2012 Fiscal Year Final Research Report
A Breakthrough in Preparation of Noble Metal Nanoparticle Catalysts Supported on Activated Carbon Support - A New Approach from the View Point of Coordination Chemistry
| Project/Area Number |
22550054
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | 金属錯体化学 |
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| Research Abstract |
Activated carbon-supported Pd and Rh nanoparticles (Pd/C andRh/C) have been prepared by a new method which is based on the self-redox of their oxaltecomplexes without any additional reducing agents. Octylamine-and oleylamine-stabilizedPd nanoparticles supported on activated carbon (octyla-Pd/C and oleyla-Pd/C) have beenalso prepared. Catalytic properties of these Pd/C, Rh/C, octyla-Pd/C and oleyla-Pd/C wereevaluated for the hydrogenation of phenol, and compared with those of commerciallyavailable catalysts.
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