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2012 Fiscal Year Final Research Report

Creation of Functionalized Chiral Heterobidentate Ferrocene Ligands bearing a Heterocyclic Group and Their Catalysis

Research Project

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Project/Area Number 22550044
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionChuo University

Principal Investigator

FUKUZAWA Shinichi  中央大学, 理工学部, 教授 (50173331)

Co-Investigator(Renkei-kenkyūsha) OGATA Kenichi  中央大学, 理工学部, 助教 (60431970)
Project Period (FY) 2010 – 2012
Keywordsフェロセン / 不斉触媒 / ヘテロ環 / 異原子配位子 / 環化付加反応 / 共役付加反応アゾメチンイリド
Research Abstract

Chiral ferrocenyl hetero-bidentate ligand, ThioClickFerrophos was newly prepared. The complex of silver acetate with ThioClickFerrophos was efficient catalyst for the reaction using glycine imino ester as a starting compound. Thus, it cata

  • Research Products

    (19 results)

All 2013 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (11 results) Remarks (1 results)

  • [Journal Article] Stereochemistry of Substitution of the α-Dimethylamino Group by Dialkylzinc in ChiralBenzylferrocene2012

    • Author(s)
      T. Takahashi, K. Ogata, S. Fukuzawa
    • Journal Title

      J. Org. Chem

      Volume: 77 Pages: 6638-6642

    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Enantioselective Hydrogenation of Unsaturated Phosphonates by ClickFerrophos Ligands2012

    • Author(s)
      T. Konno, K. Shimizu, K. Ogata, S. Fukuzawa
    • Journal Title

      J. Org. Chem

      Volume: 77 Pages: 3318-3324

    • Peer Reviewed
  • [Journal Article] Silver/ThioClickFerrophos-Catalyzed Enantioselective Conjugate Addition and Cycloaddition of Glycine Imino Ester with Nitroalkenes2012

    • Author(s)
      K. Imae, T. Konno, K. Ogata, S. Fukuzawa
    • Journal Title

      Org. Lett

      Volume: 14 Pages: 4410-4413

    • Peer Reviewed
  • [Journal Article] Copper(I) 1,2,3-Triazol-5-ylidene Complexes as Efficient Catalysts for Click Reactions of Azides with Alkynes2011

    • Author(s)
      T . Nakamura, T. Terashima, K. Ogata, S. Fukuzawa
    • Journal Title

      Org. Lett

      Volume: 13 Pages: 620-623

    • Peer Reviewed
  • [Journal Article] Ag/ThioClickFerrophos-Catalyzed Enantioselective Mannich Reaction and Amination of Glycine Schiff Base2011

    • Author(s)
      K. Imae, K. Shimizu, K. Ogata, S. Fukuzawa
    • Journal Title

      J. Org. Chem

      Volume: 76 Pages: 3604-3608

    • Peer Reviewed
  • [Journal Article] Highly Endo-Selective and Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylide with α-Enones Catalyzed by a Silver(I)/ThioClickFerrophos Complex2010

    • Author(s)
      I. Oura, K. Shimizu, K. Ogata, S. Fukuzawa
    • Journal Title

      Org. Lett

      Volume: 39 Pages: 1752-1755

    • Peer Reviewed
  • [Journal Article] Ag/ThioClickFerrophos catalyzed highly enantioselective 1,3-dipolar cycloaddition of azomethine ylides with alkenes2010

    • Author(s)
      K. Shimizu, K. Ogata, S. Fukuzawa
    • Journal Title

      Tetrahedron Lett

      Volume: 51 Pages: 5068-5070

    • Peer Reviewed
  • [Presentation] 二官能性触媒酢酸銀/ThioClickFerrophos 錯体を用いるアゾメチンイリドと電子不足アルケンとの不斉 1,3‐ 双極子環化付加反応2013

