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2012 Fiscal Year Final Research Report

Development of a single spin-rotational state-selected O2 beam and its application to the surface reaction analysis

Research Project

  • PDF
Project/Area Number 22360021
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

KURAHASHI Mitsunori  独立行政法人物質・材料研究機構, 極限計測ユニット, 主幹研究員 (10354359)

Project Period (FY) 2010 – 2012
Keywords表面 / 酸素分子 / 立体 / スピン
Research Abstract

O2 is a magnetic molecule with an anisotropic shape, and its interaction with surfaces is important technologically. In this study, we prepared a state-selected O2 beam, for which both the spin and the rotational angular momentum are well defined, by using magnetic hexapolar field technique. In O2 sticking on Si(100), we have found that molecules parallel to surfaces are much more reactive than those perpendicular to the surface. We also clarified the dynamical process of O2 adsorption on Al(111), which has been disputed for more than 20 years.

  • Research Products

    (18 results)

All 2013 2012 2011 2010 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (10 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Steric Effect in O2 Sticking on Al(111): Preference for Parallel Geometry2013

    • Author(s)
      M. Kurahashi and Y. Yamauchi
    • Journal Title

      Phys. Rev. Lett.

      Volume: 110 Pages: 4

    • Peer Reviewed
  • [Journal Article] Huge steric effects in surface oxidation of Si(100)2012

    • Author(s)
      M. Kurahashi and Y. Yamauchi
    • Journal Title

      Phys. Rev. B

      Volume: 85[16] Pages: 4

    • Peer Reviewed
  • [Journal Article] Magnetic properties of O2 adsorbed on Cu(100): A spin-polarized metastable He beam study2012

    • Author(s)
      M. Kurahashi, X. Sun, Y. Yamauchi
    • Journal Title

      Phys. Rev. B

      Volume: 86[24] Pages: 6

    • Peer Reviewed
  • [Journal Article] Spin polarization of the Si(111)-7 x 7 surface: A study with a spin-polarized metastable helium atom beam2011

    • Author(s)
      M. Kurahashi, A. Pratt, Y. Yamauchi
    • Journal Title

      Surf. Sci.

      Volume: 605 Pages: 612-615

    • Peer Reviewed
  • [Journal Article] Spin-polarized metastable He study of surface magnetic order in Ho thin films2011

    • Author(s)
      A. Pratt, M. Kurahashi, Y. Yamauchi
    • Journal Title

      J. Appl. Phys.

      Volume: 109 Pages: 3

    • Peer Reviewed
  • [Journal Article] 六極磁子による酸素分子の単一スピン・回転状態選別2010

    • Author(s)
      倉橋光紀、山内泰
    • Journal Title

      J. Vac. Soc. Of Japan

      Volume: 53 Pages: 681-685

    • Peer Reviewed
  • [Presentation] Al(111)表面初期酸化における立体効果の観測2013

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      日本物理学会第68回年次大会
    • URL

      -

    • Place of Presentation
      広島大学
    • Year and Date
      20130326-29
  • [Presentation] Si(100)表面酸化における立体異方性:面内方位依存性の観測2012

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      20120918-21
  • [Presentation] Observation of a large steric effect in the initial oxidation of Si(100)2012

    • Author(s)
      M. Kurahashi, Y. Yamauchi
    • Organizer
      The 24th conference of the EPS condensed matter division
    • Place of Presentation
      Edinburgh convention center, Edinburgh, UK
    • Year and Date
      20120902-07
  • [Presentation] Observation of large steric effects in O2 adsorption on Si(100)2012

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      第28回化学反応討論会
    • Place of Presentation
      九州大学
    • Year and Date
      20120606-08
  • [Presentation] Si(100)表面初期酸化における立体効果の観測2012

    • Author(s)
      倉橋光紀, 山内泰:
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学
    • Year and Date
      20120315-18
  • [Presentation] State-selected O2 beam andsteric effects in the initial oxidation ofSi(100)2012

    • Author(s)
      M. Kurahashi
    • Organizer
      Seminar at FOM institute DIFFER
    • Place of Presentation
      Nieuwegein, the Netherlands
    • Year and Date
      2012-08-27
  • [Presentation] 状態選別酸素分子ビームによる表面反応立体異方性の観測2011

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      2011年日本物理学会秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      20110921-24
  • [Presentation] Production of a single spin-rotational-state-selected O2 beam by a hexapole magnet2011

    • Author(s)
      M. Kurahashi
    • Organizer
      special seminar in Department of Chemistry
    • Place of Presentation
      National aiwan University, Taipei, Taiwan
    • Year and Date
      20110623-24
  • [Presentation] Development of a elocity variable state-selected O2 beam2011

    • Author(s)
      倉橋光紀, 山内泰
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      20110608-10
  • [Presentation] 速度可変単一スピン・回転状態選別酸素分子ビームの開発(I)2011

    • Author(s)
      倉橋光紀、山内泰
    • Organizer
      応用物理学会春季大会
    • Place of Presentation
      神奈川工科大学(震災のため中止)
    • Year and Date
      20110324-27
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

  • [Patent(Industrial Property Rights)] 永久磁石型多段六極磁子装置及び六極磁子焦点距離可変方法2011

    • Inventor(s)
      倉橋光紀、山内泰
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Patent Publication Number
      特開2013-020855号
    • Filing Date
      2011-07-13

URL: 

Published: 2014-08-29  

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