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2012 Fiscal Year Final Research Report

Development of on-off controllable photochromic dinuclear ruthenium complexes by redox switch

Research Project

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Project/Area Number 22550062
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

YAMAGUCHI Motoo  首都大学東京, 都市環境科学研究科, 教授 (60174637)

Co-Investigator(Kenkyū-buntansha) SATO Kiyoshi  首都大学東京, 都市環境科学研究科, 准教授 (40285101)
Project Period (FY) 2010 – 2012
Keywords多核錯体 / フォトクロミズム
Research Abstract

Pyrazine-bridged dinuclear ruthenium complexes show color change in solution by selective dissociation of the bridging ligand under visible-light irradiation. The dinuclear complexes display photochromic behavior, since they are recovered by heating. In this study, we synthesized the dinuclear complexes having redox responsive switchingmoieties, such as benzoquinone and hydroquinone, and the photodissociation rates of these complexes have been measured. It was found that the photodissociation rate of thedinuclear complexes having benzoquinone moieties was depressed. The observation suggests that the application of the complexes developed in this study to the new photochromic material which is controllable by external factor would be possible.

  • Research Products

    (23 results)

All 2013 2012 2011 2010

All Presentation (23 results)

  • [Presentation] 自己集合によるルテニウム環状多核錯体の合成2013

    • Author(s)
      森山良太,平山暁子,佐藤 潔,山口素夫(代表)
    • Organizer
      日本化学会第93 春季年会
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] 新規非対称型ルテニウム二核錯体の合成と配位子光解離反応の検討2013

    • Author(s)
      保坂太一,江口智文,佐藤 潔,山口素夫(代表)
    • Organizer
      日本化学会第93春季年会 2013年3月23日
    • Place of Presentation
      滋賀
    • Year and Date
      2013-03-23
  • [Presentation] ルテニウム錯体による可視光照射下での有機ハロゲン化物の脱ハロゲン化反応の検討2012

    • Author(s)
      金曽祐一,伊藤宗宣,佐藤 潔,山口素夫(代表)
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-21
  • [Presentation] 大環状三核錯体および四核錯体の自己集合による合成と包接挙動2012

    • Author(s)
      平山暁子,小原 眞,佐藤 潔,山口素夫(代表)
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-21
  • [Presentation] 三座-二座混合配位型ルテニウム錯体の合成と配位子の光解離反応の検討2012

    • Author(s)
      江口智文,正野大河,佐藤 潔,山口素夫(代表)
    • Organizer
      第62回錯体化学討論会
    • Place of Presentation
      富山
    • Year and Date
      2012-09-21
  • [Presentation] Light-induced SelectiveDissociation of Pyrazine-bridged Diruthenium Complexes2012

    • Author(s)
      Motowo Yamaguchi(代表), Sara Tsuyuki, and Kiyoshi Sato
    • Organizer
      40thInternational Conference on Coordination Chemistry
    • Place of Presentation
      Valencia (Spain)
    • Year and Date
      2012-09-10
  • [Presentation] ルテニウム錯体による可視光照射下での有機ハロゲン化物からのハライドイオン引き抜き反応の検討2012

    • Author(s)
      金曽祐一,伊藤宗宣,佐藤 潔,山口素夫(代表)
    • Organizer
      第24回配位化合物の光化学討論会
    • Place of Presentation
      駒場
    • Year and Date
      2012-08-07
  • [Presentation] Synthesis of Macrocyclic Trinuclear and Tetranuclear Ruthenium Complexes by Self-Assembly: Photoreaction and Inclusion Behaviour(Plenary Lecture)2012

    • Author(s)
      Motowo YAMAGUCHI(代表),Akiko HIRAYAMA, Makoto OBARA and Kiyoshi SATO
    • Organizer
      19th International Symposium on Pure and Applied Coordination Chemistry
    • Place of Presentation
      Sapporo (Japan)
    • Year and Date
      2012-08-03
  • [Presentation] ピラジン架橋部位を持つルテニウム錯体の自己集合による環状多核錯体の合成2011

    • Author(s)
      濱崎 彩,佐藤 潔,山口素夫(代表)
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-18
  • [Presentation] 環状多核ルテニウム錯体の自己集合による合成とその包接挙動2011

    • Author(s)
      平山暁子,小原 眞,佐藤 潔,山口素夫(代表)
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-18
  • [Presentation] 酸化還元スイッチをもつルテニウム錯体の光反応2011

