has small example numbers. In the present project, the size of pore has been minimized to 10 nm. The control of the pore size was investigated from the view point of the gelation to form precursor.As for the photo functionalization, visible light responsive photoctalyst was incorporated to the aerogel. The evaluation of the photocatalysis was done for the oxidation of aldehyde, amine, thiol, and amide, to carbondioxide.

  • Research Products

    (20 results)

All 2013 2012 2011 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (11 results) Remarks (1 results)

  • [Journal Article] 有機太陽電池の活 性層を用いた全可視光応答光触媒-汚濁物質分解・水分解へむけて?"(Full-spectrum-visible-light photocatalyst based on the active layer of an organic solar cell-towards water splitting and volatile molecule degradation-)2013

    • Author(s)
      長井圭治,阿部敏之
    • Journal Title

      高分子論文集KOBUNSHI RONBUNSHU Japanese Journal of Polymer Science and Technology

      Volume: (in press) Pages: 70

    • Peer Reviewed
  • [Journal Article] Photoelectrode Characteristics of Partially Hydrolyzed Aluminum Phthalocyanine Chloride/Fullerene C60 Composite Nanoparticles Working in a Water Phase2012

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      Molecules

      Volume: 17(9) Pages: 10801-10815

    • Peer Reviewed
  • [Journal Article] Photocatalytic Decomposition ofN-methyl-2-pyrrolidone, Aldehydes, and Thiol by Biphase and p/n Junction-like Organic Semiconductor Composite Nanoparticles Responsive to Full Spectrum of Visible Light2012

    • Author(s)
      Shuai Zhang, Prabhakarn Arunachalam, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      J. Photochem. Photobiol. Part A Photochem

      Volume: 244 Pages: 18-23

    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of Biphasic Vanadyl phthalocyanine and C60 composite nanoparticles through a reprecipitation process2012

    • Author(s)
      Arunachalam Prabhakarn, Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, and Keiji Nagai*
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 37[2] Pages: 205- 208

    • Peer Reviewed
  • [Journal Article] Organic Semiconductor Nanoparticles with Heterojunctions Composed of Fullerene C60 and Zinc Phthalocyanine and Their Application to Visible-Light-Responsive Photocatalysts2011

    • Author(s)
      Shuai Zhang, Toshiyuki Abe, Tomokazu Iyoda, Takayoshi Norimatsu, and Keiji Nagai*
    • Journal Title

      Transactions of the Materials ResearchSociety of Japan

      Volume: 36[2] Pages: 177-181

    • Peer Reviewed
  • [Journal Article] Effect of Nd:YAG Laser Energy on Multilayer Hollow Nanofiber Target's Extreme Ultraviolet Conversion Efficiency2011

    • Author(s)
      Liqin Ge*, Jianyu Ji, Lingling Bai, Teng Fei, Weichen Wang, Keiji Nagai, Hiroaki Nishimura, Yasukazu Izawa, Kunioki Mima& Takayoshi Norimatsu
    • Journal Title

      J. Macromol. Sci. Part B Phys.

      Volume: 50(9) Pages: 1761-1770

    • Peer Reviewed
  • [Journal Article] Photoelectrochemical and Photocatalytic Properties of Biphasic Organic p- and n-Type Semiconductor Nanoparticles Fabricated by a Reprecipitation Process2011

    • Author(s)
      Shuai Zhang, Ryohei Sakai, Toshiyuki Abe, Tomokazu Iyoda,Takayoshi Norimatsu,and Keiji Nagai*
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 3 (6) Pages: 1902-1909

    • Peer Reviewed
  • [Journal Article] Monolithic and Low-Density (<50 mg/cm3) Metal Oxides Fabricated Using Electrospinning: Vanadium Oxide and Copper Oxide Examples2011

    • Author(s)
      Keiji Nagai*, Kohei Miyamoto, To mokazu Iyoda, Cao Pan, Zhongze Gu
    • Journal Title

