2012 Fiscal Year Final Research Report
Investigation of the effect of ion-pair formation on the stability of hydrogen-bond-assisted polyoxometalate aggregates
| Project/Area Number |
22550056
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
OZEKI Tomoji 東京工業大学, 大学院・理工学研究科, 准教授 (60214136)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 多核錯体 |
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| Research Abstract |
The hydrogen-bond assisted dimerization behavior of protonated decavanadate anions has been investigated by using small angle X-ray scattering and NMR spectroscopy. In protophobic solvents such as acetone and acetonitrile, the decavanadate anions form hydrogen-bonded dimers, whereas the dimers dissociate into monomers in protophilic solvents such as 1,4-dioxane and dimethyl sulfoxide. The dimerization behavior of the decavanadate was proved to depend on the protophilic/protophobic nature of the solvents. The stability of the dimers in the presence of tetrapentyl-, tetraoctyl- and tetradecyl-ammonium cations as the counter cations was also investigated.
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[Journal Article] Preparation and Structural Characterization of RuII-DMSO and RuIII-DMSO-substituted α-Keggin-type Phosphotungstates,[PW_11O_39 Ru^IIDMSO]^5-and[PW_11O_39 Ru^IIIDMSO]4-, and CatalyticActivity for Water Oxidation2011
Author(s)
M. Sadakane, N. Rinn, S. Moroi, H.Kitatomi, T. Ozeki, M. Kurasawa, M. Itakura, S. Hayakawa, K. Kato, M. Miyamoto, S. Ogo, Y. Ide, T. Sano
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Journal Title
Z. Anorg. Allg. Chem.
Volume: 637
Pages: 1467-1474
DOI
Peer Reviewed
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[Presentation] フッ素置換安息香酸Feクラスターの新展開原子価局在-非局在と57Fe-メスバウアー分光法による有機蒸気センシングの可能性2012
Author(s)
尾中証, 酒井陽一, 尾関智二, 中本忠宏, 高橋正, 小林雄介, 坂村雅啓, 伊藤光宏, 小木曽了, 塩塚理仁, 高山努
Organizer
錯体化学会第62回討論会
Place of Presentation
富山大学、富山県富山市
Year and Date
20120921-23
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[Presentation] 単結晶中性子回折によるモリブデンオキソ錯体中の水素結合の解析2012
Author(s)
尾関智二, 大原高志, 下野貴弘, 田中伊 知朗, 日下勝弘, 細谷孝明, 山田太郎, 栗 原和男, 新村信雄, 定金正洋, 上田渉, W. Feng
Organizer
第3回 MLFシンポジウム, いばらき量子ビーム研究センター
Place of Presentation
茨城県東海村
Year and Date
20120119-20
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[Book] ハウスクロフト無機化学2012
Author(s)
巽和行, 西原寛, 穐田宗隆, 酒井健 監訳, 穐田宗隆, 石井洋一, 石田斉, 上野圭司, 尾関智二, 加藤昌子, 酒井健, 棚瀬知明,坪村太郎, 西原寛, 長谷川美貴, 水田勉訳
Total Pages
275-314および478-520
Publisher
東京化学同人
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