    • Author(s)
      山口素夫(代表),水野義隆,正野大河,佐藤 潔
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-17
  • [Presentation] スイッチング機能をもつルテニウム二核錯体の合成とその光反応の検討2011

    • Author(s)
      露木紗羅,正野大河,佐藤 潔,山口素夫(代表)
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山
    • Year and Date
      2011-09-17
  • [Presentation] Redox-responsive Switches for Photochemical Reactions Based on Ruthenium(II) Complexes(招待講演)2011

    • Author(s)
      Motowo YAMAGUCHI(代表), Taiga MASANO, Yoshitaka MIZUNO, Sara TSUYUKI, and Kiyoshi SATO
    • Organizer
      18th Symposium on Pure and Applied Coordination Chemistry
    • Place of Presentation
      Whistler (Canada).
    • Year and Date
      2011-08-06
  • [Presentation] ピラジン架橋部位を持つ新規なルテニウム環状多核錯体の合成2011

    • Author(s)
      濱崎 彩,韓 基成,佐藤 潔,山口素夫(代表)
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
  • [Presentation] ルテニウム環状多核錯体の合成とその包接挙動2011

    • Author(s)
      平山暁子,小原 眞,佐藤 潔,山口素夫(代表)
    • Organizer
      日本化学会第91 春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
  • [Presentation] Synthesis of Macrocyclic Multinuclear Ruthenium Complexes and their Inclusion Behavior and Photochemical Reaction 20102010

    • Author(s)
      Motowo YAMAGUCHI(代表), Makoto OBARA, Kiyoshi SATO
    • Organizer
      環太平洋国際化学会議(Pacifichem2010)
    • Place of Presentation
      ハワイ(アメリカ)
    • Year and Date
      2010-12-18
  • [Presentation] Characterization of Pyrazine-bridged Ruthenium Binuclear Complexes and Examination of Their Electrochromic Properties2010

    • Author(s)
      Tsuyuki SARA, Makoto OBARA, Ryouta TANABE, Kiyoshi SATO, Motowo YAMAGUCHI(代表)
    • Organizer
      2010 環太平洋国際化学会議(Pacifichem2010)
    • Place of Presentation
      ハワイ(アメリカ)
    • Year and Date
      2010-12-16
  • [Presentation] Development of the New Photochemical Functional Ruthenium Complex Showing Switching Property on Photochemical Reaction of a Ligand2010

    • Author(s)
      Yoshitaka MIZUNO, Taiga MASANO, Kiyoshi SATO, Motowo YAMAGUCHI(代表)
    • Organizer
      2010 環太平洋国際化学会議(Pacifichem2010)
    • Place of Presentation
      ハワイ(アメリカ)
    • Year and Date
      2010-12-16
  • [Presentation] Syntheses of Photoresponsive Metalla-macrocyclic Complexes by Self-assembly and their Host-guest Complexation Behavior and Photoreactivity (招待講演)2010

    • Author(s)
      Motowo YAMAGUCHI(代表), Makoto OBARA, Akiko HIRAYAMA, and Kiyoshi SATO
    • Organizer
      2ndInternational Symposium on Photofunctional Chemistry of Complex Systems
    • Place of Presentation
      ハワイ(アメリカ)
    • Year and Date
      2010-12-12
  • [Presentation] Development of Photoresponsive Ruthenium-square: Synthesis of Macrocyclic Tetranuclear Ruthenium Complex by Self-assembly and Its Inclusion Behavior(招待講演)2010

    • Author(s)
      Motowo YAMAGUCHI(代表), Makoto OBARA, Akiko HIRAYAMA, Kiyoshi SATO
    • Organizer
      The 17thInternational Symposium on Society of Pure and Applied Coordination Chemistry
    • Place of Presentation
      鹿児島
    • Year and Date
      2010-10-14
  • [Presentation] 配位子光解離反応におけるスイッチング機能を持つ新規な光機能性ルテニウム錯体の開発2010

    • Author(s)
      水野義隆,正野大河,佐藤 潔,山口素夫(代表)
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] ピラジン架橋ルテニウム二核錯体のエレクトロクロミズム2010

    • Author(s)
      22露木紗羅,小原 眞,田辺良太,佐藤 潔,山口素夫(代表)
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28
  • [Presentation] サンドイッチ型ポルフィリンを有する光反応性ルテニウム二核錯体の合成と性質2010

    • Author(s)
      土屋宏充,小原 眞,佐藤 潔,山口素夫(代表)
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-28

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Published: 2014-08-29  

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