      Fusion Sci. Technol

      Volume: 59 (1) Pages: 216-220

    • Peer Reviewed
  • [Presentation] FULL-SPECTRUM VISIBLE-LIGHT-RESPONSIVE ORGANOPHOTOCATALYST FILM2012

    • Author(s)
      Keiji Nagai, Prabhakarn Arunachalam, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      International Symposium on Polymer Chemistry (PC2012)
    • Place of Presentation
      ChangChun
    • Year and Date
      20120602-0606
  • [Presentation] Low density plastics target fabrication and its deuteration for laser-induced D-D reaction2011

    • Author(s)
      Keiji Nagai, Ayumi Hatano
    • Organizer
      Workshop on Ashura (Asia laser plasma) Project 2011
    • Place of Presentation
      Kanazawa ANA Crown hotel
    • Year and Date
      20111125-1130
  • [Presentation] フロログルシノールとフロログ ルシノールカルボン酸を用いたフェノー ル樹脂由来多孔質ゲルの合成とナノ構造に関する研究2011

    • Author(s)
      幡野亜由美、波多野慎悟、彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      20110928-30
  • [Presentation] Influences of the affinity between exchange solvents and organic aerogels consisting of phenols and formaldehyde2011

    • Author(s)
      Ayumi Hatano, Shingo Hadano, Tomokazu Iyoda, and Keiji Nagai
    • Organizer
      The 18th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'18) 2011
    • Place of Presentation
      Tianjin
    • Year and Date
      20110916-0918
  • [Presentation] Full-Spectrum Visible-Light-Responsive Organophotocatalyst Film for Removal and Degradation of Low Concentration Volatile molecules2011

    • Author(s)
      Keiji Nagai, Yuzuri Yasuda, Ichirou Kimishima, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      The 18th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'18) 2011
    • Place of Presentation
      Tianjin
    • Year and Date
      20110916-0918
  • [Presentation] PHOTOCATALYTIC DEGRADATION OF VOLATILE ORGANIC CCOMPOUNDS BY ORGANIC SEMICONDUCTORS WITH P-N JUNCTION RESPONSIVE TO FULL-SPECTRUM VISIBLE LIGHT2011

    • Author(s)
      Keiji Nagai
    • Organizer
      INV-S13-11, The 14th Asian Chemical Congress 2011 (14 ACC) 2011
    • Place of Presentation
      Bangkok
    • Year and Date
      20110905-0908
  • [Presentation] Transparent adsorbent materials consisting of cellulose derivatives2011

    • Author(s)
      Risa Arai and Keiji Nagai
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering (ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Year and Date
      20110606-0609
  • [Presentation] Degradation of Organic Compounds Using Organophotocatalyst with p-n Junction Responsive to Full-Spectrum Visible Light2011

    • Author(s)
      Keiji Nagai, Shuai Zhang,Yuzuri Yasuda, Ichirou Kimishima, Tomokazu Iyoda, Toshiyuki Abe
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering(ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Year and Date
      20110606-0609
  • [Presentation] Effect of solvent exchange in preparation of aerogels consisting of resorcinol and phloroglucinol carboxylic acid2011

    • Author(s)
      Ayumi HATANO, Shingo HADANO, Tomokazu IYODA, Keiji NAGAI
    • Organizer
      The 6th International Symposium on Integrated Molecular/Materials Engineering (ISIMME'6) 2011
    • Place of Presentation
      Beijing
    • Year and Date
      20110606-0609
  • [Presentation] フロログルシノールとフロログルシノールカルボン酸を用いたフェノール樹脂由来多孔質ゲルの合成と化学構造解析2011

    • Author(s)
      幡野亜由美、波多野慎悟、彌田智一、長井圭治
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪国際会議場
    • Year and Date
      20110524-27
  • [Presentation] セルソース誘導体エアロゲルによるホルムアルデヒドの吸着2011

    • Author(s)
      荒井理沙、彌田智一、長井圭治
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
  • [Remarks] 東京工業大学彌田・長井研究室ホームページ

    • URL

      http://ime.res.titech.ac.jp/

URL: 

Published: 2014-08-29  

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