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2012 Fiscal Year Final Research Report

Preparation of gas Hydrates with the Balance between Gas Storage Amounts and Formation Conditions

Research Project

  • PDF
Project/Area Number 22360410
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionOsaka University

Principal Investigator

SUGAHARA Takeshi  大阪大学, 大学院・基礎工学研究科, 助教 (20335384)

Co-Investigator(Kenkyū-buntansha) OHGAKI Kazunari  大阪大学, 大学院・基礎工学研究科, 今日中 (80107078)
Project Period (FY) 2010 – 2012
Keywordsエネルギー輸送・貯藏 / ガスハイドレート / 水素 / 天然ガス / 化学工学 / ラマン分光分析 / 高圧示差走査分析
Research Abstract

To establish the preparation method of gas hydrates with the balance between the storage capacity and the formation and storage condition, the mechanism of the tuned large-cage occupancy of gases (tuning effect) under the existence ofadditives has been investigated. The present experimental results reveal that the important factors for the tuning effect are both the existence of mobile water molecules (quasi-liquid layer) at the ice surface and the competitive large-cage occupancy of gases and additives.

  • Research Products

    (15 results)

All 2013 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 3 results) Presentation (8 results) Remarks (2 results)

  • [Journal Article] In situ Raman Spectra of Hydrogen in Large Cages of Hydrogen +Tetrahydrofuran Mixed Hydrates2013

    • Author(s)
      A. Nishikawa, T. Tanabe, K. Kitamura, K. Ohgaki, T. Sugahara
    • Journal Title

      Chem. Eng. Sci.

      Volume: (in press)

    • DOI

      DOI:10.1016/j.ces.2013.05.044

    • Peer Reviewed
  • [Journal Article] ガスハイドレートの科学と技術2011

    • Author(s)
      菅原 武、大垣一成
    • Journal Title

      化学と教育

      Volume: 60巻 Pages: 8-13

    • URL

      http://www.chemistry.or.jp/journal/chemicaleducation/vol60-no1.html

  • [Journal Article] Large-Cage Occupancies of Molecular Hydrogen in Binary Clathrate Hydrates Dependent on Pressures2011

    • Author(s)
      T. Sugahara, P.S.R. Prasad, E.D. Sloan, A.K. Sum, C.A. Koh, K. Ohgaki
    • Journal Title

      Phys. Chem. Ice 2010

      Pages: 117-125

    • URL

      http://hup.gr.jp/modules/zox/index.php?main_page=product_book_info&products_id=787

    • Peer Reviewed
  • [Journal Article] 温和な条件における分子状水素貯蔵媒体の探求2011

    • Author(s)
      菅原 武
    • Journal Title

      大阪大学低温センターだより

      Volume: 157巻 Pages: 1-5

    • URL

      http://hdl.handle.net/11094/8579

  • [Journal Article] Large-Cage Occupancies of Hydrogen in Binary Clathrate Hydrates Dependent on Pressures and Guest Concentrations2010

    • Author(s)
      T. Sugahara, J.C. Haag, A.A. Warntjes, P.S.R. Prasad, E.D. Sloan, A.K. Sum, C.A. Koh
    • Journal Title

      J. Phys. Chem. C

      Volume: Vol. 114 Pages: 15218-15222

    • DOI

      DOI:10.1021/jp105379x

    • Peer Reviewed
  • [Presentation] ガスハイドレートの熱力学的安定性とゲスト分子の籠占有性2012

    • Author(s)
      菅原 武
    • Organizer
      化学工学会第44回秋季大会(招待講演)
    • Place of Presentation
      東北大学
    • Year and Date
      2012-09-21
  • [Presentation] 混合ハイドレートにおける水素と補助剤の競争的籠占有2012

    • Author(s)
      西川明男、田邉智大、菅原 武、大垣一成
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学
    • Year and Date
      2012-09-20
  • [Presentation] ガスハイドレート利用研究の現状と課題2011

    • Author(s)
      菅原 武
    • Organizer
      第4回化学工学学会3支部合同福井大会(招待講演)
    • Place of Presentation
      ホテルフジタ福井
    • Year and Date
      2011-12-09
  • [Presentation] 構造II型ハイドレートにおける水素分子のケージ占有性2011

    • Author(s)
      菅原 武、西川明男、北村一磨、大垣一成
    • Organizer
      日本高圧力学会第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2011-11-08
  • [Presentation] H_2+tert-butylamine+H_2O系の相平衡測とラマン分光分析2011

    • Author(s)
      田邉智大、西川明男、菅原 武、大垣一成
    • Organizer
      日本高圧力学会第53回高圧討論会
    • Place of Presentation
      大阪大学
    • Year and Date
      2011-11-07
  • [Presentation] 水素+アセトン混合ガスハイドレートにおける水素のL-cage占有性2011

    • Author(s)
      藤澤祐弥、西川明男、津田崇暁、菅原 武、大垣一成
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2011-09-14
  • [Presentation] Molecular Storage of Hydrogen in Simple and Binary Clathrate Hydrates2011

    • Author(s)
      T. Sugahara, T. Tsuda, K. Ohgaki, P.S.R. Prasad, V. Taghikhani, E.D. Sloan, C.A. Koh, A.K. Sum
    • Organizer
      7th International Conference on Gas Hydrates
    • Place of Presentation
      エジンバラ(イギリス)
    • Year and Date
      2011-07-20
  • [Presentation] Structural Stability of (t-BuNH2-H2/CH4) Binary Hydrates2011

    • Author(s)
      P.S.R. Prasad, T. Sugahara, E.D. Sloan, A.K. Sum, C.A. Koh
    • Organizer
      7th International Conference on Gas Hydrates
    • Place of Presentation
      エジンバラ(イギリス)
    • Year and Date
      2011-07-19
  • [Remarks] 西川明男 シンポジウム最優秀学生講演賞受賞(化学工学会第44回秋季大会,2012)

  • [Remarks] シンポジウム優秀学生講演賞受賞(化学工学会第43回秋季大会,2011)

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Published: 2014-08-29  

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