2012 Fiscal Year Final Research Report
Development of High Performance Heterogeneous Catalysts and NewCatalytic Reactions Based on the Properties of Metal Hydroxides
| Project/Area Number |
22360334
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | The University of Tokyo |
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Principal Investigator |
YAMAGUCHI Kazuya 東京大学, 大学院・工学系研究科, 准教授 (50334313)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 金属水酸化物 / 固体触媒 / 有機合成 / 溶存状態制御 / 新反応開拓 |
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| Research Abstract |
In this project, high performance heterogeneous catalysts based on the properties of metal hydroxides and oxides have been developed. For example, supported copper hydroxides could act as efficient heterogeneous catalysts for aerobic oxidative homocoupling of terminal alkynes and 1,3-dipolar cycloaddition. In addition, several new catalytic transformations, e.g., oxidative amidations of alcohols, amines, and alkylarenes using OMS-2 as a catalyst, molecular oxygen as an oxidant and ammonia as a nitrogen source, have also been developed.
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