2012 Fiscal Year Final Research Report
Studies on thermal deactivation processes of phosphorescent states in transition-metal complexes
| Project/Area Number |
22550057
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | University of Toyama |
|---|
Principal Investigator |
NOZAKI Koichi 富山大学, 大学院・理工学研究部, 教授 (20212128)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
IWAMURA Munetaka 富山大学, 大学院・理工学研究部, 講師 (60372942)
|
|---|
| Project Period (FY) |
2010 – 2012
|
| Keywords | リン光 |
|---|
| Research Abstract |
Thermal deactivation pathways of phosphorescent state in d6 and d8metal complexes were elucidated based on the pathways calculated using DFT and observed activation energies and volumes. It was revealed that the rate-determining step of the deactivation process was at dd->GS for Ru（II) tris-bipyridine complexes whereas it was located between MLCT and dd for Pt（II) acac complexes.
|
-
[Journal Article] hotoinduced electron transfer of platinum bipyridine diacetylides linked by triphenylamine- and aphthaleneimide-derivatives and its application to photoelectric conversion systems2013
Author(s)
S. Suzuki, Y. Matsumoto, M. Tsubamoto, R. Sugimura, M. Kozaki, K. Kimoto, M. Iwamura, K. Nozaki, N. Senju, C. Uragami, H. Hashimoto, Y. Muramatsu, A. Konno, K. Okada
-
Journal Title
Physical Chemistry Chemical Physics
Pages: 15
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
