2012 Fiscal Year Final Research Report
Synthesis of Atrane-type Molecules including Group 14 Elements and Their Unique Electronic Systems
| Project/Area Number |
22550037
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Hiroshima University |
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Principal Investigator |
KAWACHI Atsushi 広島大学, 大学院・理学研究科, 准教授 (70260619)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 14族元素 / アトラン分子 / ラジカル / 半結合 / スピン挙動 |
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| Research Abstract |
Tris[o-(fluorodimethylsilyl)phenyl]germylpotassium was prepared by tcleavage of the Si-Ge bond in the corresponding benzosilagermacyclobutene withKF. Reaction of the germylpotassium with dimethylchlorosilane afforded the dimethylsilylgermane. Reaction of [o-(fluorodimethylsilyl)phenyllithium with a SiCl2-carbene complex provided a novel {[o-(fluorodimethylsilyl)phenyl}chlorosilylene-carbene complex.
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