    • Author(s)
      渡部紗世,徳光千尋,紺野貴史, 緒方賢一・福澤信一
    • Organizer
      日本化学会第93 春季年会
    • Place of Presentation
      立命館大学,草津
    • Year and Date
      2013-03-22
  • [Presentation] 銀(I)/ThioClickFerrophos 錯体触媒を用いるグリシンイミノエステルと α,β-不飽和エステルとの不斉共役付加反応2012

    • Author(s)
      紺野貴史,緒方賢一,福澤信一
    • Organizer
      第64回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      長岡技術科学大学,長岡
    • Year and Date
      2012-12-01
  • [Presentation] Asymmetric Conjugate Addition of Glycine Imine to Nitroalkenes catalyzed by Ag/ThioClickFerrophos Complex2012

    • Author(s)
      Shin-ichi Fukuzawa
    • Organizer
      Cambodian Malaysian Chemical Conference
    • Place of Presentation
      シェムリアップ,カンボジア
    • Year and Date
      2012-10-19
  • [Presentation] Silver ThioClickFerrophos-Catalyzed Enantioselective conjugate Addition and Cycloaddition ofGlycine Schiff Base with Nitroalkenes2012

    • Author(s)
      Takashi Konno, Kazumi Imae, Kenichi Ogata,Shin-ichi Fukuzawa
    • Organizer
      International Conference on Organometallic Chemistry
    • Place of Presentation
      リスボン,ポルトガル
    • Year and Date
      2012-09-07
  • [Presentation] ビニルセレノンとアゾメチンイリドとの 1,3-双極子環化付加反応を経るピロール合成2012

    • Author(s)
      渡部紗世,緒方賢一,福沢信一
    • Organizer
      第63回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      東京理科大,野田
    • Year and Date
      2012-05-19
  • [Presentation] 光学活性アミノフェロセンの alpha 位置換反応の立体化学の再検証2012

    • Author(s)
      高橋樹生,福沢信一,緒方賢一
    • Organizer
      第63回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      東京理科大,野田
    • Year and Date
      2012-05-19
  • [Presentation] 新型ClickFerrophos -ロジウム錯体を用いるα,β-不飽和リン酸エステルの不斉水素化反応2012

    • Author(s)
      紺野貴史・緒方賢一・ 福澤信一
    • Organizer
      日本化学会第92 春季年会
    • Place of Presentation
      慶應義塾大学,日吉
    • Year and Date
      2012-03-26
  • [Presentation] Synthesis of Palladium 1,2,3-Triazol-5-ylidene Complexes and Their Catalysis in Coupling Reactionswith Aryl Halides2011

    • Author(s)
      S. Fukuzawa, T. Terashima
    • Organizer
      XIX EuCheMS Conference on Organometallic Chemistry
    • Place of Presentation
      トゥルーズ,フランス
    • Year and Date
      2011-07-05
  • [Presentation] ClickFerrophos/銀錯体触媒を用いるイミノエステルの不斉 α-アミノ化反応および Mannich反応2011

    • Author(s)
      今榮麗仁,緒方賢一, 福澤信一
    • Organizer
      日本化学会第91 春季年会
    • Place of Presentation
      神奈川大学,横浜
    • Year and Date
      2011-03-29
  • [Presentation] Preparation of new ClickFerrophos ligands and their application to asymmetric synthesis2010

    • Author(s)
      K. Imae, K. Shimizu, K. Ogata, S. Fukuzawa
    • Organizer
      PACHIFICHEM2010
    • Place of Presentation
      ホノルル,USA
    • Year and Date
      2010-12-17
  • [Presentation] Asymmetric C-C-Bond Formation by Ag and Cu/ClickFerrophos Ligands2010

    • Author(s)
      K. Shimizu, K. Imae, K. Ogata, S. Fukuzawa
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学,八王子
    • Year and Date
      2010-09-17
  • [Remarks]

    • URL

      http://www.chem.chuo-u.ac.jp/~fukuzawaweb/index.html

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Published: 2014-08-29  

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